• 제목/요약/키워드: Reduction behavior

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Hydrogen Reduction Behavior of Oxide Scale in Water-atomized Iron Powder (수분사 Fe 분말의 산화물 및 이의 수소가스 환원거동)

  • Shin, Hea-Min;Baik, Kyeong-Ho
    • Journal of Powder Materials
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    • v.21 no.6
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    • pp.422-428
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    • 2014
  • In this study, the reduction kinetics and behaviors of oxides in the water-atomized iron powder have been evaluated as a function of temperature ranging $850-1000^{\circ}C$ in hydrogen environment, and compared to the reduction behaviors of individual iron oxides including $Fe_2O_3$, $Fe_3O_4$ and FeO. The water-atomized iron powder contained a significant amount of iron oxides, mainly $Fe_3O_4$ and FeO, which were formed as a partially-continuous surface layer and an inner inclusion. During hydrogen reduction, a significant weight loss in the iron powder occurred in the initial stage of 10 min by the reduction of surface oxides, and then further reduction underwent slowly with increasing time. A higher temperature in the hydrogen reduction promoted a high purity of iron powder, but no significant change in the reduction occurred above $950^{\circ}C$. Sequence reduction process by an alternating environment of hydrogen and inert gases effectively removed the oxide scale in the iron powder, which lowered reduction temperature and/or shortened reduction time.

The Hydrogen Reduction Behavior of MoO3 Powder (MoO3 분말의 수소환원거동)

  • Koo, Won Beom;Yoo, Kyoungkeun;Kim, Hanggoo
    • Resources Recycling
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    • v.31 no.1
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    • pp.29-36
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    • 2022
  • The hydrogen reduction behavior of molybdenum oxides was studied using a horizontal-tube reactor. Reduction was carried out in two stages: MoO3 → MoO2 and MoO2 → Mo. In the first stage, a mixed gas composed of 30 vol% H2 and 70 vol% Ar was selected for the MoO3 reduction because of its highly exothermic reaction. The temperature ranged from 550 to 600 ℃, and the residence time ranged from 30 to 150 min. In the second step, pure H2 gas was used for the MoO2 reduction, and the temperature and residence time ranges were 700-750 ℃ and 30-150 min, respectively. The hydrogen reduction behavior of molybdenum oxides was found to be somewhat different between the two stages. For the first stage, a temperature dependence of the reaction rate was observed, and the best curve fittings were obtained with a surface reaction control mechanism, despite the presence of intermediate oxides under the conditions of this study. Based on this mechanism, the activation energy and pre-exponential were calculated as 85.0 kJ/mol and 9.18 × 107, respectively. In addition, the pore size within a particle increases with the temperature and residence time. In the second stage, a temperature dependence of the reaction rate was also observed; however, the surface reaction control mechanism fit only the early part, which can be ascribed to the degradation of the oxide crystals by a volume change as the MoO2 → Mo phase transformation proceeded in the later part.

Studies on the Aging Behavior of Coated Paper(I) -Effect of latex on optical properties of coated paper during dry heat aging- (도공지 노화에 관한 연구(I) - 도공지 강제열화 시 라텍스가 도공지의 광학적 특성에 미치는 영향 -)

  • Kim, Sun-Kyung;Cho, Byoung-Uk;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.1
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    • pp.11-16
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    • 2011
  • This study was carried out in order to elucidate the effect of latex dosage and properties on aging behavior of coated paper. The coated paper with five different coating formulations were prepared and also four different latices were used. The coated paper were thermally aged at $105^{\circ}C$ for 14 days and the optical properties were measured. Increasing latex content increased the magnitude of reduction in brightness and whiteness. In addition, the variations in CIE a$^*b^*$ were larger with increasing latex dosage. Latex which has the lower gel content and the higher Tg showed the higher reduction in brightness and whiteness and much variation in CIE a$^*b^*$. However the particle size of latex didn't affect to thermal behavior of coated paper. These results indicate that latex which has higher Tg and lower gel content is the one of the main factors affecting aging behavior of coated paper.

Factors Influencing the Drinking Behavior in Female University Students (여대생의 음주행위에 영향을 미치는 요인)

  • Ryu, Hyun-Sook;Baek, Min-Ja
    • Research in Community and Public Health Nursing
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    • v.23 no.3
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    • pp.307-315
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    • 2012
  • Purpose: The purpose of this study was to identify the factors influencing the alcohol drinking behavior in female university students. Methods: The subjects were 298 female university students at three universities in J Province and G city. Data were collected using a structured questionnaire and analyzed by SPSS/PC+ 15.0. Results: The variables that affected the drinking behavior of female university students were smoking status, pocket money, coping strategy of problem solving, positive expectancy of alcohol drinking and negative expectancy of alcohol drinking. These factors could explain 30.4% of the drinking behavior. Stress did not affect the drinking behavior of subjects. Conclusion: Drinking behavior of the subjects was slightly higher than average for all women. In order to decrease the drinking behavior, the development of drinking reduction programs is needed and it can lead healthy life for female university students.

The Effect of Sodium Reduction Education Program of a Public Health Center on the Blood Pressure, Blood Biochemical Profile and Sodium Intake of Hypertensive Adults (고혈압 환자 대상 저나트륨 식생활에 대한 보건소 영양교육이 혈압, 혈액 성상 및 나트륨섭취에 미치는 영향)

  • Jung, Eun Jin;Son, Sook Mee;Kwon, Jong-Sook
    • Korean Journal of Community Nutrition
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    • v.17 no.6
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    • pp.752-771
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    • 2012
  • This study was conducted to investigate the effect of sodium reduction education program of a public health center on the blood pressure, blood biochemical profile and sodium intake of hypertensive adults. The program continued for 16 weeks with an 8-week nutrition education and an 8-week follow-up to forty two subjects, 6 males and 36 females aged 46 to 80 years. Subjects received nutrition education including lectures, activities, cooking classes and nutrition counseling. Physical fitness, management of stress, and nutrition counseling were provided during the follow-up. The program was evaluated three times, before and after the nutrition education, and after the follow-up. Systolic blood pressure (p < 0.0001) and diastolic blood pressure (p < 0.001) were decreased after completion of the program. Body weight (p < 0.005), percent body fat (p < 0.005) and body mass index (p < 0.001) were decreased, too. There were no significant differences in blood glucose, HDL-cholesterol and triglycerides, while elevated levels of total cholesterol (p < 0.001) and LDL-cholesterol (p < 0.001) appeared after the program completion. Decreased intakes of vitamin A (p < 0.05), ${\beta}$-carotene (p < 0.001) and sodium (p < 0.001) were observed. Consumption frequency of noodles, soups, stews, kimchi, fishes/shellfish, seasoned vegetables, and salted seafoods/pickles (p < 0.05~p < 0.001) were decreased, while that of all food groups were not changed during the follow-up. Total score of nutrition knowledge related to sodium intake and hypertension (p < 0.001), and that of dietary behavior associated with high sodium intakes were changed positively (p < 0.001) only during the nutrition education. This sodium reduction education program, including the follow-up study showed positive effects on the blood pressure, sodium intake, nutrition knowledge and dietary behavior of hypertensive adults.

Soil structure interaction effects on strength reduction factors

  • Eser, Muberra;Aydemir, Cem;Ekiz, Lbrahim
    • Structural Engineering and Mechanics
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    • v.41 no.3
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    • pp.365-378
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    • 2012
  • In this study, strength reduction factors are investigated for SDOF systems with period range of 0.1-3.0 s with elastoplastic behavior considering soil structure interaction for 64 different earthquake motions recorded on different site conditions such as rock, stiff soil, soft soil and very soft soil. Soil structure interacting systems are modeled and analyzed with effective period, effective damping and effective ductility values differing from fixed-base case. For inelastic time history analyses, Newmark method for step by step time integration was adapted in an in-house computer program. Results are compared with those calculated for fixed-base case. A new equation is proposed for strength reduction factor of interacting system as a function of structural period of system (T), ductility ratio (${\mu}$) and period lengthening ratio (T/T). It is concluded that soil structure interaction reduces the strength reduction factors for soft soils, therefore, using the fixed-base strength reduction factors for interacting systems lead to non-conservative design forces.

The Effects of the Risk Reduction Behavior and the Choice Attribute on the Fund Investment Behaviors (펀드 위험감소행동과 선택속성이 펀드투자행동에 미치는 영향)

  • Jang, Boo Yeon;Ha, Kyu Soo
    • Asia-Pacific Journal of Business Venturing and Entrepreneurship
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    • v.10 no.3
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    • pp.161-170
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    • 2015
  • Recently the fund has been popular for the representative financial investment. In the decision making procedure of the investor about this fund investment, this research analyze how the factor was considered as fund investing behavior. The paper examines investors' risk reduction behavior and fund choice attribution for fund investment behavior, provides insight for marketing strategy in fund market for fund investment behavior. The period for the survey is from December 2014 to January 2015 and analyzed 431 samples of using a fund investor The research results showed that fund distribution, fund literacy and fund performance appeared to be statistically significant variables that positive affected fund investment satisfaction, but fund advertise negative affected fund investment satisfaction. Also, the fund management company, benefit, fund literacy, fund performance, and recommend appeared to be statistically significant variables that positive affected fund investment intention. It is expected that fund marketing strategy based on research return should be established to cope with the fund literacy as well as the fund investing behavior. Concretely to fund investment satisfaction make informed decision in fund performance, fund information provided to investor should be customized to contribute the improvement of overall fund literacy.

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Analysis of AM and AEM Oxides Behavior in a SF Electrolytic Reduction Process (사용후핵연료 전기환원 공정에서의 알카리, 알카리토 금속 산화물들의 거동 분석)

  • 박병흥;강대승;서중석;박성원
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.268-277
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    • 2004
  • process (ACP), electrochemical properties of high heat-generating alkali and alkali earth oxides in molten salt were measured and the behavior of those elements were analyzed. The reduction potentials of Cs, Sr, and Ba in a molten LiCl-$Li_2O$ system were more cathodic than that of Li and closely located one another. Thus, it is expected that the alkali and alkali earth would not hinder the reaction mechanism which is via lithium reduction. Alkali and alkali earth metals are likely to recycle into molten salt when the process is operated beyond metal reduction potentials and the effect of electric current on the mass transport is also determined by measuring the metal concentrations in the molten salt phase at different current conditions.

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