• Title/Summary/Keyword: Reduction Unit

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Electropolymerization Mechanism for Poly(o-phenylenediamine) (PPD) and Its Electrocatalytic Behavior for $O_2$ Reduction

  • Jang, Dong Hun;Yu, Yong Seop;O, Seung Mo
    • Bulletin of the Korean Chemical Society
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    • v.16 no.5
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    • pp.392-397
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    • 1995
  • o-Phenylenediamine (o-PD) was electropolymerized on glassy carbon electrodes under a potential cycling condition. The resulting polymer films mediated electrons for the reduction of molecular oxygen at pH=1.0. It was found from the RDE, RRDE, and cyclic voltammetry experiments that the modified electrodes reduce oxygen to hydrogen peroxide at about 300 mV lower potential than the bare glassy carbon electrode. The polymer film consisted of more than two components. Among those, only one component was active in oxygen reduction, which was formed mainly in the earlier stage of the electropolymerization. 2,3-Diaminophenazine, a cyclic dimer of o-PD, was also active in the oxygen reduction reaction, from which it was suggested that the active polymeric component has a structural unit similar to the cyclic dimer. Finally, the electropolymerization mechanism for the formation of the active and inactive components has been proposed.

Preparation of α-Linked 6-Deoxy-D-altro-heptopyranosidic Residues

  • 신영숙;천근호;Shin, E. Nam;Gerald O. Aspinall
    • Bulletin of the Korean Chemical Society
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    • v.16 no.7
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    • pp.625-630
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    • 1995
  • α-Linked D-altropyranosidic derivatives were obtained by configurational change at C-3 of α-D-mannopyranosides as the key step in preparation of allyl and methyl α-D-glycopyranosides of 6-deoxy-D-altro-heptose. The manno-altro conversion was effected by sequential reactions of Swern oxidation and stereoselective borohydride reduction. Allyl 4,6-O-benzylidene-2-O-p-methoxybenzyl-α-D-mannopyranoside was transformed to the corresponding altropyranoside via 3-oxo-arabino-hexopyranoside. Allyl 7-O-benzyl-6-deoxy-3,4-O-isopropylidene-α-D-altro-heptopyranoside has been prepared as a glycosyl acceptor to be coupled with β-D-GlcpNAc-(1→3)-α-D-Galp glycosyl donor for the synthesis of an O-antigen repeating unit of Campylobacter jejuni serotypes O:23 and O:36. Stereoselective borohydride reduction also succeeded in yielding methyl 2,4,7-tri-O-benzyl-6-deoxy-α-D-altro-heptopyranoside from the corresponding 3-oxo-α-D-arabino-heptopyranoside. C-6 Homologation was achieved by sequential reactions of cyanide displacement of 6-sulphonates, reduction of the resulting heptopyranosidurononitrile with diisobutylaluminum hydride, hydrolysis of the imine, and further reduction with sodium borohydride.

BLOCK-BASED ADAPTIVE BIT ALLOCATION FOR REFENCE MEMORY REDUCTION

  • Park, Sea-Nae;Nam, Jung-Hak;Sim, Dong-Gy;Joo, Young-Hun;Kim, Yong-Serk;Kim, Hyun-Mun
    • Proceedings of the Korean Society of Broadcast Engineers Conference
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    • 2009.01a
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    • pp.258-262
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    • 2009
  • In this paper, we propose an effective memory reduction algorithm to reduce the amount of reference frame buffer and memory bandwidth in video encoder and decoder. In general video codecs, decoded previous frames should be stored and referred to reduce temporal redundancy. Recently, reference frames are recompressed for memory efficiency and bandwidth reduction between a main processor and external memory. However, these algorithms could hurt coding efficiency. Several algorithms have been proposed to reduce the amount of reference memory with minimum quality degradation. They still suffer from quality degradation with fixed-bit allocation. In this paper, we propose an adaptive block-based min-max quantization that considers local characteristics of image. In the proposed algorithm, basic process unit is $8{\times}8$ for memory alignment and apply an adaptive quantization to each $4{\times}4$ block for minimizing quality degradation. We found that the proposed algorithm could improve approximately 37.5% in coding efficiency, compared with an existing memory reduction algorithm, at the same memory reduction rate.

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Comparing Carbon Reduction Estimates for Tree Species from Different Quantitative Models

  • Hyun-Kil Jo;Hye-Mi Park
    • Journal of Forest and Environmental Science
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    • v.39 no.3
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    • pp.119-127
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    • 2023
  • In this study, quantitative models were applied to case parks to estimate the carbon reduction by trees, which was compared and analyzed at the tree and park levels. At the tree level, quantitative models of carbon storage and uptake differed by up to 7.9 times, even for the same species and size. At the park level, the carbon reduction from quantitative models varied by up to 3.7 times for the same park. In other words, carbon reduction by quantitative models exhibited considerable variation at the tree and park levels. These differences are likely due to the use of different growth environment coefficients and annual diameter at breast height growth rates and the overestimation of carbon reduction due to the substitution of the same genus and group model for each tree species. Extending the annual carbon uptake per unit area of the case park to the total park area of Chuncheon a carbon uptake ranging from a minimum of 370.4 t/yr and a maximum of 929.3 t/yr, and the difference can reach up to 558.9 t/yr. This is equivalent to the carbon emissions from the annual household electricity consumption of approximately 2,430 people. These results suggest that the indiscriminate application of quantitative models to estimate carbon reduction in urban trees can lead to significant errors and deviations in estimating carbon storage and uptake in urban greenspaces. The findings of this study can serve as a basis for estimating carbon reduction in urban greening research, projects, and policies.

Insecticidal Efficacy of Porteresia coarctata (Roxb.) on Bio-chemical Alteration of Spodoptera litura (Fab.)

  • Bhattacharyya Atanu;Goswami Arunava;Dihidar Shankar;Adhikari Sujit;Banerjee Sudip Kumar;Talapatra Soumendra Nath;Barik Bikas Ranjan;Bhattacharya Subir Kumar;Chandra Asit Kumar
    • International Journal of Industrial Entomology and Biomaterials
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    • v.14 no.1
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    • pp.9-13
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    • 2007
  • Hexane extract of Porteresia coarctata (Roxb.) exhibits a toxic effect on the tissues of Spodoptera litura (F) while fed at the dose of 1000 and 2000 ppm thoroughly mixing with castor leaves (Ricinus communis L) after dissolving in DMSO at late fourth instar whereas only DMSO treated castor leaves were fed to control group. The larvae were put to rear at $28^{\circ}C{\pm}1^{\circ}C$, $76{\pm}4%$ R.H. under 12 L + 12 D photoperiodic regime. In test group insects substantial reduction of protein and DNA content was marked in fat body and midgut tissues compared to DMSO treated control group. The significant biochemical alterations in the midgut tissues and fat body of test group insects indicate the insecticidal property of the said plant extract that could be tested in facilitating the phenomenal stride in Integrated Pest Management.

Experience of Surgical Treatment through Ambulatory Care Unit (일 병원에서 통원병실을 이용한 수술적 치료의 경험)

  • Sohn, Jong-Min;Ha, Nan-Kyung
    • Quality Improvement in Health Care
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    • v.8 no.1
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    • pp.84-94
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    • 2001
  • Background : in order to adapt to changes of the medical environm interests that is drawn in ambulatory surgery are increased as a method of approaching a patients' satisfaction and cost-effective management. The purpose of this study is to a assess the operation which is able to perform through ambulatory care unit, to identify the problem in ambulatory surgery, and to increased the opportunity of ambulatory surgery with safety. Methods : Between May 13th, 1998 and June 30th, 2000, we performed surgical treatment through ambulatory care unit, and evaluate the results of them. The sorts of operation, duration of stay in the hospital, total cost of treatment, satisfaction of patients and safety if anesthesia were assessed. Results : We performed ambulatory surgery without serve complications and the patients were satisfied with surgical treatment through ambulatory care unit. In comparison of ambulatory and admission surgery, there was a reduction of cost to 16.7~25.3% in ambulatory surgery. Also, the duration of admission was 2 days shorter than admission surgery. Conclusions : According to our results, the surgical treatment through ambulatory care unit is safe and useful method that increase the quality of medical service, satisfaction of patients and reduce the cost of treatments.

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Structure and Antibiotic Activity of a Porcine Myeloid Antibacterial Peptide, PMAP-23 and its Analogues

  • Shin, Song-Yub;Kang, Joo-Hyun;Jang, So-Yun;Kim, Kil-Lyong;Hahm, Kyung-Soo
    • BMB Reports
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    • v.33 no.1
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    • pp.49-53
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    • 2000
  • PMAP-23 is a 23-residue antimicrobial peptide derived from porcine myloid cells. In order to investigate the effects of two Pro residues at positions 12 and 15 of PMAP-23 on antibiotic activity, two analogues in which Ala was substituted for Pro residue at position 12 or 15 were synthesized. $Pro^{12}{\rightarrow}Ala$ (PMAPl) or $Pro^{15}{\rightarrow}Ala$(PMAP2) substitution in PMAP-23 caused a significant reduction on antitumor and phospholipid vesicle-disrupting activities, but did not cause a significant effect on antibacterial activity. PMAP-23 displayed the type I ${\beta}-turn$ structure with a negative ellipticity at near 205 om in SDS micelle, whereas PMAP1 and PMAP2 had a somewhat ${\alpha}-helical$ propensity in TFE solution, as compared to PMAP-23. These results suggest that two Pro residues of positions 12 and 15 in PMAP-23 play important roles in the formation of ${\beta}-turn$ structure on lipid membrane and its ${\beta}-turn$ structure may be essential for antibiotic activity including phospholipid vesicle-disrupting property.

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Improvement Method of the Sound Insulation Performance of Aluminium Extruded Panels by the Unit Structure Modification (단위 구조 변경에 의한 알루미늄 압출재의 차음성능 개선)

  • Lee, Hyun-Woo;Kim, seock-Hyun;Kim, Jeong-Tae;Song, Dal-Ho
    • Proceedings of the KSR Conference
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    • 2009.05b
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    • pp.457-462
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    • 2009
  • In a high speed train, aluminium extruded panel is widely used in floor, side wall and roof structures for high bending stiffness and weight reduction. However, with some inevitable reasons, aluminium extruded panel shows inferior sound insulation performance compared with the flat panel having same weight. Especially, occurrence of local resonance modes in the particular frequency band, is one of the main reason in the deterioration of the sound insulation performance. Local resonance modes are generated in the structure which consists of periodic unit structure, such as the aluminium extruded panel. The local resonance frequency is determined by the specification of the unit structure. In this study, we predict the local resonance frequency band on the aluminium extruded panel used for the high speed train, and investigate how the design modification in the unit structure influences the local resonance frequency band and panel bending stiffness. The purpose of the study is to provide the design information for the effective unit structure in order to improve the sound insulation performance of the aluminium extruded panel.

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Analysis of Vibration Characteristics of Modular Unit by Road Test (도로 주행 시험을 통한 모듈러 유닛의 진동 특성 분석)

  • Kwak, Myong Keun;Back, Jung Hoon;Seol, Wook Je
    • Journal of the Architectural Institute of Korea Planning & Design
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    • v.35 no.1
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    • pp.29-35
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    • 2019
  • The unit modular system is a type of prefabricated construction method that completes the building by uniting the modular units on site by transporting the unit module structure manufactured in the factory to the site. Since the unit module structure is not only the frame but also the finished form including the inner and outer materials, it is most likely to be brought into the field. Therefore, not only the damage of the inner and outer materials but also deformation of frame structure due to the vibration generated during the transportation of the vehicle, And it is necessary to take appropriate methods when transporting the module structure. However, there are no methods to prevent modular structure damage due to vehicle vibration in domestic and foreign modular transportation guidelines or standards. In this study, we investigate the vibrations during the vehicle transportation of the module structure through the road driving test, identify the vibration frequency characteristics of the vehicle through FFT analysis, and propose a vibration reduction methods for module transportation.

Experimental Investigation on DeNOx Performance according to the Urea-SCR System Control at Various Operating Conditions for Diesel Engines (디젤엔진의 운전조건 변화 및 Urea-SCR 시스템 제어에 따른 DeNOx 성능에 대한 실험적 연구)

  • Han, Jung-Won;Gong, Ho-Jeong;Hwang, In-Goo;Myung, Cha-Lee;Park, Sim-Soo
    • Transactions of the Korean Society of Automotive Engineers
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    • v.18 no.6
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    • pp.76-83
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    • 2010
  • Recently, as the current and future emission regulations go stringent, the research of NOx reduction has become a subject of increasing interest and attention in diesel engine. Selective Catalytic Reduction (SCR) is one of the effective technology to reduce NOx emission from diesel engine. Especially, Urea-SCR that uses urea as a reductant is becoming increasingly popular as a cost effective way of reducing NOx emissions from heavy duty vehicles. In this research, we designed urea injector and DCU (Dosing Control Unit) specially developed for controlling the Urea-SCR process onboard vehicles. As passenger and commercial diesel engine experiment, we grasped characteristics of NOx emission and SCR catalyst temperature level in advance. As a result, highest NOx emission level was shown in condition of low engine speed and high load. On the other hand, SCR catalyst temperature was highest at high engine speed and load. On the basis of these result, we conducted the NOx reduction test at steady engine operating conditions using the urea injector and DCU. It was shown that 74% NOx conversion efficiency on the average and 97% NOx conversion efficiency was obtained at high SCR catalyst temperature.