• Title/Summary/Keyword: Reduction of NO

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Unified Modeling and Performance Prediction of Diesel $NO_x$ and PM Reduction by DOC-DPF-SCR System (DOC-DPF-SCR 시스템에 의한 디젤 배기 내 $NO_x$, 입자상 물질 저감 과정의 일관 모델링 및 성능 예측)

  • Jung, Seung-Chai;Yoon, Woong-Sup
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.4
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    • pp.110-119
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    • 2008
  • Computer methods with simplified mathematical models in conjunction with empirical model parameters can be efficiently practiced into an optimization of a diesel aftertreatment system. Components of prime interests are diesel particulate filter, diesel oxidation catalyst and de-$NO_x$ catalytic converter. de-$NO_x$, de-PM, and de-HC processes in each part are individually modeled, formulated and then combined into an integrated analysis procedure for a unified simulation of the diesel emission aftertreatment. The model is empirically tuned and validated with comprehensive engine and laboratory data. The effects of emission species and space velocity on the $NO_x$ and soot reductions are parametrically investigated. A lowered $NO_2/NO_x$ ratio due to PM oxidation in DPF contributes to promote the $NO_x$ reduction by SCR at intermediate gas temperatures. $NO_x$ reduction is inert to the PM oxidation at high temperatures. Rate of PM trapping strongly depends on temperature and $NO_x$ concentration.

Comparison Study of Open Reduction and Closed Reduction in Treatment of Mandibular Subcondylar Fractures (하악골 과두하부골절 정복술에서 관혈적 정복술과 비관혈적 정복술의 비교 연구)

  • Jang, Ju Yun;Kang, Dong Hee
    • Archives of Craniofacial Surgery
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    • v.9 no.2
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    • pp.51-54
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    • 2008
  • Purpose: The choice of open versus closed reduction for mandibular subcondylar fracture is a debatable issue. To evaluate the advantage of open approach to closed method with IMF(intermaxillary fixation), we conducted a retrospective study to compare the outcomes of each method. Methods: From 2002 to 2006, 29 patients with mandibular subcondylar fractures were treated by open or closed reduction. 17 patients were treated by open reduction and 12 patients by closed reduction and IMF. Each group was assessed for duration of mandibular immobilization, incidences of buccal palsy, malocclusion, TMJ(temporomandibular joint) pain, and deviation of the mandible on mouth opening. Results: All cases showed accurate reduction in anatomical position, no significant displacement and no deviation on mouth opening during the follow-up period. IMF period is statistically shorter in open reduction (p<0.05). Differences in incidence of other complications were not significant statistically. Conclusion: As there are significant independent morbidities associated with IMF which requires postoperative rehabilitation, prolonged temporomandibular immobilization should not be overlooked. Some patients with poor compliances will not tolerate IMF in nonsurgical treatment. In the aspect of patient's convenience and early recovery by short IMF period, open reduction would be recommended as a better treatment method.

Experimental Study on Flame Stabilization and $NO_{x}$ Reduction in a Non-Premixed Burner with Sawtooth Mixer

  • Fujimoto, Yohei;lnokuchi, Yuzo;Orino, Minoru;Yamasaki, Nobuhiko
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.03a
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    • pp.485-490
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    • 2004
  • Sawtooth mixing device used in a non-premixed burner is evaluated for flame stabilization and NO$_{x}$ reduction. Three mixers with different blade angles are tested. Methane is delivered through the fuel jet and air passes through the co-flow annulus. The flame mode changes (attached flame, lifted flame and extinction) against the fuel flow speed are measured, and the stability diagram is drawn. Moreover, by traversing thermocouple and sampling probe in the flame, the distribution of temperature and NO$_{x}$ mole fraction are measured. With the change in blade angle, flame shape, flame stabilization, the distribution of temperature and NO$_{x}$ mole fraction are changed considerably.rably.

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Effect of Nitrate on Iron Reduction and Phosphorus Release in Flooded Paddy Soil (논토양에서 질산 이온이 철의 환원과 인의 용출에 미치는 영향)

  • Chung, Jong-Bae
    • Korean Journal of Environmental Agriculture
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    • v.28 no.2
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    • pp.165-170
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    • 2009
  • The increase in P availability to rice under flooded soil conditions involves the reductive dissolution of iron phosphate and iron (hydr)oxide phosphate. However, since $NO_3^-$ is a more favourable electron acceptor in anaerobic soils than Fe, high$NO_3^-$ loads function as a redox buffer limiting the reduction of Fe. The effect of adding $NO_3^-$ on Fe reduction and P release in paddy soil was investigated. Pot experiment was conducted where $NO_3^-$ was added to flooded soil and changes of redox potential and $Fe_2^+$, $NO_3^-$ and $PO_4^{3-}$ concentrations in soil solution at 10 cm depth were monitored as a function of time. Redox potential decreased with time to -96 mV, but it was temporarily poised at about 330${\sim}$360 mV when $NO_3^-$ was present. Nitrate addition to soil led to reduced release of $Fe_2^+$ and prevented the solubilization of P. Phosphate in pore water began to rise soon after incubation and reached final concentrations about 0.82 mg P/L in the soil without $NO_3^-$ addition. But, in the soil with $NO_3^-$ addition, $PO_4^{3-}$ in pore water was maintained in the range of 0.2${\sim}$0.3 mg P/L. The duration of inhibition in $Fe_2^+$ release was closely related to the presence of $NO_3^-$, and the timing of $PO_4^{3-}$ release was inversely related to the $NO_3^-$ concentration in soil solution. The results suggest that preferential use of $NO_3^-$ as an electron acceptor in anaerobic soil condition can strongly limit Fe reduction and P solubilization.

The Effects of Advanced Reburning with SNCR on NOx and CO Reduction (무촉매 환원법이 적용된 응용 재연소 방법에 의한 NOx와 CO의 저감 효과)

  • Lee Chang-Yeop;Kim Dong-Min;Baek Seung-Wook
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.8 s.251
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    • pp.788-795
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    • 2006
  • From the view of the environmental protection against the use of fossil fuels, the great of efforts have been exerted to find an effective method which is not only pollutant reduction but also high thermal efficiency. Reburning is a useful technology in reducing nitric oxide through injection of a secondary hydrocarbon fuel. In this paper, an experimental study has been conducted to evaluate the hybrid effects of reburning and selective non-catalytic reaction (SNCR) on $NO_x/CO$ reduction from oxygen-enriched LPG flame. Experiments were performed in flames stabilized by a co-flow swirl burner, which was mounted at the bottom of the furnace. Tests were conducted using LPG gas as main fuel and also as reburn fuel. The paper reported data on flue gas emissions, temperature distribution in furnace and various heat fluxes at the wall for a wide range of experimental conditions. Overall temperature in the furnace, heat fluxes to the wall and $NO_x$ generation were observed to increase by oxygen-enriched combustion, but due to its hybrid effects of reburning and SNCR, $NOx/CO$ concentration in the downstream has considerably decreased.

Conversion of NOx by Plasma-hydrocarbon Selective Catalytic Reduction Process (플라즈마-탄화수소 선택적 촉매환원공정을 이용한 질소산화물 저감 연구)

  • Jo, Jin-Oh;Mok, Young Sun
    • Applied Chemistry for Engineering
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    • v.29 no.1
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    • pp.103-111
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    • 2018
  • A plasma-catalytic combined process was used as an attempt to improve the conversion efficiency of nitrogen oxides ($NO_x$) over a wide temperature range ($150{\sim}500^{\circ}C$) to cope with the exhaust gas whose temperature varies greatly. Since the catalytic $NO_x$ reduction is effective at high temperatures where the activity of the catalyst itself is high, the $NO_x$ reduction was carried out without plasma generation in the high temperature region. On the other hand, in the low temperature region, the plasma was created in the catalyst bed to make up for the decreased catalytic activity, thereby increasing the $NO_x$ conversion efficiency. Effects of the types of catalysts, the reaction temperature, the concentration of the reducing agent (n-heptane), and the energy density on $NO_x$ conversion efficiency were examined. As a result of comparative analysis of various catalysts, the catalytic $NO_x$ conversion efficiency in the high temperature region was the highest in the case of the $Ag-Zn/{\gamma}-Al_2O_3$ catalyst of more than 90%. In the low temperature region, $NO_x$ was hardly removed by the hydrocarbon selective reduction process, but when the plasma was generated in the catalyst bed, the $NO_x$ conversion sharply increased to about 90%. The $NO_x$ conversion can be maintained high at temperatures of $150{\sim}500^{\circ}C$ by the combination of plasma in accordance with the temperature change of the exhaust gas.

Secondary reduction mammaplasty using different pedicle from the initial pedicle : Report of two cases (일차 수술과 다른 혈관경을 이용한 이차 유방 축소술: 증례 보고)

  • Kim, Kyu Nam;Lee, Taik Jong;Kim, Eun Key;Kim, Tae Gon
    • Archives of Plastic Surgery
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    • v.36 no.6
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    • pp.784-787
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    • 2009
  • Purpose: Reduction mammaplasty is one of the most commonly performed operations in plastic surgery. Although secondary surgery is occasionally required for minor aesthetic problems or for treatment of the complications of the primary surgery, there are no clear operative guidelines of management. We report here two cases of secondary reduction mammaplasty using differrent pedicle from the initial ones. Methods: One case of secondary reduction mammaplasty were performed using medial pedicle after central (19 years) pedicle reduction mammaplasty because of subsequent breast ptosis and asymmetry. The other case were performed using medial pedicle after superior (4 years) pedicle reduction mammaplasty with contralateral immediate breast reconstruction with TRAM flap because of subsequent breast ptosis and asymmetry. Care was taken to include sufficient width of pedicle and adequate soft tissue attachment beneath the nipple - areolar complex. Results: There was no significant complication such as nipple - areolar necrosis or fat necrosis. The results were well maintained throughout the follow - up period. Conclusion: Medial pedicle reduction mammaplasty can be safely performed after central or superior pedicle reduction mammaplasty when sufficient width of pedicle and adequate soft tissue attachment beneath the nipple - areolar complex are maintained.

Analysis of Clinical Factors and Operative Findings in Childhood Intussusception (소아 장중첩증에서 임상양상과 수술소견과의 관계에 관한 분석)

  • Choi, Kum-Ja
    • Advances in pediatric surgery
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    • v.2 no.2
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    • pp.81-87
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    • 1996
  • Although nonoperative reduction plays a major role in the management of uncomplicated intussusception in the pediatric age group, surgical treatment is still a necessary alternative when nonoperative reduction is unsuccessful. The author analyzed the clinical features of 68 patients requiring operation in order to identify factors which might influence the type of operative management. A nine-year experience at Ewha Womans University Hospital was reviewed, and the findings compared to previous reports. Barium was used for the initial reduction attempt in 33 cases, saline in 35. Manual reduction by milking at operation achieved success in 41 cases(60.3%). Fifteen cases(22.1%) required resection of bowel, and 12 patients(17.6%) were found to have spontaneous and complete reduction of the intussusception at operation. Two cases had pathologic leading points. There were no perforations due to nonoperative reduction. There were no significant differences in demographic data, clinical findings, laboratory data, and anatomic type of intussusception between barium and saline reduction groups. However, a significant number of cases with spontaneous reduction were in saline reduction group(p<0.05). There was a slight chance of spontaneous reduction in infants under 6 month of age(p<0.001). Age under 6 month. body temperature over $38^{\circ}C$, symptom over 24 hours, and ileo-colic and ileo-ileo-colic intussusception contributed significantly to the necessity for bowel resection(p<0.05-0.001). The author believes that the age, body temperature, duration of illness, and anatomic type of intussusception strongly influence operative management.

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Experiment on Low $NO_x$ Combustion Characteristics by Flue Gas Dilution In Air and Fuel Sides (공기 및 연료에 대한 배기가스 희석 방법에 의한 저 $NO_x$ 연소특성에 관한 실험)

  • Cho, Eun-Seong;Chung, Suk-Ho
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.1499-1504
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    • 2004
  • Flue gas recirculation (FGR) is a method used to control oxides of nitrogen ($NO_x$) in combustion system. The recirculated flue gases resulted in slow reaction and low flame temperatures, which in turn resulted in decreased thermal NO production. Recently, it has been demonstrated that introducing the recirculated flue gas in the fuel stream, that is, the fuel induced recirculation (FIR), resulted in a much greater reduction in $NO_x$ per unit mass of recirculated gas, as compared to introducing the flue gases in air. In the present study, the effect on $NO_x$ reduction in turbulent swirl flame in laboratory scale using FGR/FIR methods through the dilution using $N_2$ and $CO_2$. Results. show the $CO_2$ dilution is more effective $NO_x$ reduction methods because of large temperature drop due to the larger specific heat $CO_2$ compared to $N_2$. FIR is more effective to reduce $NO_x$ emission than FGR when the same recirculation ratio of dilution gas.

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Effect of $CO_2$ Addition on Flame Structure and NOx Formation of $CH_4-Air$ Counterflow Diffusion Flames ($CO_2$ 첨가가 $CH_4$-공기 대향류 확산화염의 구조 및 NOx 생성에 미치는 영향)

  • Lee, S.R.;Han, J.W.;Lee, C.E.
    • Journal of the Korean Society of Combustion
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    • v.4 no.2
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    • pp.97-108
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    • 1999
  • This numerical study was to investigate the effect of $CO_2$ addition on the structures and NOx formation characteristics in $CH_4$ counterflow diffusion flame. The importance of radiation effect was identified and $CO_2$ addition effect was investigated in terms of thermal and chemical reaction effect. Also the causes of NOx reduction were clarified by separation method of each formation mechanisms. The results were as follows : The radiation effect was intensified by $CO_2$ addition. Thermal effect mainly contributed to the changes in flame structure and the amount of NO formation but the chemical reaction effect also cannot be neglected. The reduction of thermal NO was dominant with respect to reduction rate, but that of prompt NO was dominant with respect to total amount.

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