• 제목/요약/키워드: Recyclable catalyst

검색결과 35건 처리시간 0.026초

Synthesis of 2-Substituted Benzofurans from o-Iodophenols and Terminal Alkynes with a Recyclable Palladium Catalyst Supported on Nano-sized Carbon Balls under Copper- and Ligand-Free Conditions

  • Yum, Eul Kgun;Yang, Ok-Kyung;Kim, Ji-Eun;Park, Hee Jung
    • Bulletin of the Korean Chemical Society
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    • 제34권9호
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    • pp.2645-2649
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    • 2013
  • We have developed a one-step synthesis of benzofurans from o-iodophenol and various terminal alkynes, by using Pd catalyst supported on nano-sized carbon balls (NCB) under copper- and ligand free conditions. This recyclable catalyst could be reused more than 5 times in the same heteroannulation reaction. The results have demonstrated that diverse 2-substituted benzofurans with tolerant functional groups can be prepared simply and conveniently under these conditions.

Synthesis of Quinoxaline Derivatives Using TiO2 Nanoparticles as an Efficient and Recyclable Catalyst

  • Alinezhad, Heshmatollah;Tajbakhsh, Mahmood;Salehian, Fatemeh;Biparva, Pourya
    • Bulletin of the Korean Chemical Society
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    • 제32권10호
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    • pp.3720-3725
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    • 2011
  • $TiO_2$ nanoparticles were synthesized and characterized by SEM and XRD techniques. The $TiO_2$ nanoparticles were employed as a recyclable, inexpensive and efficient catalyst for the synthesis of substituted quinoxalines in high to excellent yields and in relatively short duration.

Montmorillonite KSF Clay as Novel and Recyclable Heterogeneous Catalyst for the Microwave Mediated Synthesis of Indan-1,3-Diones

  • Marvi, Omid;Giahi, Masoud
    • Bulletin of the Korean Chemical Society
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    • 제30권12호
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    • pp.2918-2920
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    • 2009
  • Various indan-1,3-dione derivatives were synthesized from the reaction of different phthalic anhydrides with diethylmalonate using montmorillonite KSF clay as a recyclable heterogeneous acidic catalyst and microwave irradiation in good yields and short reaction times.

One Pot Four-Component Synthesis of Novel Substituted 2-Phenyl-4(3H) Quinazolinones Using Recyclable Nanocrystalline CuMnO3 Catalyst

  • Borhade, A.V.;Tope, D.R.;Gare, G D.;Dabhade, G.B.
    • 대한화학회지
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    • 제61권4호
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    • pp.157-162
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    • 2017
  • In the present study, nanocrystalline mixed metal oxide, $CuMnO_3$ catalyst have been synthesized by mechanochemical method with green chemistry approach. The synthesized catalyst was characterized by analytical techniques including FTIR, XRD, SEM, TEM and BET surface area. The synthesized catalyst shows high surface area is $121.06m^2/g$ with particle size 18 nm. The one pot four component synthesis of substituted 2-phenyl-4(3H) quinazolinone from the reaction of anthranilic acid, benzoyl chloride, hydrazine hydrate and substituted benzaldehyde in presence of $CuMnO_3$ nanocatalyst has been carried out. It affords the corresponding products with high yield (76-95%) in very short reaction time. All the obtained products were characterized with $^1HNMR$, $^{13}CNMR$, FTIR and EIMS.

재사용이 가능한 MFB로부터 AMCA의 합성 공정 개발 (Practical Process Development of AMCA from Recyclable Source MFB)

  • 김종천;류영;김석찬
    • 공업화학
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    • 제27권5호
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    • pp.508-511
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    • 2016
  • 재활용이 가능한 자원인 MFB를 출발 물질로 하여 AMCA의 합성을 진행하였으며, AMBA로부터 AMCA로의 최적의 상업화 합성 조건을 찾고자 촉매, 수소 압력, 반응 온도, 반응 시간 같은 공정 변수를 조사하였다. 최적의 조건은 촉매는 [5% Pd/C : 5% Pt/C : 5% Rh/C (1 : 1 : 1)]의 복합 촉매를 반응 시간은 8 h, 반응 온도는 $130^{\circ}C$, 압력은 30 bar일 때(수율 90%, 순도 99.9%)임을 확인하였다.

Peroxopolyoxotungsten-based Ionic Hybrid as a Highly Efficient Recyclable Catalyst for Epoxidation of Vegetable oil with H2O2

  • Wu, Jianghao;Jiang, Pingping;Qin, Xiaojie;Ye, Yuanyuan;Leng, Yan
    • Bulletin of the Korean Chemical Society
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    • 제35권6호
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    • pp.1675-1680
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    • 2014
  • A peroxopolyoxotungsten-based ionic hybrid was synthesized by anion-change of peroxopolyoxometalate (POM) $PW_4O{_{24}}^{3-}$ with dicationic long-chain alkyl imidazolium ionic liquids. The characterization was conducted by FT-IR, TGA, $^1H$-NMR and CHN Elemental analyses. Its catalytic performance was evaluated by the epoxidation of soybean oil with $H_2O_2$ under solvent-free condition, including testing of organic cations influence, catalytic reusability and reaction conditions. The catalyst was proved to be a highly efficient recyclable catalyst for epoxidation of various vegetable oils with $H_2O_2$, showing high $H_2O_2$ utilization efficiency, high catalytic activity, convenient recovery and good reuse ability.

Montmorillonite K-10 Clay as an Efficient Reusable Heterogeneous Catalyst for the Solvent-Free Microwave Mediated Synthesis of 5-Substituted 1H-Tetrazoles

  • Marvi, Omid;Alizadeh, Abdolhamid;Zarrabi, Saeid
    • Bulletin of the Korean Chemical Society
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    • 제32권11호
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    • pp.4001-4004
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    • 2011
  • Various 5-substituted 1H-tetrazole derivatives were synthesized in a simple and environmentally benign method from the reaction of aryl and benzyl nitriles with sodium azide in solvent-free media using montmorillonite K-10 clay as solid recyclable heterogeneous acidic catalyst and microwave irradiation in good yields and short reaction times.