• Title/Summary/Keyword: Reduced atmosphere

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Photovoltaic Generating System on Ships to Reduce Fossil Fuel Dependence (선박에서 화석연료 의존도 절감을 위한 태양광 발전)

  • Takeshi Katagi;Yoshimi Fujii;Eiichi Nishikawa;Takeshi Hashimoto;Kenji Ishida
    • Journal of Advanced Marine Engineering and Technology
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    • v.20 no.3
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    • pp.176-176
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    • 1996
  • The release of polluting gases such as NOx of SOx to the atmosphere from ships is causing increasing concern. To reduce destruction to the marine environment, the value of the utilization of photovoltaic energy is highly appreciated since photovoltaic energy is and alternate clean energy source to fossil fuels. The use of a photovoltaic generating system to supplement diesel engine driven electric power system on ships has been studied. The design of the photovoltaic generating system based on a photovoltaic array is presented in this paper. The amount of NOx and SOx emission is found to be significantly reduced for a small vessel operated within a harbour after a photovoltaic generating system is installed to supplement the diesel engine generator system.

Effects of Packaging Methods on the Shelf Life of Selenium-Supplemented Chicken Meat during Refrigerated Storage

  • Rhee, Min-Suk;Ryu, Youn-Chul;Kim, Byoung-Chul
    • Food Science and Biotechnology
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    • v.15 no.3
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    • pp.431-436
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    • 2006
  • Effects of vacuum packaging and modified atmosphere packaging (MAP) on shelf life of selenium-supplemented chicken meat during refrigerated storage were examined. Body weight and feed efficiency were unaffected by dietary selenium level. Dietary treatments and packaging methods had no significant effects on level of microbial growth, lightness, and metmyoglobin content. MAP decreased purge loss (10.9-34.5%) and lipid oxidation (15.2-15.9%) more efficiently than vacuum packaging. Broiler chicks supplemented with ${\alpha}$-tocopherol or ${\alpha}$-tocopherol + selenium had similar TBA values. Dietary supplementation of 4 and 8 ppm selenium reduced lipid oxidation, and this effect was less significant in MAP breast meat.

Tantalum Powder Preparation from Ta2O5 by Calciothermic Reduction (칼슘 열환원법에 의한 Ta2O5로부터 Ta분말제조)

  • Ha, Jung-Woo;Sohn, Ho-Sang;Jung, Jae-Young
    • Korean Journal of Metals and Materials
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    • v.50 no.11
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    • pp.823-828
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    • 2012
  • Direct reduction of $Ta_2O_5$ using liquid calcium was investigated. The experiment was conducted in a closed stainless steel chamber in an Ar atmosphere for 5-120 minutes. Most of $Ta_2O_5$ was reduced to ${\alpha}-Ta$ in 30 minutes above 1173 K and at a molar ratio of Ca and $Ta_2O_5$ above 10. The particles size increased with the reaction temperature, but it did not change much above 1223 K. The oxygen content of metal Ta was about 1 wt%.

Photoluminescence of the Mn-doped ZnGa₂O₄ Phosphors Prepared by Coprecipitation of Metal Salts

  • 고중곤;박희동;김동표
    • Bulletin of the Korean Chemical Society
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    • v.20 no.9
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    • pp.1035-1039
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    • 1999
  • Manganese-activated zincgallate (Zn1-xMnxGa2O4) phosphor as a green phosphor was readily prepared by coprecipitation in aqueous basic solution of metal salts. The obtained product converted to amorphous zincgallate even at 300℃, followed by crystallization at 1000 ℃. The pyrolyzed phosphor showed fine particle, then reduction treatment at 900 ℃ changed into homogeneous shape with slight grain growth(particle size less than 0.5 mm). The photoluminescence characteristics of the zincgallates have been investigated as a function of dopant concentrations, reducing atmospheres and temperatures. Under UV excitation the phosphors displayed the highest green emission efficiency at 504 nm when the specimen oxidized at 1000 ℃ was reduced at 900 ℃ in a mild hydrogen atmosphere (97% N2, 3% H2) with a flow rate of 100 ml/min.

Reduction of Alkyl Halides by Homonuclear Bridging Hydride, (μ-H)[(η$^5-MeCp)$Mn(CO)₂]₂-ppn+

  • 박용광;김영웅
    • Bulletin of the Korean Chemical Society
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    • v.17 no.3
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    • pp.269-273
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    • 1996
  • Alkyl halides were reduced to the corresponding alkanes by the homonuclear bridging hydride, (μ-H)[(η5-MeCp)Mn(CO)2]2-PPN+ in THF at the elevated temperatures (40-60 ℃) under the pseudo first order reaction conditions where excess of alkyl halide was employed under nitrogen atmosphere. The reaction is of overall second order; first order with respect to [bridging hydride] and first order with respect to [alkyl halide] with the activation parameters, ΔH≠=28.93 kcal/mol and ΔS≠=17.95 e.u. The kinetic data, the ESR evidence and the reaction with cyclopropyl canbinyl bromide ensure that two possible reaction pathways are operable in this reaction: (1) concerted mechanism, and (2) single electron transfer pathway are in competition leading to the same product, the corresponding alkane.

High-Ic YBCO thick film fabricated by the MOD process (MOD 공정으로 제조된 고임계전류 YBCO 후막)

  • Shin, Geo-Myung;Song, Kyu-Jung;Moon, Seung-Hyun;Yoo, Sang-Im
    • Progress in Superconductivity and Cryogenics
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    • v.10 no.1
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    • pp.6-9
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    • 2008
  • We have investigated the MOD process successfully for the fabrication of the YBCO thick film on the $LaAlO_3$(001) single crystalline substrate. The cracking problem in YBCO thick film, a serious problem in the conventional TFA-MOD method, could be overcome with a careful control of precursor materials. Thus coating solution was prepared for the YBCO thick film by using fluorine-free precursor material. The precursor solutions were coated on the LAO(001) single crystalline substrate using the dip coating method, calcined at the temperature up to $500^{\circ}C$, and fired at various high temperatures for 2 h in a reduced oxygen atmosphere. Optimally processed YBCO thick film exhibited high critical current($I_c$) over 200 A/cm-width at 77K in self-field.

Effects of Thermal Treatment Conditions on the Powder Characteristics of Uranium Oxide in HTGR Fuel Preparation (고온가스로용 핵연료 제조에서 열처리 조건이 우라늄산화물 입자 특성에 미치는 영향)

  • Kim, Yeon-Ku;Jeong, Kyung-Chai;Oh, Seung-Chul;Suhr, Dong-Soo;Cho, Moon-Sung
    • Journal of Powder Materials
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    • v.16 no.2
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    • pp.115-121
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    • 2009
  • The effects of thermal treatment conditions on ADU (ammonium diuranate) prepared by SOL-GEL method, so-called GSP (Gel supported precipitation) process, were investigated for $UO_2$ kernel preparation. In this study, ADU compound particles were calcined to $UO_3$ particles in air and Ar atmospheres, and these $UO_3$ particles were reduced and sintered in 4%-$H_2$/Ar. During the thermal calcining treatment in air, ADU compound was slightly decomposed, and then converted to $UO_3$ phases at $500^{\circ}C$. At $600^{\circ}C$, the $U_3O_8$ phase appeared together with $UO_3$. After sintering of theses particles, the uranium oxide phases were reduced to a stoichiometric $UO_2$. As a result of the calcining treatment in Ar, more reduced-form of uranium oxide was observed than that treated in air atmosphere by XRD analysis. The final phases of these particles were estimated as a mixture of $U_3O_7$ and $U_4O_9$.

Methane Partial Oxidation Using Cu-ferrite (Cu-ferrite에 의한 메탄의 부분산화)

  • Woo, Sung-Woung;Kang, Kyoung-Soo;Kim, Chang-Hee;Park, Chu-Sik
    • Transactions of the Korean hydrogen and new energy society
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    • v.18 no.2
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    • pp.124-131
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    • 2007
  • Methane is partially oxidized to produce the syngas by the lattice oxygen of metal oxides in the absence of gaseous oxygen. The present work deals with ferrite including copper component, which does not chemisorb methane, to investigate the suppression of the carbon deposition during the reduction of metal oxides by methane. Iron-based oxides of $Cu_xFe_{3-x}O_4$(X=0.25, 0.5, 1.0) was synthesized by the co-precipitation method. Thermogravimetric Analysis(TGA) was used to observe the isothermal reduction behavior of $Cu_xFe_{3-x}O_4$ and $Fe_3O_4$ at $600-900^{\circ}C$ under methane atmosphere. The crystal structures of reduced specimens were characterized by X-rays powder diffraction(XRD) technique. From the analyses of TGA, it is concluded that the reduction kinetics of $CuFe_2O_4$ was the fastest among $Fe_3O_4$ and $Cu_xFe_{3-x}O_4$(X=0.25, 0.5, 1.0). The X-ray diffraction analyses indicated that $Cu_xFe_{3-x}O_4$ was decomposed to Cu and $Fe_3O_4$ phase at $600^{\circ}C$ and was reduced to Cu and Fe phase at $800^{\circ}C$. $Fe_3O_4$, which was reduced at $900^{\circ}C$, showed Fe, graphite and $Fe_3C$ phases. On the contrary, $Cu_xFe_{3-x}O_4$ does not show the graphite or $Fe_3C$ phases. This results infer that Cu component suppress the carbon deposition on Cu-ferrite.

Low incubation temperature successfully supports the in vitro bovine oocyte maturation and subsequent development of embryos

  • Sen, Ugur;Kuran, Mehmet
    • Asian-Australasian Journal of Animal Sciences
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    • v.31 no.6
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    • pp.827-834
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    • 2018
  • Objective: The aim of this study was to compare the effects of $36.5^{\circ}C$ and $38.5^{\circ}C$ incubation temperatures on the maturation of bovine oocytes and developmental competence of embryos. Methods: In experiment 1, oocytes were maturated in bicarbonate-buffered TCM-199 for 22 hours in a humidified atmosphere of 5% $CO_2$ in the air at either $36.5^{\circ}C$ or $38.5^{\circ}C$ and nuclear maturation status were determined. In experiment 2, in vitro fertilized oocytes were allocated randomly into synthetic oviductal fluid medium with or without a mixture of 1 mM L-glutathione reduced and 1,500 IU superoxide dismutase and cultured in a humidified atmosphere of 5% $CO_2$, 5% $O_2$, and 90% $N_2$ in the air at $38.5^{\circ}C$ for 8 days. Results: There were no significant differences between incubation temperatures in terms of oocyte maturation parameters such as cumulus expansion, first polar body extrusion and nuclear maturation. Incubation temperatures during in vitro maturation had no effects on developmental competence of embryos, but supplementation of antioxidants increased (p<0.05) developmental competence of the embryos. Blastocysts from oocytes matured at $38.5^{\circ}C$ had comparatively higher inner cell mass, but low overall and trophectoderm cell numbers (p<0.05). Conclusion: The results of present study showed that maturation of bovine oocytes at $36.5^{\circ}C$ may provide a suitable thermal environment for nuclear maturation and subsequent embryo development.

Forecast Sensitivity Analysis of An Asian Dust Event occurred on 6-8 May 2007 in Korea (2007년 5월 6-8일 황사 현상의 예측 민감도 분석)

  • Kim, Hyun Mee;Kay, Jun Kyung
    • Atmosphere
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    • v.20 no.4
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    • pp.399-414
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    • 2010
  • Sand and dust storm in East Asia, so called Asian dust, is a seasonal meteorological phenomenon. Mostly in spring, dust particles blown into atmosphere in the arid area over northern China desert and Manchuria are transported to East Asia by prevailing flows. An Asian dust event occurred on 6-8 May 2007 is chosen to investigate how sensitive the Asian dust transport forecast to the initial condition uncertainties and to interpret the characteristics of sensitivity structures from the viewpoint of dynamics and predictability. To investigate the forecast sensitivities to the initial condition, adjoint sensitivities that calculate gradient of the forecast aspect (i.e., response function) with respect to the initial condition are used. The forecast aspects relevant to Asian dust transports are dry energy forecast error and lower tropospheric pressure forecast error. The results show that the sensitive regions for the dry energy forecast error and the lower tropospheric pressure forecast error are initially located in the vicinity of the trough and then propagate eastward as the surface low system moves eastward. The vertical structures of the adjoint sensitivities for the dry energy forecast error are upshear tilted structures, which are typical adjoint sensitivity structures for extratropical cyclones. Energy distribution of singular vectors also show very similar structures with the adjoint sensitivities for the dry energy forecast error. The adjoint sensitivities of the lower tropospheric pressure forecast error with respect to the relative vorticity show that the accurate forecast of the trough (or relative vorticity) location and intensity is essential to have better forecasts of the Asian dust event. Forecast error for the atmospheric circulation during the dust event is reduced 62.8% by extracting properly weighted adjoint sensitivity perturbations from the initial state. Linearity assumption holds generally well for this case. Dynamics of the Asian dust transport is closely associated with predictability of it, and the improvement in the overall forecast by the adjoint sensitivity perturbations implies that adjoint sensitivities would be beneficial in improving the forecast of Asian dust events.