• 제목/요약/키워드: Reactive synthesis

검색결과 263건 처리시간 0.034초

적색 항균성 반응염료의 합성과 염색특성 (Synthesis of Antibiotic Red Reactive Dye and Its Dyeing Property)

  • 김이진;김삼수;김준호
    • 한국염색가공학회지
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    • 제16권2호
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    • pp.15-24
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    • 2004
  • The antibiotic reactive dye was synthesized by coupling of reactive chromagen with diazotised silver sulfadiazine for an antibiotic property. The highly reactive MCT(monochlorotriazine) and DCT (dichlorotriazine) type functional groups which have heterocyclic ring and moderately reactive VS-type dye that has good dyeability were used for reactivity. The synthesized antibiotic reactive dye is expected to impart the antibiotic function with high durability on cotton fabric only by one-step dyeing process without further finishing treatment. The synthesis of antibiotic dye was easily proceeded thorough diazotisation of silver sulfadiazine and coupling with suitable chromogen. The dyeability of synthesized dye for cotton fabrics was excellent and the dyed fabrics showed good level of lightfastness, resistance to washing and rubbing. The antibiotic tests revealed that the dyed cotton fabrics with the synthesized dye had very good antibiotic properties.

시나리오 기반 명세 모델로부터 반응형 시스템 모델 개발 (Developing a Reactive System Model from a Scenario-Based Specification Model)

  • 권령구;권기현
    • 인터넷정보학회논문지
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    • 제13권1호
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    • pp.99-106
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    • 2012
  • 다수의 오브젝트로 구성된 반응형 시스템을 모델링 하거나 디자인하기 위해 외부의 입력 및 오브젝트들간의 상호작용을 분석하는 것은 중요하고 어려운 문제이다. 또한, 반응형 시스템이 요구 사항들을 모든 가능한 환경 하에서 올바르게 만족하는지를 확인하는 것은 많은 노력이 필요하다. 본 논문에서는 요구 사항들을 기존에 다양한 분야에서 사용되는 시나리오 명세 언어인 MSC(Message Sequence Chart)에 대해 구문 및 의미를 확장한 LSC(Live Sequence Chart)를 이용하여 반응형 시스템에 적합한 시나리오 기반 명세 모델을 만든다. 그리고 LTL Synthesis를 통해 각 오브젝트에 대하여 모든 요구 사항을 올바르게 만족하는 반응형 시스템 모델을 자동으로 생성한다. 마지막으로 생성된 반응형 시스템 모델로부터 의미적으로 동일한 코드로 변환하는 과정을 반복함으로써 전체 반응형 시스템을 개발하는 방법을 제안한다.

Synthesis and characterization of Reactive Banana-Shaped Mesogens

  • Choi, Min-Ho;Choi, E-Joon;Kim, Young-Chul;Park, Sang-Hyon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.854-857
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    • 2006
  • The synthesis of ester type, banana-shaped, photo - crosslinkable mesogens is described. The reactive mesogens, derivatives of 1,3-phenylene bis{4-[4'- (alken-1-yloxy)-biphenyl-4-carboxylate]benzoate}s, were synthesized varying the length of alkyl end groups. The obtained monomers and polymers were characterized by FT/IR, NMR spectroscopy, DSC, polarized optical microscopy, and X-ray diffractometry.

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Reactive Synthesis of ZrB2-based Ultra High Temperature Ceramics

  • Liu, Hai-Tao;Zhang, Guo-Jun
    • 한국세라믹학회지
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    • 제49권4호
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    • pp.308-317
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    • 2012
  • Reactive processing, such as reactive hot pressing (RHP) and reactive spark plasma sintering (R-SPS), is effective densification method to prepare $ZrB_2$-based ultra high temperature ceramics (UHTCs). The present paper reviewed some typical reactive processing of $ZrB_2$-based UHTCs. All the reactions from the starting materials in the reactive processing are thermodynamically favorable, which generate enough energy and driving force for the densification of the final products under a relatively low temperature. Besides, compared with non-reactive processing, anisotropic $ZrB_2$ grains, such as $ZrB_2$ platelets, can only be obtained in the reactive processing, resulting in an improvement of the mechanical properties.

환경 스트레스, 활성산소와 스트레스-에틸렌 간의 상호관계

  • 이호준;오승은
    • The Korean Journal of Ecology
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    • 제17권1호
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    • pp.91-100
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    • 1994
  • 비록 스트레스의 종류는 다를지라도, 환경 스트레스들은 공통적으로 식물채 내의 활성 산소의 양을 증가시킨다. 활성산소에 의하여 스트레스-에틸렌의 생성량은 증가하고 결국 식물체의 노화는 촉진된다. 반면에, 활성산소 분해 효소들과 antioxidiant들에 의하여 활성산소에 의한 스트레스-에틸렌 생성이 제한될 경우 한정된 양의 에틸렌에 의하여 스트레스에 대한 저항이 유도될 가능성이 있다.

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Application of Living Ionic Polymerizations to the Design of AB-Type Comb-like Copolymers of Various Topologies and Organizations

  • Lanson, David;Ariura, Fumi;Schappacher, Michel;Borsali, Redouane;Deffieux, Alain
    • Macromolecular Research
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    • 제15권2호
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    • pp.173-177
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    • 2007
  • Living anionic and cationic polymerizations have been combined to prepare various types of comb-like copolymers composed of polystyrene (PS) and polyisoprene (PI) blocks, with a precisely controlled architecture. According to the relative placement of these elementary building blocks, combs with randomly distributed PS and PI or with poly(styrene-b-isoprene) diblock branches (I & II, respectively) can be prepared. The reaction procedure initially includes the synthesis of a poly(chloroethylvinyl ether) using living cationic polymerization, which is used as the reactive backbone to successively graft $PS^-Li^+$ and $PI^-Li^+$ or $PI-b-PS^-Li^+$ to obtain structures (I) or (II). The synthesis of Janus-type PS-comb-b-PI-combs (III) initially involves the synthesis of a diblock backbone using living cationic polymerization, which bears two distinct reactive functions having either a protected or activated form. Living $PS^-Li^+$ and $PI^-Li^+$ are then grafted, in two separate steps, onto each of the reactive functions of the backbone, respectively.

Asymmetric Ring Opening of Epoxides Catalyzed by Novel Heterobimetallic Schiff-Bases Containing Transition Metal Salts

  • Kawthekar, RahulB;Bi, Wentao;Kim, Geon-Joong
    • Bulletin of the Korean Chemical Society
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    • 제29권2호
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    • pp.313-318
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    • 2008
  • An enantioselective ring opening of racemic terminal epoxides has been achieved by using heterobimetallic cobalt salen complexes with variety of nucleophiles. They were proven to be highly enantioselective and reactive for the synthesis of valuable chiral building blocks in enantio-riched forms up to 98% ee.

폴리프로필렌 纖維用 反應性染料의 合成 (Synthesis of Reactive Dye for Polypropylene Fiber)

  • 임용진;이학기
    • 대한화학회지
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    • 제23권6호
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    • pp.412-416
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    • 1979
  • 폴리프로필렌纖維는 他纖維에 比하여 機械的, 化學的性質이 매우 優秀하나 難染性 때문에 衣料用으로는 別로 쓰여지지 않고 있다. 폴리프로필렌의 染色性을 向上시키기 爲한 많은 硏究와 特許가 나와있으나 이들 大部分은 纖維의 개질등에 의한 방법으로서, 纖維에 직접, 견고한 染色을 할 수 있는 染料의 硏究는 거의 없다. 著者들은 카르벤을 生成시키므로써 他 纖維에는 勿論 폴리프로필렌纖維에 直接 染色될 수 있는 새로운형의 反應性染料를 合成하였다. 卽 알데히드基를 가지는 分散染料와 토실히드라진으로부터 合成한 새로운 反應性染料로서 폴리프로필렌을 染色한 結果, 濃色의 堅固한 染色物을 얻을 수 있었다.

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Synthesis and characterization of sugarcane bagasse/zinc aluminium and apple peel/zinc aluminium biocomposites: Application for removal of reactive and acid dyes

  • Safa, Yusra;Tariq, Saadia Rashid;Bhatti, Haq Nawaz;Sultan, Misbah;Bibi, Ismat;Nouren, Shazia
    • Membrane and Water Treatment
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    • 제9권5호
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    • pp.301-307
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    • 2018
  • In this research work, synthesis of sugarcane bagasse/zinc aluminium biocomposite and apple peel/zinc aluminium biocomposite and their application for removal of Reactive Red-241 and Acid Orange-7, respectively, was studied using various parameters. At pH 2 the sorption was the highest for both dyes. The trend showed that the dye sorption declined by decreasing the biocomposite dose and enhanced by increasing the dye concentration and temperature. Equilibrium was achieved at 60 minutes for Reactive Red-241 onto sugarcane bagasse/zinc aluminium biocomposite and 90 minutes for Acid Orange-7 onto apple peel/zinc aluminium biocomposite.The research data was good fitted to pseudo-2nd-order kinetic model and Langmuir isotherm. FT-IR analysis was used to confirm the biosorption of the selected dyes at the surface of biosorbent through various binding sites. Surface morphology modification of both biocomposites before and after biosorption was inspected through SEM. Crystallinity of biocomposite was examined through XRD analysis. It was implied that sugarcane bagasse/ zinc aluminium biocomposite and apple peel/ zinc aluminium biocomposite are good adsorbents for dyes elimination from aqueous solutions.

ATP and Purinergic Receptor Agonists Stimulate the Mitogen-Activated Protein Kinase Pathway and DNA Synthesis in Mouse Mammary Epithelial Cells

  • Yuh In-Sub
    • Reproductive and Developmental Biology
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    • 제28권4호
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    • pp.211-219
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    • 2004
  • The effects of adenosine 5'-triphosphate (ATP) and ATP analogs, P/sub 2y/ purinoceptor agonists, on growth of normal mouse mammary epithelial cells (NMuMG) were examined. Cells were plated onto 24 well plates in DMEM supplemented with 10 % fetal calf serum. After serum starvation for 24 hours, ATP, P/sub 2y/ purinoceptor agonists (AdoPP[NH]P, ATP-α-S, ATP-γ-S, β, γ-me-ATP and 2me-S-ATP), P/sub 2u/ purinoceptor agonist (UTP) and P/sub 2y/ purinoceptor antagonists (Reactive Blue 2, more selective to P/sub 2y/ receptor than PPADS; PPADS) were added. DNA synthesis was estimated as incorporation of 3H-thymidine into DNA (1 hour pulse with 1 μ Ci/ml, 18~19 hours after treatment). ATP, Adopp[NH]P, ATP-α-S or ATP-γ-S, significantly increased DNA synthesis at 1, 10 and 100 μM concentrations with dose-dependency (P<0.05), and the maximum responses of ATP and ATP analogs were shown at 100 μM concentration (P<0.05). The potency order of DNA synthesis was ATP≥ATP- γ -S>Adopp [NH]P>ATP-α-S. β, γ -me-ATP, 2me-S-ATP and UTP did not increase DNA synthesis. In autoradiographic analysis of percentage of S-phase cells, similar results were observed to those of DNA synthesis. Addition of 1, 10 or 100 μM Reactive Blue 2 or PPADS significantly decreased ATP (100 μM)-induced DNA synthesis, however, PPADS was less effective than Reactive Blue 2. In Elvax 40P implant experiment, ATP directly stimulated mammary endbud growth in situ suggesting the physiological regulator of ATP in mammary growth. ATP 100 μM rapidly increased MAPK activity, reaching a maximum at 5 min and then gradually decreasing to the base level in 30 min. ATP analogs, Adopp[NH]P and ATP-γ-S also increased MAPK activity, however, β, γ-me-ATP and 2me-S-ATP did not. The inhibitor of the upstream MAPK kinase (MEK), PD 98059 (25 μM), effectively reduced ATP (100 μM) or EGF(10 ng/ml, as positive control)-induced MAPK activity and DNA synthesis (P<0.05). These results indicate that ATP-induced DNA synthesis was prevented from the direct inhibition of MAPK kinase pathway. Overall results support the hypothesis that the stimulatory effects of normal mouse mammary epithelial growth by addition of ATP or ATP analogs are mediated through mammary tissue specific P/sub 2y/ purinoceptor subtype, and MAPK activation is necessary for the ATP-induced cell growth.