• Journal of the Korean Society of Combustion
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• v.6 no.2
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• pp.36-42
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• 2001

Usually, we use the flame thickness and turbulence scale to classify the flame structure on a phase diagram of turbulent combustion. The flame structure in turbulence is still in debate, and many studies have been done. Since the flame motion is rapid and its reaction zone thickness is very thin, it is difficult to estimate the flame thickness. Here, we propose a new approach to determine the reaction zone thickness based on ion current signals obtained by an electrostatic probe, which has enough time and space resolution to detect flame fluctuation. Since the signal depends on the flow condition and flame curvature, it may be difficult to analyze directly these signals and examine the flame characteristics. However, ion concentration is high only in the region where hydrocarbon-oxygen reactions occur, and we can specify the reaction zone. Based on the reaction zone existing, we estimate the reaction zone thickness. We obtain the thickness of flames both in the cyclone-jet combustor and on a Bunsen burner, compared with theoretically predicted value, the Zeldovich thickness. Results show that the experimentally obtained thickness is almost the same as the Zeldovich thickness. It is concluded that this approach can be used to obtain the local flame structure for modeling turbulent combustion.

• Journal of the Korean Society of Combustion
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• v.11 no.3
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• pp.1-7
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• 2006

A reaction mechanism of methane partial oxidation, which consists of thermal and plasma chemistry reaction pathways, has been investigated using with an arc-jet reactor. The reaction zone of the arc-jet reactor is spatially separated into thermal and non-thermal plasma zone. Methane conversion rates, selectivity of $H_2$ and $C_2$ chemicals in each zone are obtained, which reveals clearly different characteristics of reaction pathways depending on the temperature conditions. The conversion rates obtained in thermal plasma zone is higher than those in non-thermal plasma zone. The selectivity, however, obtained in non-thermal plasma zone is significantly higher than those in thermal plasma zone. Further parametric study on $O_2/C$ ratio, arc length and SED shows that the present process is mainly governed by thermal chemistry pathways.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.5 no.2
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• pp.109-121
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• 1995

Reaction coulples of SiC with cobalt were annealed in an Ar/4 vol% $H_2$ atmosphere at temperatures between $950^{\circ}C$ and $1250^{\circ}C$for various times between 4 and 100 h. At temperatures above $950^{\circ}C$, solid state reactions lead to the formation of various silicides with carbon precipitates. The typical reaction layer sequence was $SiC/CoSi + C/CozSi + C/CozSi/CozSi + C/{\cdot\cdot\}/CO_2Si/CO$ in the reaction zone. The mechanism of the periodic band structure formation with the carbon precipitation behaviour was examined and discussed in terms of reaction kinetics and thermodynamic considerations. The growth of the reaction zone has a square root of time dependence. The reaction kinetics is proposed to estimate the effective reaction constant from the parabolic gowth of the reaction zone. The mechanical properties of the reaction zones were determined by the microhardness test.

• Transactions of the Korean hydrogen and new energy society
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• v.19 no.4
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• pp.276-282
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• 2008

The effects of hydrogen enrichment to methane have been investigated with swirl-stabilized premixed hydrogen-enriched methane flame in a laboratory-scale pre-mixed combustor. The hydrogen-enriched methane fuel and air were mixed in a pre-mixer and introduced to the combustor through different degrees of swirl vanes. The flame characteristics were examined for different amount of hydrogen addition to the methane fuel and different swirl strengths. The hydrogen addition effects and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using micro-thermocouple, particle image velocity meter (PIV) and chemiluminescence techniques to provide information about flow field. The results show that the flame area increases at upstream of reaction zone because of increase in ignition energy from recirculation flow for increase in swirl intensity. The flame area is also increased at the downstream zone by recirculation flow because of increase in swirl intensity which results in higher centrifugal force. The higher combustibility of hydrogen makes reaction faster, raises the temperature of reaction zone and expands the reaction zone, consequently recirculation flow to reaction zone is reduced. The temperature of reaction zone increases with hydrogen addition even though the adiabatic flame temperature of the mixture gas decreases with increase in the amount of hydrogen addition in this experiment condition because the higher combustibility of hydrogen reduces the cooler recirculation flow to the reaction zone.

• Journal of the Korean Society of Combustion
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• v.16 no.3
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• pp.33-40
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• 2011

Combustion experiments were conducted at three different fuels ($CH_4$, $C_2H_4$ and $C_3H_8$) to investigate the effects of combustor pressure (30 ~ -30 kPa) on combustion charateristics and reaction zone structure. Regardless of the fuels, emission index of CO (EICO) increased with decreasing combustor pressure, and EICO of $C_2H_4$ was mostly affected by changing combustor pressure at subatmospheric pressure. In order to observe reaction zone, $OH^*$, $CH^*$ and ${C_2}^*$ chemiluminescence intensity were measured. The sequence of the chemiluminescence intensity peak position was affected by chemical characteristics of fuels rather than changing combustor pressure. The emission zone thickness of $C_2H_4$ and $C_3H_8$, defined by the full width at half maximum (FWHM) of $CH^*$ intensity profile, were increased with decreasing combustor pressure. however, the thickness of $C_2H_4$ exhibited the opposite tendency due to the characteristics of the fuel as the bond structure.

• Journal of Environmental Science International
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• v.27 no.5
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• pp.309-317
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• 2018

In this study, a laser sheet technique and PLIF (Planar laser-induced fluorescence) are applied to a laboratory-scale pulverized coal burner of the open type, and the spatial relationship of the pulverized coal particle zone and the combustion reaction zone is examined by simultaneous measurement of Mie scattering and OH-LIF images. It is found that this technique can be used to investigate the spatial relationship of the combustion reaction zone and pulverized-coal particles in turbulent pulverized-coal flames without disturbing the combustion reaction field. In the upstream region, the combustion reaction occurs only in the periphery of the clusters where high-temperature burned gas of the methane pilot flame is entrained and oxygen supply is sufficient. In the downstream region, however, combustion reaction can be seen also within clusters of pulverized-coal particles, since the temperature of pulverized-coal particles rises, and the mixing with emitted volatile matter and ambient air is promoted.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.1
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• pp.9-15
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• 2004

$CO_2$ is a well-known green house gas as well as the major source of global warming. Many researchers have studied to reduce $CO_2$ emission in combustion processes. Among the method for reducing $CO_2$ emission, oxygen-enriched combustion has been proposed. Because its adiabatic flame temperature is relatively too high, existing facilities must be changed or the flame temperature in the combustion zone should be reduced. The combustion characteristics, composition in the flame zone, temperature profile and emission gases were investigated experimentally for the various oxygen-enriched ratios(OER) by the addition of $CO_2$, under constant $O_2$ flow rate. Results showed that the reaction zone was quenched and broadened as the addition of $CO_2$ was increased. The emission of NOx in flue gas was decreased as decreasing temperature in reaction zone. It was also shown that the reaction was delayed by the cooling effect. As the addition of $CO_2$ was increased, the composition of CO in the flame zone was increased due to the increase of reaction rate by increasing mixing effect of oxidant/fuel at OER=0％, but the composition of CO was decreased by quenching effect at OER=50％ and 100％.

• Proceedings of the KSME Conference
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• 2003.04a
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• pp.1389-1394
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• 2003

$CO_2$ is a well-known green house gas, which is the major source of global warming. Many researchers have studied to reduce $CO_2$ emission in combustion processes. Among the method for reducing $CO_2$ emission, oxygen-enriched combustion has been proposed. But the adiabatic flame temperature is too high. So existing facilities must be changed, or the adiabatic flame temperature in the combustion zone should be reduced. The combustion characteristics, composition in the flame zone, temperature profile and emission gases were studied experimentally for the various oxygen-enriched mtios(OER) by addition of $CO_2$ under coustant $O_2$ flowrate. Results showed that the reaction zone was quenched, broadened, as addition of $CO_2$ was increased. Temperature has a large effect on the NOx emission. The emission of NOx in flue gas decreased due to the decreased temperature of reaction zone. It was also shown that the reaction was delayed by the cooling effect. As the addition of $CO_2$ was increased, the composition of CO in the flame zone increased due to the increase of reaction rate by increasing mixing effect of oxidant/fuel at OER=0, but the composition of CO decreased by quenching effect at OER=50 and 100%.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.20 no.7
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• pp.2337-2346
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• 1996

One of the most useful method for increasing combustion loading of premixed flame is to strengthen the turbulent intensity of unburned mixture. It produces an important information to a design of efficient combustion equipment that analysing microstructure of strong turbulence premixed flame. The flame structure and characteristics are depend on the turbulence of unburned mixture. Therefore, to strengthen the turbulent intensity of unburned mixture make flame scale small and accomplish efficient combustion. We measured the velocity of local flame front movements, local eddy radius and local reaction zone thickness quantitatively with increasing turbulent intensity of unburned mixture. We researched the microstructure of flame using ion currents that react sensitively in the reaction zone. Consequently, the velocity of local flame front movements is depend on the velocity of unburned mixture and local eddy scale is to be small with increasing turbulent intensity. But there is no change in local reaction zone thickness with turbulence.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.33 no.5
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• pp.343-348
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• 2009

The present study has experimentally investigated the effects of $CO_2$ diluted oxygen on the structure of swirl-stabilized flame in a lab-scale combustor. The methane fuel and oxidant mixture gas ($CO_2$ and $O_2$) were mixed in a pre-mixer and introduced to the combustor through different degrees of swirl vanes. The flame characteristics were examined for various amount of carbon dioxide addition to the methane fuel and various swirl strengths. The effects of carbon dioxide addition and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using chemiluminescence techniques to provide information about flow field. The results show that the hot combustion zone increases at the upstream reaction zone because of an increase in the recirculation flow for an increase in swirl intensity. The hot combustion zone is also increased at the downstream zone by recirculation flow because of an increase in swirl intensity which results in higher centrifugal force. The OH and CH radical intensities of reaction zone decrease with carbon dioxide addition because the carbon dioxide plays a role of diluted gas in the reaction zone.