• Journal of the Korean Crystal Growth and Crystal Technology
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• v.13 no.3
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• pp.117-121
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• 2003

Nickel(Ni) powders were prepared from the mixture of nickel chloride and magnesium stearate by a hydrogen reduction process, and the effect of reaction temperature and the addition of magnesium stearate on the chracteristics of the powders were investigated. The effect of size reduction of nickel particles was observed in the presence of magnesium stearate owing to the inhibition of excess growth of paricles. The size reduction and the degree of agglomeration of the particles affected by the amounts of liqiud phase, which related to the increase of magnesium stearate.

• Journal of Institute of Control, Robotics and Systems
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• v.20 no.10
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• pp.1023-1029
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• 2014

In this paper, we propose an SPDR (Smith Predictor for Disturbance Reduction) scheme to improve the temperature control by reduction of the disturbance in ROT process with measurement delay. The proposed controller is a combination of Astrom's modified Smith predictor with a disturbance reduction controller and a grey predictor. The grey prediction is used to calculate the inverse of the measurement delay and to predict future variations and tendencies of system output. The simulation results demonstrate the successful performance of the proposed disturbance reduction controller and enhance the robustness of the proposed control scheme.

• Journal of Environmental Science International
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• v.12 no.1
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• pp.47-54
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• 2003

This paper have examined the optimum combination of SNCR and SCR by varying SNCR injection temperature and NSR ratio along with SCR space velocity. NOx reduction experiments using a SNCR/SCR combined process have been conducted in simple NO/NH$_3$/O$_2$ gas mixtures. Total gas flow rate was kept constant 4 liter/min throughout the SNCR and SCR reactors, where initial NOx concentration was 500 ppm in the presence of 5% O$_2$. Commercial catalyst, sulfated V$_2$O$\_$5/-WO$_3$/TiO$_2$, was used for SCR NOx reduction. The residence time and space velocity were around 1.67 sec, 2,400 h$\^$-1/ and 6,000 h$\^$-1/ in the SNCR and SCR reactors, respectively. SNCR NOx reduction effectively occurred in a temperature window of 900-950$^{\circ}C$. About 88% NOx reduction was achieved with an optimum temperature of 950$^{\circ}C$ and NSR=1.5. SCR NOx reduction using commercial V$_2$O$\_$5/-WO$_3$-SO$_4$/TiO$_2$ catalyst occurred in a temperature window of 200-450$^{\circ}C$ 80-98% NOxreduction was possible with SV=2400 h$\^$-1/ and a molar ratio of 1.0-2.0. A SNCR/SCR(SV=6000 h$\^$-1/) combined process has shown same NOx reduction compared with a stand-alone SCR(SV=2400 h$\^$-1/) unit process of 98% NOx reduction. The NH$_3$-based chemical could routinely achieve SNCR/SCR combined process total NOx reductions of 98% with less than 5 ppm NH$_3$ slip at NSR ranging from about 1.5 to 2.0, SNCR temperature of 900$^{\circ}C$-950$^{\circ}C$, and SCR space velocity of 6000 h$\^$-1/. Particularly, more than 98% NOx reduction was possible using the combined process under the conditions of T$\_$SNCR/=950$^{\circ}C$, T$\_$SCR/=350$^{\circ}C$, 5% O$_2$, SV=6000 h$\^$-1/ and NH$_3$/NOx=1.5. A catalyst volume was about three times reduced by SNCR/SCR combined process compared with SCR process under the same controlled conditions.

• Korean Journal of Metals and Materials
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• v.48 no.4
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• pp.315-319
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• 2010

In this study, the hydrogen reduction behavior of ball-milled NiO nanopowder was investigated depending on the partial pressure of water vapor. The hydrogen reduction behavior was analyzed by thermogravimetry and hygrometry under heating to 873 K in hydrogen. In order to change the partial pressure of the water vapor, the dew point of hydrogen was controlled in the range of 248 K~293 K by passing high-purity hydrogen through a saturator that contained water. Interestingly, with the increase in the dew point of the hydrogen atmosphere, the first step of the hydrogen reduction process decreased and the second step gradually increased. After the first step, a pore volume analysis revealed that the pore size distribution in the condition with a higher water vapor pressure shifted to a larger size, whereas the opposite appearedat a lower pressure. Thus, it was found that the decrease in the pore volume during the chemical reaction controlled process at a dew point of 248 K caused a reduction in retardation in the diffusion controlled process.

• Journal of Powder Materials
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• v.10 no.4
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• pp.270-274
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• 2003

Recently, the fabrication process of W-Cu nanocomposite powders has been researched to improve the sinterability by mechanochemical process (MCP), which consists of ball milling and hydrogen-reduction with W- and Cu-oxide mixture. However, there are many control variables in this process because the W oxides are hydrogen-reduced via several reduction stages at high temperature over 80$0^{\circ}C$ with susceptive reduction conditions. In this experiment, the W-15 wt%Cu nanocomposite powder was fabricated with the ball-milling and hydrogen-reduction process using W and CuO powder. The microstructure of the fabricated W-Cu nanocomposite powder was homogeneously composed of the fine W particles embedded in the Cu matrix. In the sintering process, the solid state sintering was certainly observed around 85$0^{\circ}C$ at the heating rate of 1$0^{\circ}C$/min. It is considered that the solid state sintering at low temperature range should occur as a result of the sintering of Cu phase between aggregates. The specimen was fully densified over 98% for theoretical density at 120$0^{\circ}C$ for 1 h with the heating rate of 1$0^{\circ}C$/min.

• Bulletin of the Korean Chemical Society
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• v.8 no.5
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• pp.414-418
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• 1987

Electrochemical reduction of dibenzoylmethane was studied on mercury electrode by means of cyclic voltammetry, polarography and potentiostatic measurements in ethanol-water system. In acidic solutions monomeric pinacol was produced by irreversible two-electron process while monomeric and dimeric pinacol were competitively produced by the same process in neutral solution. However, in basic solution the dimeric pinacol was mostly produced through radical by irreversible one-electron transfer process. Mechanisms of the reduction of dibenzoylmethane are deduced from Tafel slope, pH dependance and reaction order with respect to the concentration of dibenzoylmethane in the solution of various pH.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2007.05a
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• pp.127-130
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• 2007

Effect of the forging process parameters on the void crushing is the cogging process has been studied in order to find the most effective factor. The Process parameters used for this study are die width ratio, reduction ratio and pre-cooling time before cogging process. Void crushing analysis about the selected process parameters was carried out using FE analysis. The results of FE analysis were evaluated by Taguchi method. It was found that the efficiency of void crushing increases with an increase in the values of all selected process parameters and the principal factor controlling the void crushing was identified as the reduction ratio.

• Transactions of Materials Processing
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• v.16 no.7
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• pp.502-508
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• 2007

Effect of the process parameters of the cogging process on the void crushing has been studied in order to identify the most effective factor. The process parameters considered in this study are die width ratio, reduction ratio and pre-cooling time before cogging process. Void crushing analysis with the selected process parameters was carried out using FE analysis. The results of FE analysis were evaluated by Taguchi method. It was found that the efficiency of void crushing increases with an increase in the values of all selected process parameters and the principal factor controlling the void crushing was identified as the reduction ratio.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.13 no.7
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• pp.532-538
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• 2003

This paper studies on the noise reduction for a small automobile DC Motor (a window motor) using the 6 sigma process. The application of 6 sigma process suggested reliable and valuable statistical data for the quality of the DC motor at the production line. In the measurement step in 6 sigma process. the FMEA(failure mode effect analysis) were used for the detection of noise sources. The application of 6 sigma Process gave not only the improving method for the quality of the DC motor but also the confidence of improvement Itself since it was done on the basis of the test results for a number of DC motors at the production line. Consequently the 6 sigma process was proved very effective for the noise reduction at the production line.

• Transactions of Materials Processing
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• v.12 no.6
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• pp.558-565
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• 2003

Rotary swaging is one of the incremental forming process which is a chipless metal forming process for the reduction of cross-sections of bars, tubes and wires. In the present work, the rotary swaging machine and dies were designed to investigate the formability of TDS(Tube Drive Shaft) used in automotive industry. The process variables such as the speed of forming, the shape of the formed materials and the reduction of area were also estimated to study experimental analyses of rotary swaging process using the materials of 34Mn5 and S45C. From experimental results, it was found that the process variables affected the quality of TDS in terms of hardness, the precision of products and the surface roughness. The hardness after swaging approved to be Increased with the increase in the reduction of diameter. And it was found that the grain size became smaller and the elongated grains were formed in the axis direction.