• 제목/요약/키워드: Reference electrode

검색결과 282건 처리시간 0.025초

NASICON 고체 전해질을 사용한 SOx 가스 감지센서 (SOx Sensor Using NASICON Solid Electrolyte)

  • 최순돈;이광범
    • 센서학회지
    • /
    • 제5권4호
    • /
    • pp.25-34
    • /
    • 1996
  • NASICON 전해질을 이용하여 대기환경 측정용의 SOx센서를 개발하였다. 다음 형태의 $Na_{2}SiO_{3}(Pt)$ 기준전극을 사용한 갈바니 셀을 조립하였다. Pt | $Na_{2}SiO_{3}$ | NASICON | $Na_{2}SO_{4}$ | Pt, $SO_{2}$, air $SO_{2}$ 와 NASICON의 반응을 피하기 위해 $Na_{2}SO_{4}(Pt)$를 지시전극으로 사용하였으며, $400{\sim}550^{\circ}C$ 범위에서 $5{\sim}95ppm$ 농도의 $SO_{2}$ 가스를 주입하고 나서 EMF를 측정하였다. $500^{\circ}C$ 이상의 온도에서 측정된 EMF는 계산치와 일치하였으나, $500^{\circ}C$ 이하에서는 불완전한 평형 때문에 센서의 거동이 불안정하였다. 감응시간은 약 10분 정도 이내였다. 이전지의 안정도와 응답시간으로 보건데, $Na_{2}SiO_{3}(Pt)$를 기준전극으로 하고 순수 $Na_{2}SO_{4}(Pt)$를 지시전극으로한 NASICON 고체전해질은 SOx 측정용의 상업적인 센서물질로써 가능성이 있다.

  • PDF

4채널 전두엽 전극 배치법의 제안과 측정된 뇌파에서의 안전도 제거에 관한 연구 (Proposition for 4 Channel Frontal Lobe Electrode Configuration and Study on EOG Removal from Measured EEG)

  • 신수인;조진호;김명남
    • 한국멀티미디어학회논문지
    • /
    • 제6권1호
    • /
    • pp.167-175
    • /
    • 2003
  • 본 논문에서는 전두엽에서의 뇌파 측정시 안전도를 제거할 수 있는 새로운 전극배치법과 제거방법을 제안하였다. 제안한 방식에서는 전두엽에서의 4개의 신호전극과 1개의 접지전극 및 좌측 귓불의 기준전극을 이용하여 뇌파를 측정하였다. 그리고 제안한 전극방식을 통하여 뇌파 측정시 안전도를 제거하기 위하여 ICA를 이용하는 분리방법을 제안하였다. 뇌파 측정실험을 통하여 피험자가 다른 사람의 도움 없이 손쉽게 전극을 사용하여 자신의 뇌파를 측정할 수 있음을 알 수 있었으며 제안한 방법이 뇌파신호로부터 안전도를 제거하는데 유효함을 확인하였다.

  • PDF

해상용 원심펌프 임펠러의 침식억제법으로 음극방식 및 재료개발에 관한 기초연구 1 (Fundamental Study on Cathodic Protection and Material Development as Erosion-Control Methods of Oceanic Centrifugal Pump(1))

  • 이진열;임우조
    • Journal of Advanced Marine Engineering and Technology
    • /
    • 제19권2호
    • /
    • pp.56-66
    • /
    • 1995
  • Recently, with theraped advancement in th oceanology such an ocean-going vessel and oceanic structures, there is a need to study the cavitation erosion-corrosion control of pump impeller, the partial element of ocean machinery, for more effective operation. Especially, the cathodic protection (impressed current method & Al-sacrificial anode method) was applied to sea water, and Cu-alloy material mixed Zn & Al was used as a control method of cavitation erosion-corrosion. In this study, used the piezoelectric vibrator with 20KHz, 24.mu.m to cavity generation apparatus, and investigated the weight loss, weight loss rate, electrode potential & current density etc. under this condition. According to test result, thos describes how to indentify an influence of the cathodic protection and Al & Zn addition in material development for the control of cavitation erosion-corrosion, and those will serve as fundamental data on the cavitation erosion-corrosion control of oceanic centrifugal pump.

  • PDF

Electrochemical Oxidation of Ethanol at Nickel Hydroxide Electrodes in Alkaline Media Studied by Electrochemical Impedance Spectroscopy

  • Kim, Jae-Woo;Park, Su-Moon
    • 전기화학회지
    • /
    • 제8권3호
    • /
    • pp.117-124
    • /
    • 2005
  • Electrochemical oxidation of ethanol at nickel electrodes has been studied in 1 M KOH solution containing 0.20M ethanol using electrochemical impedance spectroscopy. Equivalent circuits have been worked out by simulating the impedance data, and the results were used to model the oxidation of ethanol as well as the passivation of the electrode. The maximum rate of oxidation of $Ni(OH)_2$ to NiOOH was observed at about 0.37V vs. Ag/AgCl reference electrode, while the maximum rate of ethanol oxidation at the Ni electrode was observed at about 0.42V, The charge-transfer resistance for oxidation of the electrode itself became smaller in the presence of ethanol than in its absence. These results suggest that the $\beta-Ni(OH)_2/\beta-NiOOH$ redox couple is acting as an effective electron transfer mediator far ethanol oxidation. The kinetic parameters also were obtained by the experimental and simulated results.

Detection of Protein Molecules by Electrical Current Response Using Two-Electrode Method

  • Lyu, Hong-Kun;Woo, Sung-Ho;Han, Yoon-Soo;Lee, Hee-Ho;Shin, Jang-Kyoo
    • 센서학회지
    • /
    • 제20권2호
    • /
    • pp.90-95
    • /
    • 2011
  • In order to protect human lives from disease, various biosensors having the potential to analyze a variety of biomolecules have been utilized. Biosensors constitute one of the most promising ways to monitor and detect various biomolecules corresponding to diseases. In this study, we demonstrate that the reaction of streptavidin molecules with biotin on a gold electrode can be detected using the twoelectrode method with a gold electrode and a platinum reference electrode. We also show the characteristics of the electrical current response. While detecting 2-${\mu}M$ streptavidin molecules dissolved in phosphate buffered saline(PBS) solution, we found that an analytical biosensor can operate on the principle of detecting an antigen-antibody reaction event of protein molecules using the two-electrode method. We think that the "potential step" method might be useful to detect the occurrence of any antigen-antibody reactions and can be combined with other devices or ICs such as BJTs, MOSFETs, and OP-amps for the detection of biomolecules of diseases.

변전소 접지설계를 위한 접지전극 주변의 위험전압 측정과 분석 (Measurement and Analysis of the Dangerous Voltage Around Grounding Electrode for Safety in Substation Ground)

  • 손석금;김재철
    • 전기학회논문지P
    • /
    • 제60권4호
    • /
    • pp.214-219
    • /
    • 2011
  • The substation grounding design,"IEEE Guide for Safety in AC Substation Grounding (ANSI / IEEE Std 80)"has been widely used. Substation grounding design and substation grounding resistance of grounding network site to predict the voltage at the risk of a very important task, which is a ground fault current due to the influx of the ground network and due to rise in the Earth's potential can be applied to human dangerous Voltage within safe tolerances be configured to be the ground because the network. IEEE Std. 80 for the substation construction safety equipment on the ground securing the ground electrode and the mesh around the boundary potential distribution in terms of risk analysis by the touch voltage and the reference was to clean up the definition and the basic steps of the voltage of the voltage limits the risk of peripheral grounding electrode Suppression by the simulator through a new secure from dangerous voltage design techniques were presented.

Polypyrrole-Glucose Oxidase 효소전극의 배위자 크기에 따른 전기 화학적 특성 (Electrochemical Properties of Polypyrrole-Glucose Oxidase Enzyme Electrode Depending on Dopant Size)

  • 김현철;구할본;사공건
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
    • /
    • pp.745-748
    • /
    • 2001
  • We synthesized polypyrrole (PPy) by electrolysis of the pyrrole monomer solution containing support electrolyte KCl and/or p-toluene sulfonic acid sodium salt (p-TS). The electrochemical behavior was investigated using cyclic voltammetry and AC impedance. In the case of using electrolyte p-TS, the redox potential was about -0.3 V vs. Ag/AgCl reference electrode, while the potential was about 0 V for using electrolyte KCl. It is considered as the backbone forms a queue effectively by doping p-T S. Therefore, it is possible to be arranged regularly. That leads to improvement in the electron hopping. The AC impedance plot gave a hint of betterment of mass transport. PPy doped with p-TS has improved in mass transport, or diffusion. That is because the PPy doped with p-TS has a good orientation, and is more porous than PPy with KCl.

  • PDF

Recent Improvement of Luminous Efficacy for AC-PDP with Tilted Facing Electrode

  • Ok, Jung-Woo;Kim, Deok-Won;Lim, Jeong-Hwan;Kim, Dong-Hyun;Lee, Ho-Jun;Park, Chung-Hoo
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
    • /
    • pp.65-68
    • /
    • 2008
  • In this study, in order to improve luminous efficacy of AC-PDP, the new facing discharge structure has been suggested. The suggested structure has tilted facing electrode. It shows lower discharge current, higher luminance and luminous efficacy compared with those of reference structure with coplanar electrode structure.

  • PDF

포도당 산화효소를 고정화한 Polypyrrole 효소전극의 배위자 변화에 다른 전기화학적 특성 (Electrochemical Properties of Polypyrrole Enzyme Electrode Immobilized Glucose Oxidase with Different Ligand)

  • 김현철;구할본
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
    • /
    • pp.529-532
    • /
    • 2001
  • We synthesized polypyrrole (PPy) by electrolysis of the pyrrole monomer solution containing support electrolyte KCl and/or p-toluene sulfonic acid sodium salt (p-TS). The electrochemical behavior was investigated using cyclic voltammetry and AC impedance. In the case of using electrolyte p-TS, the redox potential was about -0.3 V vs. Ag/ AgCl reference electrode, while the potential was about 0 V for using electrolyte KCl. It is considered as the backbone forms a queue effectively by doping p-TS Therefore, it is possible to be arranged regularly. That leads to improvement in the electron hopping. The AC impedance plot gave a hint of betterment of mass transport. PPy doped with p-TS has improved in mass transport, or diffusion. That is because the PPy doped with p-TS has a good orientation, and is more porous than PPy with KCl.

  • PDF

마이크로머시닝 기술을 이용한 3차원 마이크로 챔버형 글루코스 센서의 개발 (Development of Three-dimensional Chamber-type Glucose Sensor Using Micromachining Technology)

  • 김성호;김창교
    • 한국산학기술학회논문지
    • /
    • 제6권1호
    • /
    • pp.24-28
    • /
    • 2005
  • 3차원 실리콘 챔버를 갖는 $15.8{\times}15.8 mm^2$크기의 칩을 바이오 센서용으로 마이크로머시닝 기술을 이용하여 개발하였다. 비등방성 식각기술을 이용하여 (100)방향의 p형 실리콘 웨이퍼위에 마이크로 챔버를 형성하였다. 마이크로 챔버를 갖는 웨이퍼와 백금전극이 도포된 Pyrex 유리를 DGF-48S 접착제를 이용하여 접합하였다. 백금전극과 Ag/AgCl 기준전극에 의한 전기화학적 특성을 조사하였다.

  • PDF