• Title/Summary/Keyword: Reactive synthesis

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Synthesis of Antibiotic Red Reactive Dye and Its Dyeing Property (적색 항균성 반응염료의 합성과 염색특성)

  • 김이진;김삼수;김준호
    • Textile Coloration and Finishing
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    • v.16 no.2
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    • pp.15-24
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    • 2004
  • The antibiotic reactive dye was synthesized by coupling of reactive chromagen with diazotised silver sulfadiazine for an antibiotic property. The highly reactive MCT(monochlorotriazine) and DCT (dichlorotriazine) type functional groups which have heterocyclic ring and moderately reactive VS-type dye that has good dyeability were used for reactivity. The synthesized antibiotic reactive dye is expected to impart the antibiotic function with high durability on cotton fabric only by one-step dyeing process without further finishing treatment. The synthesis of antibiotic dye was easily proceeded thorough diazotisation of silver sulfadiazine and coupling with suitable chromogen. The dyeability of synthesized dye for cotton fabrics was excellent and the dyed fabrics showed good level of lightfastness, resistance to washing and rubbing. The antibiotic tests revealed that the dyed cotton fabrics with the synthesized dye had very good antibiotic properties.

Developing a Reactive System Model from a Scenario-Based Specification Model (시나리오 기반 명세 모델로부터 반응형 시스템 모델 개발)

  • Kwon, Ryoung-Kwo;Kwon, Gi-Hwon
    • Journal of Internet Computing and Services
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    • v.13 no.1
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    • pp.99-106
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    • 2012
  • It is an important and a difficult task to analyze external inputs and interactions between objects for designing and modeling a reactive system consisting of multiple object. Also the reactive system is required huge efforts on confirm it can satisfy requirements under all possible circumstances. In this paper, we build from requirements to a scenario-based specification model using LSC(Live Sequence Chart) extending MSC(Message Sequence Chart) with richer syntax and semantic. Then the reactive system model satisfying all requirements for each object in this system can be automatically created through LTL Synthesis. Finally, we propose a method of reactive system development by iterative process transforming a reactive system model to codes.

Synthesis and characterization of Reactive Banana-Shaped Mesogens

  • Choi, Min-Ho;Choi, E-Joon;Kim, Young-Chul;Park, Sang-Hyon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.854-857
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    • 2006
  • The synthesis of ester type, banana-shaped, photo - crosslinkable mesogens is described. The reactive mesogens, derivatives of 1,3-phenylene bis{4-[4'- (alken-1-yloxy)-biphenyl-4-carboxylate]benzoate}s, were synthesized varying the length of alkyl end groups. The obtained monomers and polymers were characterized by FT/IR, NMR spectroscopy, DSC, polarized optical microscopy, and X-ray diffractometry.

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Reactive Synthesis of ZrB2-based Ultra High Temperature Ceramics

  • Liu, Hai-Tao;Zhang, Guo-Jun
    • Journal of the Korean Ceramic Society
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    • v.49 no.4
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    • pp.308-317
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    • 2012
  • Reactive processing, such as reactive hot pressing (RHP) and reactive spark plasma sintering (R-SPS), is effective densification method to prepare $ZrB_2$-based ultra high temperature ceramics (UHTCs). The present paper reviewed some typical reactive processing of $ZrB_2$-based UHTCs. All the reactions from the starting materials in the reactive processing are thermodynamically favorable, which generate enough energy and driving force for the densification of the final products under a relatively low temperature. Besides, compared with non-reactive processing, anisotropic $ZrB_2$ grains, such as $ZrB_2$ platelets, can only be obtained in the reactive processing, resulting in an improvement of the mechanical properties.

환경 스트레스, 활성산소와 스트레스-에틸렌 간의 상호관계

  • 이호준;오승은
    • The Korean Journal of Ecology
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    • v.17 no.1
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    • pp.91-100
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    • 1994
  • Although the types of stress are various, environmental stresses generally increase the amounts of reactive oxygen species in plants. These reactive oxygen species stimulate stress-ethylene synthesis and accelerate senescence of plants. However, when stress-ethylene synthesis is suppressed through antioxidative enzymes and antioxidants, the resistance of plants against stress could be induced by limited production of ethylene.

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Application of Living Ionic Polymerizations to the Design of AB-Type Comb-like Copolymers of Various Topologies and Organizations

  • Lanson, David;Ariura, Fumi;Schappacher, Michel;Borsali, Redouane;Deffieux, Alain
    • Macromolecular Research
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    • v.15 no.2
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    • pp.173-177
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    • 2007
  • Living anionic and cationic polymerizations have been combined to prepare various types of comb-like copolymers composed of polystyrene (PS) and polyisoprene (PI) blocks, with a precisely controlled architecture. According to the relative placement of these elementary building blocks, combs with randomly distributed PS and PI or with poly(styrene-b-isoprene) diblock branches (I & II, respectively) can be prepared. The reaction procedure initially includes the synthesis of a poly(chloroethylvinyl ether) using living cationic polymerization, which is used as the reactive backbone to successively graft $PS^-Li^+$ and $PI^-Li^+$ or $PI-b-PS^-Li^+$ to obtain structures (I) or (II). The synthesis of Janus-type PS-comb-b-PI-combs (III) initially involves the synthesis of a diblock backbone using living cationic polymerization, which bears two distinct reactive functions having either a protected or activated form. Living $PS^-Li^+$ and $PI^-Li^+$ are then grafted, in two separate steps, onto each of the reactive functions of the backbone, respectively.

Asymmetric Ring Opening of Epoxides Catalyzed by Novel Heterobimetallic Schiff-Bases Containing Transition Metal Salts

  • Kawthekar, RahulB;Bi, Wentao;Kim, Geon-Joong
    • Bulletin of the Korean Chemical Society
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    • v.29 no.2
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    • pp.313-318
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    • 2008
  • An enantioselective ring opening of racemic terminal epoxides has been achieved by using heterobimetallic cobalt salen complexes with variety of nucleophiles. They were proven to be highly enantioselective and reactive for the synthesis of valuable chiral building blocks in enantio-riched forms up to 98% ee.

Synthesis of Reactive Dye for Polypropylene Fiber (폴리프로필렌 纖維用 反應性染料의 合成)

  • Yong-Jin Lim;Hak-ki Lee
    • Journal of the Korean Chemical Society
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    • v.23 no.6
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    • pp.412-416
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    • 1979
  • Although isotactic polypropylene gives an excellent fiber having high tenacity, abrasion resistance and chemical stability, it has not been widely used as a fabric for chlothing because of its poor dyeability. A number of methods for improvement of its dyeability have been proposed, but they were too complicated and/or gave damage its original excellent properties of polypropylene. We now wish to report the synthesis of a new reactive dye for polypropylene fiber by means of carbenic process. A reactive dye was synthesized from azo disperse dye having an aldehyde group and tosylhydrazine. By using this synthesized reactive dye, polypropylene fiber was dyed to thick and fast color.

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Synthesis and characterization of sugarcane bagasse/zinc aluminium and apple peel/zinc aluminium biocomposites: Application for removal of reactive and acid dyes

  • Safa, Yusra;Tariq, Saadia Rashid;Bhatti, Haq Nawaz;Sultan, Misbah;Bibi, Ismat;Nouren, Shazia
    • Membrane and Water Treatment
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    • v.9 no.5
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    • pp.301-307
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    • 2018
  • In this research work, synthesis of sugarcane bagasse/zinc aluminium biocomposite and apple peel/zinc aluminium biocomposite and their application for removal of Reactive Red-241 and Acid Orange-7, respectively, was studied using various parameters. At pH 2 the sorption was the highest for both dyes. The trend showed that the dye sorption declined by decreasing the biocomposite dose and enhanced by increasing the dye concentration and temperature. Equilibrium was achieved at 60 minutes for Reactive Red-241 onto sugarcane bagasse/zinc aluminium biocomposite and 90 minutes for Acid Orange-7 onto apple peel/zinc aluminium biocomposite.The research data was good fitted to pseudo-2nd-order kinetic model and Langmuir isotherm. FT-IR analysis was used to confirm the biosorption of the selected dyes at the surface of biosorbent through various binding sites. Surface morphology modification of both biocomposites before and after biosorption was inspected through SEM. Crystallinity of biocomposite was examined through XRD analysis. It was implied that sugarcane bagasse/ zinc aluminium biocomposite and apple peel/ zinc aluminium biocomposite are good adsorbents for dyes elimination from aqueous solutions.

ATP and Purinergic Receptor Agonists Stimulate the Mitogen-Activated Protein Kinase Pathway and DNA Synthesis in Mouse Mammary Epithelial Cells

  • Yuh In-Sub
    • Reproductive and Developmental Biology
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    • v.28 no.4
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    • pp.211-219
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    • 2004
  • The effects of adenosine 5'-triphosphate (ATP) and ATP analogs, P/sub 2y/ purinoceptor agonists, on growth of normal mouse mammary epithelial cells (NMuMG) were examined. Cells were plated onto 24 well plates in DMEM supplemented with 10 % fetal calf serum. After serum starvation for 24 hours, ATP, P/sub 2y/ purinoceptor agonists (AdoPP[NH]P, ATP-α-S, ATP-γ-S, β, γ-me-ATP and 2me-S-ATP), P/sub 2u/ purinoceptor agonist (UTP) and P/sub 2y/ purinoceptor antagonists (Reactive Blue 2, more selective to P/sub 2y/ receptor than PPADS; PPADS) were added. DNA synthesis was estimated as incorporation of 3H-thymidine into DNA (1 hour pulse with 1 μ Ci/ml, 18~19 hours after treatment). ATP, Adopp[NH]P, ATP-α-S or ATP-γ-S, significantly increased DNA synthesis at 1, 10 and 100 μM concentrations with dose-dependency (P<0.05), and the maximum responses of ATP and ATP analogs were shown at 100 μM concentration (P<0.05). The potency order of DNA synthesis was ATP≥ATP- γ -S>Adopp [NH]P>ATP-α-S. β, γ -me-ATP, 2me-S-ATP and UTP did not increase DNA synthesis. In autoradiographic analysis of percentage of S-phase cells, similar results were observed to those of DNA synthesis. Addition of 1, 10 or 100 μM Reactive Blue 2 or PPADS significantly decreased ATP (100 μM)-induced DNA synthesis, however, PPADS was less effective than Reactive Blue 2. In Elvax 40P implant experiment, ATP directly stimulated mammary endbud growth in situ suggesting the physiological regulator of ATP in mammary growth. ATP 100 μM rapidly increased MAPK activity, reaching a maximum at 5 min and then gradually decreasing to the base level in 30 min. ATP analogs, Adopp[NH]P and ATP-γ-S also increased MAPK activity, however, β, γ-me-ATP and 2me-S-ATP did not. The inhibitor of the upstream MAPK kinase (MEK), PD 98059 (25 μM), effectively reduced ATP (100 μM) or EGF(10 ng/ml, as positive control)-induced MAPK activity and DNA synthesis (P<0.05). These results indicate that ATP-induced DNA synthesis was prevented from the direct inhibition of MAPK kinase pathway. Overall results support the hypothesis that the stimulatory effects of normal mouse mammary epithelial growth by addition of ATP or ATP analogs are mediated through mammary tissue specific P/sub 2y/ purinoceptor subtype, and MAPK activation is necessary for the ATP-induced cell growth.