• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.5
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• pp.143-149
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• 2020

The purpose of this study is to manufacture a variable density - hybrid lattice structure control by filling the pore of the metal addictive manufactured lattice structure with lightweight reactive acrylic compounds(RAC). To apply the variable density - hybrid lattice structure to the construction industry, the enhancing adhesion - reactive acrylic compounds(EA-RAC) which increased the adhesion strength was manufactured by adding ordinary portland cement to the RAC. Finally, the EA-RAC was filled into the lattice structure to test the specific density, water absorption, and adhesion strength of the variable density - hybrid lattice structure. The results were obtained with density controllable, water absorption less than 1.0%, and 1-day bonding strength of 1.78 MPa to 1.98 MPa.

• Elastomers and Composites
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• v.14 no.2
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• pp.83-102
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• 1979

The purpose of this dissertation is to study some of the vulcanization characteristics of rubber-bound antioxidants such as G-1, [N-(3-methacryloyloxy-2-hydroxypropyl)-N'-phenyl-p-phenylene diamine] and acryl, acrylamide & acrylester substituted hindered phenols. The influence of these antioxidants upon vulcanization characteristics in NR and SBR compounds in the presence of vulcanizing accelerators such as MSA, TT, DM, M & D was evaluated by means of Oscillationg Disk Cure Meter. The comparison was also made between the influence of rubber-bound antioxidants and that of conventional non-reactive antioxidants such as N-alkyl substituted PADA series. Regarding the influence of reactive type antioxidant G-1 mixed with accelerator TT upon vulcanization characteristics, rapid onset of vulcanization and higher degree of cross-linking were discovered, whereas in the case of accelerator M and DM, the result was slow onset of vulcanization and lesser degree of cross-linking. The comparison of vulcanizing characteristics among acrylic substituted hindered phenols as antioxidants was made under several vulcanization accelerator systems. Under such systems, MSA-S combined accelerator caused the onset of vulcanization to slow down and lowered the degree of cross-linking. Finally in the case of hindered phenol derivatives containing longer substituent, the delayed onset of vulcanization and the lowered degree of cross-linking could be discerned.

• Toxicological Research
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• v.14 no.4
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• pp.557-562
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• 1998

Allyl alcohol is metabolized in the liver through two steps, first to reactive acrolein by alcohol dehydrogenase (ADH), subsequently to acrylic acid by aldehyde dehydrogenase (ALDH). Since ethanol could compete the same enzymes to be metabolized in the liver, we have determined the plasma concentrations of allyl alcohol and ethanol followed by combined treatment. Pretreatment of rats with 2g/kg ethanol followed by ip administration of 40mg/kg allyl alcohol increased the lethality significantly. Determination of in vivo blood concentrations revealed that ethanol pretreatment caused the apparent decrease in allyl alcohol clearance, whereas acetaldehyde level in blood increased significantly by allyl alcohol treatment, as determined by head space GC analysis. Treatment of 4-methylpyrazole, an inhibitor of ADH, delayed allyl alcohol elimination significantly and reduced its lethality. Collectively, these findings suggested that reduction of allyl alcohol clearance in the presence oj ethanol was mediated through ADH competitive inhibition.

• Journal of the Korean Chemical Society
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• v.30 no.2
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• pp.237-242
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• 1986

(E,E)-p-Phenylene diacrylic acid derivatives were prepared in moderate to good yields by the palladium catalyzed vinylation of 4-bromoiodobenzene or 4-diiodobenzene with 2 equiv of acrylic acid derivatives in the presence of triethylamine. 4-Diiodobenzene was more reactive than 4-bromoiodobenzene in the above reactions and the reactions were proceeded stereospecifically. (E,E)-p-Phenylene diacrylic acid derivatives and several other 1,4-diolefinic aromatic compounds were also synthesized by utilizing the selective vinylation of 4-bromoiodobenzene.

• Journal of Environmental Impact Assessment
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• v.27 no.6
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• pp.582-594
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• 2018

In this study, the vertical and horizontal flow wetlands were combined in series to create conditions for flow in the exhalation and anaerobic state with the aim of monitoring the variability and reduction of dissolved organic matterin the bio-reactive artificial wetlands, and the performance assessment was conducted as acrylic reaction groups by designing artificial wetlands that filled the functionalresiduals. In case of artificial wetlands in vertical and horizontal planes, the concentration of dissolved oxygen (DO) in the reaction tank was measured as 2.7 mg/L in the vertical flow wetlands under exhalation, and N.D. in the horizontal flow artificial wetlands under anaerobic conditions. The test was carried out by changing the operation time to 140 min, 80 min, and 60 min. The test was conducted with the same natural operation time of 20 min depending on the operation time. All hours of operation were shown to be due to microbial activity. In 3D-EEM, it was found that the longer the driving time was taken, the more reduction the organic compounds in the areas of insoluble human resources, III and V. Further research on the mechanism analysis of future reduction effects is expected to be carried out, but the findings are expected to contribute to the development of technologies for reducing obfuscated substances using artificial wetlands in the future.