• Title/Summary/Keyword: Reduction Potential

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A Study on Potential of Aquatic Plants to Remove Indoor Air Pollutants (실내오염물질 정화를 위한 수생식물의 이용가능성에 관한 연구)

  • Park, Soyoung;Kim, Jeoung;Jang, Young-Kee;Sung, Kijune
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.8 no.5
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    • pp.1-9
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    • 2005
  • This study was conducted to investigate the effect of aquatic plant as a botanical air purification on the indoor air pollution by formaldehyde. Three aquatic plants such as Eichhornia crassipes, Cyperus alternifolius, Echinodorus cordifolius, were selected for this study and they were placed in the artificially contaminated chamber under laboratory condition. The results showed that all three plants could remove the formaldehyde from the contaminated air system effectively. Reduction in the formaldehyde levels by Eichhornia crassipes, which is the floating plant, might be associated with the factors of plant and water. Reduction in the formaldehyde levels by Cyperus helferi and Echinodorus cordifolius, which were emergent plant, was due to the complex effect of plant, soil medium and water. In aquatic plant system, dissolution, microbial degradation in rhizosphere, uptake through root and shoot, sorption to soil and shoot, hydrolysis are known as the main mechanisms of water soluble pollutants in the given system. The advantages of indoor air quality control system using aquatic plants can be; 1) various purifying mechanisms than foliage plants, 2) effective for decontamination of water soluble pollutants; 3) easy for maintenance; 4) diverse application potential. Therefore it was suggested from the results that indoor air control system of aquatic plants should be more effective for reduction of indoor air pollutants.

Substituent Effects and Correlations of Electrochemical Behaviors with Molecular Orbital Calculation of Thioxantone DerivativesⅠ

  • 곽경도;서무룡;하광수;백우현
    • Bulletin of the Korean Chemical Society
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    • v.19 no.5
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    • pp.527-530
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    • 1998
  • This paper presents the electrochemistry and molecular orbital (MO) picture of a series of conformationally-restricted thioxantone derivatives. A series of $C_2-substituted$ thioxanthones were examined to probe the electronic influence of the substituent on the electrooxidation and electroreduction sites (i.e., on the electron densities at the 10-and 9-positions), respectively. In the presence of "electrophoric" groups such as C=O and S, characteristic electrochemical reduction and oxidation responses are observed. The electrochemical reaction was diffusion-controlled, because the $I_p/{\upsilon}^{1/2}$ ratio was constant for the anodic and cathodic wave of thioxantone derivatives. These substituent effects are presented in terms of correlations of oxidation (or reduction) potentials with the highest occupied molecular orbital (HOMO), or lowest unoccupied molecular orbital (LUMO) energies, respectively. There is good correlation between energies of the HOMO vs. $E_{pa}^{(+)}$ and energies of the LUMO vs. $E_{pc}^{(-)}$. Frontier Molecular Orbital (FMO) is changed by the functional group of thioxanthones. FMO energy level was offered us the information about the electron transfer direction, and the coefficient of FMO was offered the information about the electron transfer position. Sulfur atom has an important effect on oxidation potential, $E_{pa}^{(+)}$ and the carbonyl carbon has an important effect on reduction potential, $E_{pc}^{(-)}$. Therefore we were appreciated that the contribution of sulfur atom for the $E_{pa}^{(+)}$ and HOMO energies is larger than the contribution of carbonyl group for the $E_{pc}^{(-)}$ and LUMO energies.

Policy implication of nuclear energy's potential for energy optimization and CO2 mitigation: A case study of Fujian, China

  • Peng, Lihong;Zhang, Yi;Li, Feng;Wang, Qian;Chen, Xiaochou;Yu, Ang
    • Nuclear Engineering and Technology
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    • v.51 no.4
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    • pp.1154-1162
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    • 2019
  • China is undertaking an energy reform from fossil fuels to clean energy to accomplish $CO_2$ intensity (CI) reduction commitments. After hydropower, nuclear energy is potential based on breadthwise comparison with the world and analysis of government energy consumption (EC) plan. This paper establishes a CI energy policy response forecasting model based on national and provincial EC plans. This model is then applied in Fujian Province to predict its CI from 2016 to 2020. The result shows that CI declines at a range of 43%-53% compared to that in 2005 considering five conditions of economic growth in 2020. Furthermore, Fujian will achieve the national goals in advance because EC is controlled and nuclear energy ratio increased to 16.4% (the proportion of non-fossil in primary energy is 26.7%). Finally, the development of nuclear energy in China and the world are analyzed, and several policies for energy optimization and CI reduction are proposed.

Phosphate-decorated Pt Nanoparticles as Methanol-tolerant Oxygen Reduction Electrocatalyst for Direct Methanol Fuel Cells

  • Choi, Jung-goo;Ham, Kahyun;Bong, Sungyool;Lee, Jaeyoung
    • Journal of Electrochemical Science and Technology
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    • v.13 no.3
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    • pp.354-361
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    • 2022
  • In a direct methanol fuel cell system (DMFC), one of the drawbacks is methanol crossover. Methanol from the anode passes through the membrane and enters the cathode, causing mixed potential in the cell. Only Pt-based catalysts are capable of operating as cathode for oxygen reduction reaction (ORR) in a harsh acidic condition of DMFC. However, it causes mixed potential due to high activity toward methanol oxidation reaction of Pt. To overcome this situation, developing Pt-based catalyst that has methanol tolerance is significant, by controlling reactant adsorption or reaction kinetics. Pt/C decorated with phosphate ion was prepared by modified polyol method as cathode catalyst in DMFC. Phosphate ions, bonded to the carbon of Pt/C, surround free Pt surface and block only methanol adsorption on Pt, not oxygen. It leads to the suppression of methanol oxidation in an oxygen atmosphere, resulting in high DMFC performance compared to pristine Pt/C.

Nitrate Metabolism Affected by Osmotic Stress and Nitrate Supply Level in Relation to Osmoregulation

  • Kim, Tae-Hwan
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.20 no.2
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    • pp.77-84
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    • 2000
  • Eight-week old perennial ryegrass (Lolium perenne L. cv. Reveille) plants were exposed to different NO3-concentrations or osmotic stress with NaCI. Previously labeled "N was chased during 14 days of non-labeled'NO3 feeding in order to investigate NO3 metabolism in relation to osmoregulation. The short termmeasurement of osmotic potential showed that the extemal concentration of Nos- had not great effect on theosmotic potential, but that osmotic adjustment was observed in NaCl-treated plants. Total uptake of NO 3 - waslargely increased by increasing supply level of NO3 while it was depressed by exposing to osmotic stress.Nitrate reduction increased to more than 29% by increasing extemal NO,- concentration from 1 mM to 10mM. When osmotically stressed with NaCI, nitrate reduction was depressed to about 37% as compared to thecontrol. The decrease in translocation of reduced N into leaves was also observed in NaCl exposed plants. Inthe medium exposed to 10 mM NO,., osmotic contribution of nitrate to cumulative osmotic potential wasdecreased, and it was osmotically compensated with soluble carbohydrate. When osmotically stressed withNaC1, the contribution of chloride was much higher than that of nitrate. The present data indicate that N03-in plant tissues, factually affected by the assimilation of this ion, plays an active role in osmotic regulation incorrelation with other osmotica such carbohydrate and chloride.(Key words : Nitrate metabolism, Osmotic stress, Nitrate supply level, Osmoregulation)ate supply level, Osmoregulation)

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Surface characterization and evaluation of biofouling inhibition of reverse osmosis membranes coated with Epigallocatechin gallate(EGCG)/vanillin (EGCG/바닐린 코팅 RO분리막의 표면 특성과 미생물막 억제능)

  • Jung, Jaehyun;Kim, Youngjin;Nam, Haewook;Kim, Yunjung;Lee, Eunsu;Lee, Younil;Kweon, Jihyang
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.6
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    • pp.713-723
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    • 2014
  • Biofouling in brackish water reverse osmosis (RO) membranes still needs extensive research to understand cause and mechanism and to obtain methods for reduction of its impact on RO applications. Natural compounds with biofilm formation inhibitory properties are being investigated. Two compounds, vanillin and Epigallocatechin gallate (EGCG), were selected due to their great potential on biofilm formation inhibition. Vanillin shows inhibition on quorum sensing mechanisms of biofilm formation. EGCG has potential to inactivate microbial activity. The two compounds were incorporated in typical polyamide reverse osmosis membranes and evaluated on flux behaviours and biofilm formation potential. The surface properties of membrane coated with vanillin were changed tremendously compared to those with EGCG. As a result, the flux was reduced substantially. The biofilm formation seems hindered with EGCG coated membranes compared to the virgin membranes. More research is needed to optimize coating methods applicable to RO membranes and to enhance biofouling reduction.

Comparative Life Cycle Assessment of Reusable and Disposable Distribution Packaging for Fresh Food (신선식품용 재사용 EPE박스와 EPS박스에 대한 전과정 환경영향평가)

  • SY Kim;Charoensri Korakot;YJ Shin;HJ Park
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.29 no.3
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    • pp.181-193
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    • 2023
  • In this study, we conducted a comparative life cycle assessment (LCA) of two different products, considering reusable and single-use packaging for fresh food distribution. For reusable packaging, we utilized expanded polyethylene (EPE), while for comparison, a disposable box made of widely used expanded polystyrene (EPS) was selected. We comprehensively analyzed the environmental impacts of production, transportation, reprocessing (for reused boxes), and disposal across 18 impact categories. Upon analyzing the actual reuse of 300 rounds of fresh food, the cumulative global warming potential (GWP) values for the EPE box were found to be 280.21 kg carbon dioxide (CO2) eq, demonstrating a significant 75% reduction compared to those of the EPS box. Furthermore, it was observed that the GWP values for the EPE boxes became equivalent to those of the EPS boxes after 12 rounds of reuse. In conclusion, reusable packaging shows substantial potential to contribute to the reduction of environmental burdens, aligning well with global environmental requirements for sustainable food distribution and related industries.

Evaluation Methods of Carbon Reduction Contribution for Green Budget of National R&D Projects in Agricultural Sector (농업분야 탄소인지예산제도 도입을 위한 국가연구개발사업의 탄소저감 기여도 평가 방안)

  • Kim, Solhee;Han, Seunghyun;Kang, Seong-Soo;Suh, Kyo
    • Journal of The Korean Society of Agricultural Engineers
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    • v.64 no.5
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    • pp.41-51
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    • 2022
  • Carbon neutrality is emerging as a new paradigm for the international society by transiting from climate change to climate risk. This study proposes evaluation methods for the carbon reduction contribution of climate-related national R&D projects in order to introduce a green budget system in the agricultural sector. We considered the domestic and foreign green budget systems and classified national R&D projects into positive, negative, and neutral from the perspective of carbon reduction. The results of this study propose three methods to estimate the monetary costs and carbon benefits by adopting the framework for the economic evaluation of national R&D projects conducted by the Rural Development Administration. These methods support to evaluate the potential contribution to carbon reduction of national R&D projects in the agricultural sector. Finally, the proposed methods were tested and verified for the efficiency and validity of evaluating carbon reduction contribution. These evaluation methods of the carbon reduction contribution can be used as a basic methodology for the pre-budget calculations of national R&D projects and the contribution for the greenhouse gas reduction budget.

Incorporation Effect of Green Manure Crops on Improvement of Soil Environment on Saemangeum Reclaimed Land during Silage Corn Cultivation

  • Yang, Chang-Hyu;Lee, Jang-Hee;Baek, Nan-Hyun;Shin, Pyeong;Cho, Kwang-Min;Lee, Sang-Bok;Lee, Gyeong-Bo
    • Korean Journal of Soil Science and Fertilizer
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    • v.46 no.3
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    • pp.187-192
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    • 2013
  • This study was carried out to investigate the incorporation effect of green manure crops (GMC) such as the hairy vetch on improvement of soil environment in reclaimed land during silage corn cultivation over the past two years. Plots consisted of conventional fertilization (CF) and incorporation of GMC were divided by addition rate of nitrogen fertilizer (100 kg $ha^{-1}$) with 30 - 100% of non nitrogen fertilization (NNF). Soil physico-chemical properties and growth and yield potential of silage corn were examined. The tested soils showed strong alkali and saline properties with low contents of organic matter and available phosphate while contents of exchangeable sodium and magnesium were high. Soil salinity increased during cultivation of summer crop. However, corn was not affected by salt content. The fresh weight of GMC at incorporation time was 18,345 kg $ha^{-1}$. Content of total nitrogen was 3.09% and the C/N ratio was 12.8 at incorporation time. Fresh and dry matter yield of silage corn were higher in the order of N30% reduction, CF, N50% reduction, N70% reduction, N100% reduction and NNF. Fresh and dry matter yield potential of silage corn for N30% reduction were comparable to those of CF. Bulk density of the soil decreased with incorporation of GMC, while porosity was increased. The soil pH decreased while content of exchangeable calcium, available phosphate, and organic matter increased. Also contents of exchangeable sodium and potassium decreased with incorporation of GMC. The data indicate that incorporation of hairy vetch can improve soil physical and chemical properties and reduce nitrogen fertilizer application especially for alkali saline reclaimed soil such as Saemangeum reclaimed land.