• Title/Summary/Keyword: Reaction zone

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Hydrogen Production with High Temperature Solar Heat Thermochemical Cycle Using Dual-zone Reactor and CeO2/ZrO2 Foam Device (Dual-zone reactor와 CeO2/ZrO2 Foam Device를 이용한 고온 태양열 열화학 싸이클의 수소 생산)

  • Cho, Ji-Hyun;Seo, Tae-Beom
    • Journal of the Korean Solar Energy Society
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    • v.37 no.5
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    • pp.27-37
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    • 2017
  • In this study, an artificial solar simulator composed of a 2.5 kW Xe-Arc lamp and mirror reflector was used to carry out the solar thermal two step thermochemical water decomposition cycle which can produce high efficiency continuous hydrogen production. Through various operating conditions, the change of hydrogen production due to the possibility of a dual-zone reactor and heat recovery were experimentally analyzed. Based on the reaction temperature of Thermal-Reduction step and Water-Decomposition step at $1,400^{\circ}C$ and $1,000^{\circ}C$ respectively, the hydrogen production decreased by 23.2% under the power off condition, and as a result of experiments using heat recovery technology, the hydrogen production increased by 33.8%. Therefore, when a thermochemical two-step water decomposition cycle is conducted using a dual-zone reactor with heat recovery, it is expected that the cycle can be operated twice over a certain period of time and the hydrogen production amount is increased by at least 53.5% compared to a single reactor.

A study of object analysis in safety management zone (안전관리 지역 내의 객체 분석 연구)

  • Park, Sang-Joon;Kim, Kwan-Joong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.12
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    • pp.5873-5877
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    • 2011
  • In this paper, we propose a study of analysis to the mobility of object such like pedestrian in safety management zone. If unusual situation is detected in safety management zone, it's designed that previous agreed mission will be processed. By human resource, safety management zone cannot be detected continuously so that through the induction of such detection system the reliability of area can be obtained. Hence, in this paper we propose the reaction scheme to detect special situation by object detection. By using sensor based processing system proposed by this paper, the detection of mobility and unusual situation can be implemented.

Studies on Reduction of Harmful Compound and Combustibility of $Na_3$ Citrate-treated Cigarette (시트르산나트륨첨가(添加)에 의(依)한 담배의 연소성(燃燒性) 및 유해물감소(有害物減少)에 관한 연구(硏究))

  • Kim, Ki-Hwan;Bae, Hyo-Won;Lee, Yong-Chong;Kim, Man-Uk;Park, Taek-Kyu
    • Applied Biological Chemistry
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    • v.20 no.1
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    • pp.117-122
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    • 1977
  • Development of new burning additives against nitrate salts used in past tobacco industry examined to reduce harmful nitrogenous compounds in smoke. Among several additives treated, the best effect by means of elevation of combustibility and reduction of tar and nicotin contents in smoke was observed by adding sodium citrate from 0.6 to 1% in tabacco. The following results were obtained through investigating combustibility, chemical composition, and differential thermal analysis of the tabacco treated with the buring additives. 1) The close relation was observed between the levels of the smoke components and combustibility of the treated tabacco. 2) Differential thermal analysis (D.T.A.) of citrate-treated tobacco shows an increase in H. Value and a decrease in L. Value as compared with other tobacco sample. 3) The D.T.A. of sodium-nitrate and sodium-citrate shows that sodium-nitrate gives endothermal reaction at $270^{\circ}$ and $310^{\circ}$ and sodium citrate gives exothermal reaction at $290^{\circ}$ with endothermal reaction at $170^{\circ}\;and\;310^{\circ}$. 4) $Na_3-citrate-treated$ tobacco shows an increase in smoke generation between room temperature and $350^{\circ}$ (Zone A) and a decrease in smoke generation between $350^{\circ}$ and $900^{\circ}$ (Zone B) compared with untreated tobacco. The smoke from these tobacco also contains lower levels of Tar, Nicotine, Phenols, Nitrogen oxides and Benzpyrene, and elevation of static Burning rate.

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The Effect of Casting Conditions on the Fluidity during Lost Foam Casting of Al Alloy (알루미늄 합금의 소실모형주조 시 유동도에 미치는 주조 조건의 영향)

  • Shin, Seung-Ryoul;Han, Sang-Won;Lee, Kyong-Whoan;Lee, Zin-Hyoung
    • Journal of Korea Foundry Society
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    • v.24 no.1
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    • pp.34-39
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    • 2004
  • The effects of casting condition and hot melt glue during Lost Foam Casting were investigated on the fluidity of Al alloy melt. The fluidity increased linearly with increasing pouring temperature in thick castings but non-linearly in thin casting due to the difference in main heat flow direction. The metal flow velocity was in range of $0.5{\sim}2.7$ cm/s in no evacuation condition and the minimum value of it was measured after the melt flow through the hot melt barrier. The mold evacuation improved the metal flow velocity by around $0.5{\sim}1$ cm/s. And the reaction zone layer thickness was about 1 cm in no-evacuation conditions but about 0.6 cm in mold evacuation condition of 710 torr due to the easier removal of pyrolsis product of EPS. And hot melt barrier thickness of 0.6 mm increased the reaction zone layer thickness up to about 2.5 cm. The fluidity decreased remarkably with an enlarged thickness of hot melt due to a lot of pyrolysis products.

Effects of EGR and Premixedness on NO Formation of Methane/Air Flames (EGR 및 예혼합 정도가 메탄/공기 화염의 NO 생성에 미치는 영향)

  • Lee, Won-Nam;Lee, Woong-Jae
    • Journal of the Korean Society of Combustion
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    • v.4 no.2
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    • pp.63-74
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    • 1999
  • The effects of EGR and premixedness on NO formation have been numerically investigated. The flame structure is classified into three categories; premixed flame($=1)$, rich/lean premixed flame(${\alpha}=0.6$ and 0.8) and diffusion flame(${\alpha}=0$). NO formation/destruction mechanisms are assorted to thermal, reburn and Fenimore mechanisms. The temperature of unburned gas is arranged to 298 and 500 K to have access to the condition in a real internal combustion engine. The results show that all three NO formation/destruction reaction rates in the fuel rich flame zone could be decreased by EGR for rich/lean premixed flames, while those in the fuel lean flame zone are not significantly changed. Near the stagnation plane, however, only the thermal NO reaction rate is decreased. The contribution of reburn and Fenimore mechanisms for the net NO production becomes less significant as the premixedness of a flame increases. The larger amount of NO reduction with EGR is expected under the higher temperature and/or higher fuel/air premixedness conditions due to the increased contribution of the thermal mechanism. The role of Fenimore and reburn mechanisms could be important for rich premixed and diffusion flames; therefore, the effect of EGR on NO reduction could vary with fuel/air premixedness. The premixedness of a partially premixed flame changes the flame structure and could affect the NO production characteristics.

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Fabrication of Aluminum Alloy Composites Reinforced with SiC whisker an $Al_2O_3-SiO_2$ Short Fiber by Squeeze Casting (용탕단조에 의한 $Al_2O_3-SiO_2$ 단섬유 및 SiC whisker강화 알루미늄 합금기 복합재료의 제조)

  • Hong, Sung-Kil;Yun, Jung-Yul;Choi, Jung-Chul
    • Journal of Korea Foundry Society
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    • v.17 no.1
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    • pp.28-35
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    • 1997
  • SiC whisker and $Al_2O_3-SiO_2$ short fiber reinforced AC8A, AC8B and AC8B(J) marix composites were fabricated by squeeze casting method. Preform deformation, change of reinforcement volumefraction and formation of macro-segregation in two composites were investigated by using micro Vickers hardness test, analysis of macro and micro structures with OM, SEM and EDAX. $Al_2O_3-SiO_2$ short fiber preform manufactured with 5% $SiO_2$ binder in this study was considerably deformed and cracked, nevertheless, the short fibers were distributed homogeneously in the composites. In SiC whisker reinforced composites, on the other hand, preform deforming and cracking were not occurred, however, macro segregation zone formed along the infiltration routes by interface reaction during infiltration of molten metal into the preform was observed at center-low area in the composites. The decrease of hardness in the macro segregation zone resulted from the depletion of Si and Mg atoms.

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Analysis of NOx Emissions in Thrbulent Nonpremixed Hydrogen-Air Jet Flames with Coaxial Air (동축 수소 확산화염에서의 NOx 생성 분석)

  • Park, Y.H.;Kim, S.L.;Moon, H.J.;Yoon, Y.B.;Jeung, I.S.
    • Journal of the Korean Society of Combustion
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    • v.5 no.1
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    • pp.19-30
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    • 2000
  • The characteristics of NOx emissions in pure hydrogen nonpremixed flames with coaxial air are analyzed numerically for the three model cases of coaxial air flames classified by varying coaxial air velocity and/or fuel velocity. In coaxial air flames, the flame length is reduced by coaxial air and can be represented as a function of the ratio of coaxial air to fuel velocity. Coaxial air decreases flame reaction zone, resulting in reducing flame residence time significantly. Finally, the large reduction of EINOx is achieved by the decrease of the flame residence time. It is found that because coaxial air can break down the flame self-similarity law, appropriate scaling parameters, which are different from those in the simple jet flames, are recommended. In coaxial air flames, the flame residence time based on the flame volume produces better results than that based on a cube of the flame length. And some portion of deviations from the 1/2 scaling law by coaxial air may be due to the violation of the linear relationship between the flame volume and the flame reaction zone.

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Interaction Effects of Turbulent Flow and Chemical Reaction in a Swirl Combustor (스월연소기의 난류와 화학반응 간섭효과)

  • Sung, Hong-Gye;Kim, Jong-Chan;Yang, Vigor;Cha, Bong-Jun;Ahn, I-Ki
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.04a
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    • pp.71-74
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    • 2007
  • Large Eddy Simulation(LES) has been conducted to insight interaction effects of turbulent flow and chemical reaction of a lean-Premixed swirl combustor. The unsteady turbulent flame is carefully simulated so that the motion of flow and flame can be characterized in detail. Fuel lumps escaping from the primary combustion zone move downstream and consequently produce local hot spots conveying large vortical structures in the azimuthal direction. The correlation between pressure oscillation and unsteady heat release is examined by the spatial and temporal Rayleigh parameter.

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A Study on the Combustion Characteristics of Diffusion Flame Formed in the Wake of Cylindrical Bluff Body (원통형 보염기 후류에 형성되는 확산화염의 연소특성에 관한 연구)

  • An, J.G.;Lim, D.J.;Ro, T.S.;Song, K.K.
    • 한국연소학회:학술대회논문집
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    • 1998.10a
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    • pp.23-30
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    • 1998
  • The stabilization characteristics of diffusion flame formed in the wake of a cylindrical flame holder were investigated. Distribution of turbulence intensity, concentration distribution of combustion gas, and ion currents were measured. The turbulence intensity in the wake of cylindrical- game holder is increased with increase of diameter or blockage ratio of grid. If the auxiliary fuel is injected into recirculation zone, the concentration of $C_3H_8$ is high, but the concentration of $CO_2$ is low at the boundary of recirculation zone. The region with highest average value of ion currents in the middle of flame is moved to the upstream side by the turbulent components of main stream. The flame mass with partially active reaction is moved fast for uniform flow and turbulence generator G3, but the flame mass with relatively slow reaction is moved slowly for turbulence generator G1.

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Synthesis of AlON from Partially Hydrolyzed AlN Powder and its Sintering (부분 가수분해된 AlN 분말로부터 산질화 알루미늄(AlON)의 합성 및 소결)

  • 김두영;최상욱;남건태
    • Journal of the Korean Ceramic Society
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    • v.31 no.11
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    • pp.1362-1368
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    • 1994
  • The hydrolysis of aluminum nitride was increased gradually with increasing reaction time from 1 hrs to 24 hrs and/or with decreasing the addition of the reaction water from 100 mι 100mι. Amorphous aluminum hydrate, formed in the beginning of the reaction, was transformed to bayerite and to pseudoboehmite at below and above 8$0^{\circ}C$, respectively. Aluminum oxynitride was synthesized by heating the partially hydrolyzed aluminum nitride at 1$700^{\circ}C$ for 4 hrs or at 175$0^{\circ}C$ for 30 min. AlON specimen with 1 wt% of Y2O3 that was molded and then sintered pressurelessly at 190$0^{\circ}C$, exhibits 98% of the theoretical density and a translucency of 68% in the visible ray zone.

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