• Title/Summary/Keyword: Recycle process

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Characteristics of Cyanide Decomposition by Hydrogen Peroxide Reduction (과산화수소에 의한 시안의 분해특성)

  • 이진영;윤호성;김철주;김성돈;김준수
    • Resources Recycling
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    • v.11 no.2
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    • pp.3-13
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    • 2002
  • The characteristics of cyanide decomposition in aqueous phase by hydrogen peroxide have been explored in an effort to develop a process to recycle waste water. The self-decomposition of $H_2O$$_2$at pH 10 or below was minimal even in 90 min., with keeping about 90% of $H_2O$$_2$undissociated. On the contrary, at pH 12 only 9% of it remained during the same time. In the presence of copper catalyst at 5 g Cu/L, complete decomposition of $H_2$O$_2$was accomplished at pH 12 even in a shorter time of 40 min. The volatility of free cyanide was decisively dependent on the solution pH: the majority of free cyanide was volatilized at pH 8 or below, however, only 10% of it was volatilized at pH 10 or above. In non-catalytic cyanide decomposition, the free cyanide removal was incomplete in 300 min. even in an excessive addition of $H_2$$O_2$at a $H_2$$O_2$/CN molar ratio of 4, with leaving behind about 8% of free cyanide. On the other hand, in the presence of copper catalyst at a Cu/CN molar ratio of 0.2, the free cyanide was mostly decomposed in only 16 min. at a reducedH202/CN molar ratio of 2. Ihe efnciency of HBO2 in cyanide decomposition decreased with increasing addition of H2O2 since the seu-decomposition rate of $H_2$$O_2$increased. At the optimum $H_2$$O_2$/mo1ar ratio 0.2 of and Cu/CN molar ratio of 0.05, the free cyanide could be completely decomposed in 70 min., having a self-decomposition rate of 22 mM/min and a H$_2$$O_2$ efficiency of 57%.

Evaluation for Applicability as the Inorganic Binder with Rapid Setting Property for Construction Material of LFS Produced from Various Manufacturing Process (다양한 철강제조공정에서 부산되는 전기로 환원슬래그의 급경성 무기결합재로의 적용성 검토)

  • Kim, Jin-Man;Choi, Sun-Mi;Kim, Ji-Ho
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.2
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    • pp.70-77
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    • 2012
  • The Ladle Furnace Slag, about 20% of the electric arc furnace slag, has high content of free CaO and free MgO, which generates the expansion collapse by hydration reaction. Although many researchers have been endeavoring to recycle the EAF reducing slag in construction fields, there is not found the effective recycling method up to now. However, the LFS(Ladle Furnace Slag) contains mineral composition of the system of calcium aluminate with high-reactivity. Therefore, it is possible to developed the quick setting property and the high strength at the early age by the rapid cooling. This study aimed to check the reactive minerals and predict the reactivity with water on the LFS discharged from different steel product plants. The test results show that many types of LFS has hydration reactivity and can use in construction field as a inorganic binder with the rapid setting property.

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Investigation on Economical Feasibility for Energy Business of Waste Water Sludge Discharged in 'A' Industrial Complex (A-산업단지 발생 슬러지의 에너지화를 위한 경제성 검토)

  • Byun, Jung-Joo;Lee, Kang-Soo;Phae, Chae-Gun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.20 no.4
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    • pp.61-74
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    • 2012
  • Industrial complexes in Korea have been vigorously established by economic development plan and development policy of industry in 1960s. Recently, Korean government has promoted Eco Industrial Park (EIP) project to recycle by-products and wastes in industrial park In this study, we analyzed the physical and chemical properties for the sludges discharged from A industrial complex. And we investigated the economic feasibility and environmental impact of sludge to energy facilities. The analysis results indicated that the petrochemical industry were 92% in sludge production, the highest treatment amount was landfill, followed by incineration and recycling and then ocean disposal. Wastewater sludge and process sludge samples are collected and analyzed to use as basic data on economic feasibility and environmental impact. Weighted average heating value of sludge samples was 3,891kcal/kg. Based on this data, installation and operation costs, operation returns of operating the drying facility are estimated, compared with cogeneration facility. And this study examines how the payback period of each simulation(total 8 case) with the important parameter changes. As a result, it was found that what needs the shortest payback period is 3years with connection of drying facility and cogeneration facility based on the government's financial subsidy system.

A Study on the Water-Ethanol Separation by Membrane-Aided Distillation in Bio-Ethanol Process (바이오 에탄올 생산을 위한 Membrane-Aided Distillation에 의한 물-에탄올 분리공정에 관한 연구)

  • Jung, Heon;Choi, Young-Seok;Yang, Dae-Rook;Joo, Oh-Shim;Jung, Kwang-Deog
    • Clean Technology
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    • v.14 no.2
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    • pp.129-135
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    • 2008
  • Nylon membrane was used to separate ethanol-water by a pervaporation method. Experimental equations were derived to use the simulation of membrane-aided distillation using nylon. The increases in permeation pressure resulted in the decrease in selectivity and energy consumption. The energy cost to enrich ethanol from 94 wt% to 99.5 wt% was calculated to be 53.3 won/kg of ethanol with extractive distillation and 18.9 won/kg of ethanol with a pervaporation method. The saving energy by the pervaporation method is consumed by recycling the permeate residue into the distillation column in the membrane-aided distillation column. Therefore, membrane with the high selectivity to minimize the permeate residue recycle is required to effectively enrich ethanol in the membrane-aided distillation method.

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Research on Landscape Design by Flexibly Using Resilient Theory - Focused On 'New York High Line Park'- (리질리언트 이론을 활용한 경관 디자인에 관한 연구 - 'The High Line' 를 중심으로 -)

  • Chen, Wen-Li;Hong, Kwan-Seon
    • The Journal of the Korea Contents Association
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    • v.20 no.1
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    • pp.644-657
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    • 2020
  • As the development of urbanization has cause some environmental problems and natural disasters such as natural earthquakes and floods have brought about impact, designers have turned their attention to the independent prevention ability of urban ecosystems in face of environmental pollution and natural disasters, as well as its ability to adapt to the future. This study introduces 'elasticity theory' to discuss the practical application of elasticity design in landscapes and to solve the problem of lack of elasticity in space, which can provide more scientific reference meaning to create economic, cultural, and social values for space. After selecting 'The High Line' as the object, this paper investigates the previous theories and practical cases, and infers ecology, sustainability, diversity, and adaptability. And then this paper applies five components and analyzes the specific application of these five components of the landscape spatial elasticity strategy, and summarizes the application characteristics and influencing factors of elasticity design in 'The High Line' landscape planning. It can be known from the research that elasticity strategy which is reflected in the design process is the systematic management of landscape space. Elasticity design itself can strengthen environment quality and satisfy the requirements of the environment to defense external shocks so as to adapt to environment changes. Therefore, the elasticity design can strengthen the sustainable development of the city and establish a periodic recycle system.

Preparation of Multi-functional Brick Using MSWI Fly Ash (소각재를 이용한 건축외장재 제조)

  • Ban, Hyo-Jin;Park, Eun-Zoo;Lee, Woo-Keun
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.2
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    • pp.114-118
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    • 2009
  • With the advance of industrialization and urbanization, a lot of waste has been discharged and treated by incineration. But fly and bottom ashes are generated in this process. In addition, the treatment method to recycle sewage sludge and melting slag is required to manage these wastes. The objective of this research was to prepare of multi-functional brick which were made from MSWI (Municipal solid wastes incinerator) fly ash, sewage sludge and slag. The bricks were made by mixing raw materials and then drying for 24 hours. Next, they were dried for 24 hours at $160^{\circ}C$ and fired for 2 hours. Calcination temperature was changed to discuss the effect of temperature from $1,080^{\circ}C$ to $1,130^{\circ}C$. Compressive strength of a brick was creased with the increase of temperature. To increase mixing ratio of fly ash and slag reduce the compressive strength the optimal condition was the mixing ratio of fly ash : melting slag : sewage sludge : clay as 10 : 20 : 5 : 65 and $1,150^{\circ}C$ of calcination temperature. Compressive strength was obtained as about 41 MPa at this condition.

Evaluation of the performance of encapsulated lifting system composting technology with a GORE(R) cover membrane: Physico-chemical properties and spectroscopic analysis

  • Al-Alawi, Mutaz;El Fels, Loubna;Benjreid, Ramadan;Szegi, Tamas;Hafidi, Mohamed;Simon, Barbara;Gulyas, Miklos
    • Environmental Engineering Research
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    • v.25 no.3
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    • pp.299-308
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    • 2020
  • Composting is among the most effective integrated waste management strategies used to recycle sewage sludge (SS) waste and generate a useful product. An encapsulated lifting system is a relatively new industrial-scale composting technology. The objective of this study was to evaluate the effectiveness of composting dewatered stabilized SS mixed with green waste using this new technology. The composting process was monitored by changes in the physico-chemical properties, UV-visible spectra, and fourier transform infrared (FTIR) spectra. The composting temperature was steady in the thermophilic range for 24 and 12 d in the intensive and maturation phases, respectively, which fulfilled the disinfection requirement. Moreover, the temperature increased rapidly to 76.8℃ within three days, and the thermophilic temperatures peaked twice and lasted longer than in traditional composting, which accelerated SS degradation and decreased the composting period necessary to obtain mature compost. FTIR spectroscopic analysis showed a diminished in methyl group derived from methylene C-H aliphatic groups because of organic matter degradation by microorganisms and an increased number of aromatic chains. The new technology may be a viable and sustainable alternative for SS management that converts waste into compost that is useful as a soil amendment.

Simulation and Control of the Molten Carbonate System using Aspen $Dynamics^{TM}$ and ACM (Aspen $Dynamics^{TM}$와 ACM을 이용한 용융탄산염 연료전지 시스템의 모사 및 제어)

  • Jeon, Kyoung Yein;Kwak, Ha Yeon;Kyung, Ji Hyun;Yoo, Ahrim;Lee, Tae Won;Lee, Gi Pung;Moon, Kil Ho;Yang, Dae Ryook
    • Korean Chemical Engineering Research
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    • v.49 no.4
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    • pp.423-431
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    • 2011
  • Recentincreasing awareness of the environmental damage caused by the $CO_2$ emission of fossil fuelsstimulated the interest in alternative and renewable sources of energy. Fuel cell is a representative example of hydrogen energy utilization. In this study, Molten Carbonate Fuel Cell system is simulated by using $Aspen^{TM}$. Stack model is consisted of equilibrium reaction equations using $ACM^{TM}$(Aspen Custom Modeler). Balance of process of fuel cell system is developed in Aspen $Plus^{TM}$ and simulated at steady-state. Analysis of performance of the system is carried out by using sensitivity analysis tool with main operating parameters such as current density, S/C ratio, and fuel utilization and recycle ratio.In Aspen $Dynamics^{TM}$, dynamics of MCFC system is simulated with PID control loops. From the simulation, we proposed operation range which generated maximum power and efficiency in MCFC power plant.

A Study on Recovery of Aluminum Oxide from Artificial Marble Waste by Pyrolysis (열분해에 의한 폐인조대리석으로부터 산화알루미늄 회수에 관한 연구)

  • Kim, Bok Roen;Kim, Chang Woo;Seo, Yang Gon;Lee, Young Soon
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.567-573
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    • 2012
  • Compared with the natural marble, the artificial marble has the advantages of excellent appearance, high degree of finish, even color, fine pressure and wear resistance, bear erosion and weathering, etc. It can be widely used in kitchen countertops, bath vanity tops, table tops, furniture, reception desks, etc. However, large amounts of artificial marble waste such as scraps or dust have been generated from sawing and polishing processes in artificial marble industry. Waste from artificial marble industry is increasing according to demand magnification of luxurious interior material. Artificial marble wastes can be recycled as aluminum oxide used as raw materials in electronic materials, ceramics production, etc., and methyl methacrylate(MMA) which become a raw material of artificial marble by pulverization, pyrolysis and distillation processes. The characteristics of artificial marble wastes was analyzed by using TGA/DSC and element analysis. Crude aluminum oxide was obtained from artificial marble waste by pulverization and thermal decomposition under nitrogen atmosphere. In this work, Box-Behnken design was used to optimize the pyrolysis process. The characteristics of crude aluminum oxide was evaluated by chromaticity analysis, element analysis, and surface area.

A Study on Blood Management System based on SIP for Ubiquitous Healthcare service (유비쿼터스 헬스케어 서비스를 위한 SIP 기반 혈액관리 시스템에 관한 연구)

  • Park, Yong-Min;Oh, Young-Hwan
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.36 no.10B
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    • pp.1222-1232
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    • 2011
  • RFID/USN core technologies for ubiquitous computing, It is possible to use variety of sensors, direct processors, and wireless network technology that easily collect the actual physical environment and can monitor information remotely. Especially the healthcare industry and services combined with U-Healthcare that have international competitiveness in the medical field. But the USN, standard management system of RFID such as EPCglobal architecture framework, the lack of interoperability issues and the global sensor network implementation. In this paper, a system for managing sensor nodes of the USN, USN of SIP-based management system (UMS) is proposed. UMS support Session Initiation Protocol (SIP), provide session management and mobility capabilities, that is based on Internet standard protocol. UMS architecture of the existing SIP architecture, added USN User Agent (UUA) and the USN Name Server (UNS) that the location of sensor nodes should be possible to trace. UUA on behalf of the limited capacity of the location of the sensor nodes to perform the registration process, UNS to track the location of the sensor nodes to provide name resolution services. The proposed management system has the advantage of internet applications such as Web services interoperability and easy to recycle existing resources with other SIP-based because it uses the Internet standard protocol SIP. In this paper we propose is based on the UMS blood temperature management system is verified through the scenario.