• Title/Summary/Keyword: Reduction process

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Variation of Optimum Operational pH in Partial Nitritation (암모니아 폐수의 부분아질산화에서 최적 운전 pH의 변동)

  • Bae, Wookeun;Khan, Hammad
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.5
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    • pp.228-235
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    • 2016
  • Nitrite accumulation is essential for constructing an anammox process. As the pH in the reactor exerts a complicated and strong influence on the reaction rate, we investigated its effects upon treatment of an ammonic wastewater (2,000 mgN/L) through modeling and experiment. The modeling results indicated that the reaction stability is strongly affected by pH, which results in a severe reduction of the 'stable region' of operation under alkaline environments. On a coordinate of the total ammonia nitrogen (TAN) concentration vs. pH, the maximal stable reaction rates and the maximal nitrite accumulation potentials could be found on the 'stability ridge' that separates the stable region from the unstable region. We achieved a stable and high ammonia oxidation rate (${\sim}6kgN/m^3-d$) with a nitrite accumulation ratio of ~99% when operated near the 'stability ridge'. The optimum pH that can be observed in experiments varies with the TAN concentrations utilized, although the intrinsic optimum pH is fixed. The direction of change is that the optimum operational pH falls as the TAN concentration increases, which is in excellent accordance with the observations in the literature. The optimum operational pH for 95% nitritation was predicted to be ~8.0, whereas it was ~7.2 for 55% partial nitritation to produce an anammox feed in our experimental conditions.

Control of Membrane Fouling in Submerged Membrane Bioreactor(MBR) using Air Scouring (침지형 생물 반응기 공정에서 플럭스 향상을 위한 공기 세척 효과에 관한 연구)

  • Shin, Dong-Hwan;Baek, Byung-Do;Chang, In-Soung
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.9
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    • pp.948-954
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    • 2008
  • Membrane bioreactor(MBR) processes have been widely applied to wastewater treatment for last decades due to its excellent capability of solid-liquid separation. However, membrane fouling was considered as a limiting factor in wide application of the MBR process. Excess aeration into membrane surface is a common way to control membrane fouling in most MBR. However, the excessively supplied air is easily dissipated in the reactor, which results in consuming energy and thus, it should be modified for effective control of membrane fouling. In this study, cylindrical tube was introduced to MBR in order to use the supplied air effectively. Membrane fibers were immersed into the cylindrical tube. This makes the supplied air non-dissipated in the reactor so that membrane fouling could be controlled economically. Two different air supplying method was employed and compared each other; nozzle and porous diffuser which were located just beneath the membrane module. Transmembrane pressure(TMP) was monitored as a function of airflow rate, flux, and ratio of the tube area and cross-sectioned area of membrane fibers(A$_m$/A$_t$). Flow rate of air and liquid was regulated to obtain slug flow in the cylindrical tube. With the same flow of air supply, nozzle was more effective for controlling membrane fouling than porous diffuser. Accumulation of sludge was observed in the tube with the nozzle, if the air was not suppled sufficiently. Reduction of membrane fouling was dependent upon the ratio, A$_m$/A$_t$. For diffuser, membrane fouling was minimized when A$_m$/A$_t$ was 0.27, but 0.55 for nozzle.

Electrorefining Behavior of Zirconium Scrap with Multiple Cathode in Fluoride-Based Molten Salt (불화물계 용융염을 이용한 지르코늄 스크랩의 다중전극 전해정련 거동)

  • Park, Dong Jae;Kim, Seung Hyun;Park, Kyoung Tae;Mun, Jong Han;Lee, Hyuk Hee;Lee, Jong Hyeon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.13 no.1
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    • pp.11-19
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    • 2015
  • The production of nuclear fuel cladding tube is expected to increase with the nuclear power plant expansion. Zirconium(Zr) scrap that is generated during manufacturing is also expected to increase. Zr electrorefining experiment was carried out in the fluoride salt of LiF-KF-ZrF4 using multiple electrode for scale up and improving throughput Zr electrorefiner develop-ment. The Zr reduction peak observed at-0.8 V(vs.Ni). Polarization behavior showed that the amount of applied current increases because of decreasing cell resistance as the number of cathode increases. Experimental results showed the highest recovery rate about 98% at lowest current density of 25.64 mA/cm2 using 6 electrodes. XRD and TG analysis result show that pure Zr was recovered 99.92% and ICP analysis shows that lower impurity content than conventional impurity content of the Anode(97.8%). Electrorefining consumes energy about 7.15 kWh/kg less than 39.7% compared to the Kroll process using 6 electrode width of 20 mm and height of 65 mm. Because of increasing cell efficiency and recovery rate, using multiple cathode is determined as an efficient technique for scale up electrorefining Zr scrap.

Lactic acid and alcoholic fermentation of low-salted raw kanjang digestion liquor made from Bacillus subtilis var. globigii and Scopulariopsis brevicaulis inoculated meju (Bacillus subtilis var. globigii와 Scopulariopsis brevicaulis 접종메주로 단기숙성 저염생간장의 젖산 및 알콜발효)

  • Chung, Yeung-Gun;Choi, Choeng;Chung, Hyun-Chae;Im, Moo-Hyeog;Choi, Jong-Dong;Lee, Choon-Woo;Choi, Kwang-Soo
    • Applied Biological Chemistry
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    • v.41 no.6
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    • pp.405-409
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    • 1998
  • This work was carried out to investigate the behavior of sugars contained in raw soybean during cooking and meju preparation processes, and the effects of sugar addition to the raw kanjang digestion liquor made from G8 and SB meju on the lactic acid and alcoholic fermentation of kanjang. Sharp reduction in sugars content in soybean during cooking and meju preparation process was observed. Rapid lactic acid and alcoholic fermentation in the G8 and SB kanjang with 5% added glucose was observed but not in the corresponding kanjang without sugar addition after inoculation of Pediococcus halophilus, Zygosaccharomyces rouxii and Candida versatilis starter culture to the low-salted raw kanjang digestion liquor made respectively from G8 and SB meju. 0.46% and 0.88% of lactic acid and 1% and 2% of alcohol content in the G8 and SB kanjang respectively was observed 160 hours after the inoculation of the lactic acid bacteria starter culture.

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Feasibility of Stochastic Weather Data as an Input to Plant Phenology Models (식물계절모형 입력자료로서 확률추정 기상자료의 이용 가능성)

  • Kim, Dae-Jun;Chung, U-Ran;Yun, Jin-I.
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.14 no.1
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    • pp.11-18
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    • 2012
  • Daily temperature data produced by harmonic analysis of monthly climate summary have been used as an input to plant phenology model. This study was carried out to evaluate the performance of the harmonic based daily temperature data in prediction of major phenological developments and to apply the results in improving decision support for agricultural production in relation to the climate change scenarios. Daily maximum and minimum temperature data for a climatological normal year (Jan. 1 to Dec. 31, 1971-2000) were produced by harmonic analysis of the monthly climate means for Seoul weather station. The data were used as inputs to a thermal time - based phenology model to predict dormancy, budburst, and flowering of Japanese cherry in Seoul. Daily temperature measurements at Seoul station from 1971 to 2000 were used to run the same model and the results were compared with the harmonic data case. Leaving no information on annual variation aside, the harmonic based simulation showed 25 days earlier release from endodormancy, 57 days longer period for maximum cold tolerance, delayed budburst and flowering by 14 and 13 days, respectively, compared with the simulation based on the observed data. As an alternative to the harmonic data, 30 years daily temperature data were generated by a stochastic process (SIMMETEO + WGEN) using climatic summary of Seoul station for 1971-2000. When these data were used to simulate major phenology of Japanese cherry for 30 years, deviations from the results using observed data were much less than the harmonic data case: 6 days earlier dormancy release, 10 days reduction in maximum cold tolerance period, only 3 and 2 days delay in budburst and flowering, respectively. Inter-annual variation in phenological developments was also in accordance with the observed data. If stochastically generated temperature data could be used in agroclimatic mapping and zoning, more reliable and practical aids will be available to climate change adaptation policy or decision makers.

Biomechanical Efficacy of a Combined Flexible Cage with Pedicle Screws with Spring rods: A Finite Element Analysis (Spring rod를 사용한 척추경 나사못과 동반 시술된 Flexible cage의 생체역학적 효과)

  • Kim, Y.H.;Park, E.Y.;Kim, W.H.;Hwang, S.P.;Park, K.W.;Lee, Sung-Jae
    • Journal of Biomedical Engineering Research
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    • v.38 no.1
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    • pp.9-15
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    • 2017
  • Recently, flexible cages have been introduced in an attempt to absorb and reduce the abnormal load transfer along the anterior parts of the spine. They are designed to be used with the pedicle screw systems to allow some mobility at the index level while containing ROM at the adjacent level. In this study, a finite element (FE) study was performed to assess biomechanical efficacies of the flexible cage when combined with pedicle screws with flexible rods. The post-operated models were constructed by modifying the L4-5 of a previously-validated 3-D FE model of the intact lumbar spine (L2-S1): (1) Type 1, flexible cage only; (2) Type 2, pedicle screws with flexible rods; (3) Type 3, interbody fusion cage plus pedicle screws with rigid rods; (4) Type 4, interbody fusion cage plus Type 2; (5) Type 5, Type 1 plus Type 2. Flexion/extension of 10 Nm with a compressive follower load of 400N was applied. As compared to the Type 3 (62~65%) and Type 4 (59~62%), Type 5 (53~55%) was able to limit the motion at the operated level effectively, despite moderate reduction at the adjacent level. It was also able to shift the load back to the anterior portions of the spine thus relieving excessively high posterior load transfer and to reduce stress on the endplate by absorbing the load with its flexible shape design features. The likelihood of component failure of flexble cage remained less than 30% regardless of loading conditions when combined with pedicle screws with flexible rods. Our study demonstrated that flexible cages when combined with posterior dynamic system may help reduce subsidence of cage and degeneration process at the adjacent levels while effectively providing stability at the operated level.

A Bottom up Filtering Tuple Selection Method for Continuous Skyline Query Processing in Sensor Networks (센서 네트워크에서 연속 스카이라인 질의 처리를 위한 상향식 필터링 투플 선정 방법)

  • Sun, Jin-Ho;Chung, Chin-Wan
    • Journal of KIISE:Databases
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    • v.36 no.4
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    • pp.280-291
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    • 2009
  • Skyline Query processing is important to wireless sensor applications in order to process multi-dimensional data efficiently. Most skyline researches about sensor network focus on minimizing the energy consumption due to the battery powered constraints. In order to reduce energy consumption, Filtering Method is proposed. Most existing researches have assumed a snapshot skyline query processing and do not consider continuous queries and use data generated in ancestor node. In this paper, we propose an energy efficient method called Bottom up filtering tuple selection for continuous skyline query processing. Past skyline data generated in child nodes are stored in each sensor node and is used when choosing filtering tuple. We also extend the algorithms, called Support filtering tuple(SFT) that is used when we choose the additional filtering tuple. There is a temporal correlation between previous sensing data and recent sensing data. Thus, Based on past data, we estimate current data. By considering this point, we reduce the unnecessary communication cost. The experimental results show that our method outperforms the existing methods in terms of both data reduction rate(DRR) and total communication cost.

Fabrication and Characterization of Aluminum Honeycomb Panel (경량 알루미늄 허니콤 판재의 제작 및 특성 평가)

  • Kim, Kee Joo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.1
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    • pp.666-671
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    • 2018
  • A honeycomb panel is a plate made by attaching two surface plateson eitherside of a honeycomb core. The honeycomb plate hasexcellent specific strength and energy absorption and is suitable for use in regions where good impact resistance is required. Recently, with the increasing the need for a lightweight design to facilitate transportation, numerous studies have been conducted using aluminum honeycomb plates as body materials for vehicles such as automobiles and high-speed trains. In addition, honeycomb plates have excellent sound deadening properties, as well as excellent heat insulation and durability. Savings in weight using lightweight materials such as aluminum alloy for honeycomb panel's skin can lead to increase fuel economy and reduction in air pollution. In this study, in order to improve the design technology of the honeycomb plate material, the manufacturing technology of the aluminum honeycomb core and honeycomb plate material and various mechanical properties of the honeycomb plate were evaluated. From the results, it was found that the design of the manufacturing process of the aluminum honeycomb plate, as well as itsproduction and characteristics, were improved. The resulting excellent energy absorption capability of the honeycomb plate was due to the repetitive core buckling, indicating that the higher the compressive strength, the higher the strength per bonded area.

Behaviour of steel-fibre-reinforced concrete beams under high-rate loading

  • Behinaein, Pegah;Cotsovos, Demetrios M.;Abbas, Ali A.
    • Computers and Concrete
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    • v.22 no.3
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    • pp.337-353
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    • 2018
  • The present study focuses on examining the structural behaviour of steel-fibre-reinforced concrete (SFRC) beams under high rates of loading largely associated with impact problems. Fibres are added to the concrete mix to enhance ductility and energy absorption, which is important for impact-resistant design. A simple, yet practical non-linear finite-element analysis (NLFEA) model was used in the present study. Experimental static and impact tests were also carried out on beams spanning 1.3 meter with weights dropped from heights of 1.5 m and 2.5 m, respectively. The numerical model realistically describes the fully-brittle tensile behaviour of plain concrete as well as the contribution of steel fibres to the post-cracking response (the latter was allowed for by conveniently adjusting the constitutive relations for plain concrete, mainly in uniaxial tension). Suitable material relations (describing compression, tension and shear) were selected for SFRC and incorporated into ABAQUS software Brittle Cracking concrete model. A more complex model (i.e., the Damaged Plasticity concrete model in ABAQUS) was also considered and it was found that the seemingly simple (but fundamental) Brittle Cracking model yielded reliable results. Published data obtained from drop-weight experimental tests on RC and SFRC beams indicates that there is an increase in the maximum load recorded (compared to the corresponding static one) and a reduction in the portion of the beam span reacting to the impact load. However, there is considerable scatter and the specimens were often tested to complete destruction and thus yielding post-failure characteristics of little design value and making it difficult to pinpoint the actual load-carrying capacity and identify the associated true ultimate limit state (ULS). To address this, dynamic NLFEA was employed and the impact load applied was reduced gradually and applied in pulses to pinpoint the actual failure point. Different case studies were considered covering impact loading responses at both the material and structural levels as well as comparisons between RC and SFRC specimens. Steel fibres were found to increase the load-carrying capacity and deformability by offering better control over the cracking process concrete undergoes and allowing the impact energy to be absorbed more effectively compared to conventional RC members. This is useful for impact-resistant design of SFRC beams.

Treatment of Wastewater Containing Cu(II)-EDTA Using Ferrate in Sequencing Batch Scale System (연속회분식 반응 장치에서 Ferrate를 이용한 Cu(II)-EDTA 함유 폐수 처리 연구)

  • Kim, Hyoung-Uk;Kim, Byeong-Kwon;Lee, Seung-Mok;Yang, Jae-Kyu;Kim, Hyun-Ook;Kwan, Jung-An;Im, Hang-Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.7
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    • pp.729-734
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    • 2008
  • The higher valence state of iron i.e., Fe(VI) was employed for the treatment of Cu(II)-EDTA in the aqueous/waste waters. The ferrate(VI) was prepared through wet oxidation of Fe(III) by sodium hypochlorite. The purity of prepared Fe(VI) was above 93%. The stability of Fe(VI) solution decreased as solution pH decreased through self decomposition. The reduction of Fe(VI) was obtained by using the UV-Visible measurements. The dissociation of Cu(II)-EDTA complex through oxidation of EDTA using Fe(VI) and subsequent treatment of organic matter and metal ions by Fe(III) reduced from Fe(VI) in bench-scale of continuous flow reactor were studied. The removal efficiencies of copper were 69% and 79% in pH control basin and reactor, respectively, at 120 minutes as retention time. In addition, Cu(II)-EDTA in the reactor was decomplexated more than 80% after 120 minutes as retention time. From this work, a continuous treatment process for the wastewater containing metal and EDTA by employing Fe(VI) as muluti-functional agent was developed.