• 제목/요약/키워드: Reduction-Diffusion Process

검색결과 143건 처리시간 0.025초

전해환원 공정의 우라늄 산화물 환원 거동 모사를 위한 Phase-Field 이론 적용 (Application of Phase-Field Theory to Model Uranium Oxide Reduction Behavior in Electrolytic Reduction Process)

  • 박병흥;정상문
    • 방사성폐기물학회지
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    • 제16권3호
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    • pp.291-299
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    • 2018
  • 파이로 공정에서는 사용후핵연료 관리 공정 개발의 일환으로 산화 우라늄을 고온 용융염 전해질계에서 전기화학적 방법으로 환원시키기 위한 전해환원 공정이 개발되고 있다. 이에 따른 전해환원 공정의 반응기 설계를 위해서는 전기화학적 이론에 기초한 모델이 요구되고 있다. 본 연구에서는 상 분리를 설명하는 phase-field 이론에 기초하여 우라늄 산화물의 전해환원 모사를 위한 1차원 모델이 개발되었다. 모델은 우라늄 산화물 내 산소 원소의 확산과 펠렛 표면에서 전기화학 반응 속도를 나타내는 매개변수를 사용하여 외부로부터 내부로 진행되는 전해환원을 잘 모사하고 있으며 계산 결과 전체 전류는 산소원소의 내부 확산에 크게 의존하는 것으로 나타났다. 전해환원 반응에 대한 모델은 대용량 장치 설계에 최적화된 조건 도출에 활용될 것으로 예상되며 장치 설계가 완료되면 공정 연계 모사에 직접 사용될 것으로 기대된다.

확산 Markov 프로세스 모델을 이용한 Queueing System 기반 지능 부하관리에 관한 연구 (A Study on the Intelligent Load Management System Based on Queue with Diffusion Markov Process Model)

  • 김경동;김석현;이승철
    • 전기학회논문지
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    • 제58권5호
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    • pp.891-897
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    • 2009
  • This paper presents a novel load management technique that can lower the peak demand caused by package airconditioner loads in large apartment complex. An intelligent hierarchical load management system composed of a Central Intelligent Management System(CIMS) and multiple Local Intelligent Management Systems(LIMS) is proposed to implement the proposed technique. Once the required amount of the power reduction is set, CIMS issues tokens, which can be used by each LIMS as a right to turn on the airconditioner. CIMS creates and maintains a queue for fair and proper allocation of the tokens among the LIMS requesting tokens. By adjusting the number tokens and queue management policies, desired power reduction can be achieved smoothly. The Markov Birth and Death process and the Balance Equations utilizing the Diffusion Model are employed for evaluation of queue performances during transient periods until the static balances among the states are achieved. The proposed technique is tested using a summer load data of a large apartment complex and give promising results demonstrating the usability in load management while minimizing the customer inconveniences.

Chloride diffusion study in different types of concrete using finite element method (FEM)

  • Paul, Sajal K.;Chaudhuri, Subrata;Barai, Sudhirkumar V.
    • Advances in concrete construction
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    • 제2권1호
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    • pp.39-56
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    • 2014
  • Corrosion in RCC structures is one of the most important factors that affects the structure's durability and subsequently causes reduction of serviceability. The most severe cause of this corrosion is chloride attack. Hence, to prevent this to happen proper understanding of the chloride penetration into concrete structures is necessary. In this study, first the mechanism of this chloride attack is understood and various parameters affecting the process are identified. Then an FEM modelling is carried out for the chloride diffusion process. The effects of fly ash and slag on the diffusion coefficient and chloride penetration depth in various mixes of concretes are also analyzed through integrating Virtual RCPT Lab and FEM.

다공성 미디아에 있어서 유효확산계수 (Effective Diffusion Coefficient in the Porous Media)

  • Jeehyeong Khim
    • 한국토양환경학회지
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    • 제1권2호
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    • pp.83-90
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    • 1996
  • 토양내에서의 가스나 증기상의 오염물질의 이동은 여러 가지 현상에 의해서 일어나고 있으나 농도차에 의해서 일어나는 확산이 가장 중요하다. 그런데 토양내에서의 확산은 토양 입자들로 인한 확산 부피의 감소, 또 확산경로의 불규칙성, 확산 경로에 있어서 단면적의 변화 등으로 인해 대기중에서 일어나는 확산과는 다른 면을 보인다. 본 논문에서는 이러한 현상을 설명하기 위하여 흔히 사용되는 굴절계수(toruosity), 유효확산계수(effective diffusion coefficient)의 서로 다른 그러나 같은 이름으로 사용되는 많은 정의들과 다양한 수학적 모델들에 대한 비교 검토가 이루어졌다. 굴절계수나 유효확산계수를 사용할 때는 각각의 경우 정의와 각 식의 특징에 대하여 세밀한 검토와 주의가 행하여져야 한다.

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경계 영역에서 색 번짐 감소를 위한 멀티레벨 벡터 오차 확산법 (Multi-level Vector Error Diffusion for Smear Artifact Reduction in the Boundary Regions)

  • 박태용;조양호;김윤태;하영호
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2003년도 신호처리소사이어티 추계학술대회 논문집
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    • pp.461-464
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    • 2003
  • This paper proposes the multi-level vector error diffusion for smear artifact reduction in the boundary regions. Smear artifact mainly results from a large accumulation of quantization error. Accordingly, to reduce these artifacts, the proposed method excludes the large quantization error in the error diffusion process by comparing the magnitude of the error vector with predetermined first threshold. In addition, if the vector norm of the difference between the error adjusted input vector and the primary co]or that has minimum vector norm for the error adjusted input vector is larger than second threshold, the error is excluded. As a result, the proposed method reduce smear artifact in the boundary region and produces visually pleasing halftone pattern.

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저압식 진공 침탄(LPC) 열처리 공정 기술 개발 (Development of Process Technology for Low Pressure Vaccum Carburizing)

  • 동상근;양제복
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2004년도 제29회 KOSCI SYMPOSIUM 논문집
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    • pp.231-237
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    • 2004
  • Vacuum carburizing continues to gain acceptance as an alternative to atmosphere carburizing particularly in the car industry. The advantages of low-pressure carburization over atmospheric gas carburization is not only the creation of a surface entirely free of oxide and the environmentally friendly nature of these methods but also an improvement in deformation behaviour achieved by combining carburization with gas quenching, a reduction in batch times by increasing the carburization temperature, low gas and energy consumption and the prevention of soot to a large extent. In present study, an improved vacuum carburizing method is provided which is effective to deposit carbon in the surface of materials and to reduce cycle time. Also LPC process simulator was made to optimize to process controls parameters such as pulse/pause cycles of pressure pattern, temperature, carburizing time, diffusion time. The carburizing process was simulated by a diffusion calculation program, where as the model parameters are proposed with help the experimental results and allows the control of the carburizing process with good accordance to the practical results. Thus it can be concluded that LPC process control method based on the theoretical simulation and experimental datas appears to provide a reasonable tool for prototype LPC system.

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MOLTEN SALT VAPORIZATION DURING ELECTROLYTIC REDUCTION

  • Hur, Jin-Mok;Jeong, Sang-Moon;Lee, Han-Soo
    • Nuclear Engineering and Technology
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    • 제42권1호
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    • pp.73-78
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    • 2010
  • The suppression of molten salt vaporization is one of the key technical issues in the electrolytic reduction process developed for recycling spent nuclear fuel from light-water reactors Since the Hertz-Langmuir relation previously applied to molten salt vaporization is valid only for vaporization into a vacuum, a diffusion model was derived to quantitatively assess the vaporization of LiCl, $Li_2O$ and Li from an electrolytic reducer operating under atmospheric pressure. Vaporization rates as a function of operation variables were calculated and shown to be in reasonable agreement with the experimental data obtained from thermogravimetry.