• Title/Summary/Keyword: Reaction parameter

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A Study on the Characteristic of High Tc Oxide Superconductor, Bi-Pb-Sr-Ca-Cu-O System (Bi-Pb-Sr-Ca-Cu-O계 산화물 고온초전도체의 특성에 관한 연구)

  • Kim, Y.S.;Lee, M.S.;Lee, M.S.;Jin, Y.C.
    • Journal of the Korean Society for Heat Treatment
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    • v.4 no.1
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    • pp.13-18
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    • 1991
  • The formation of high $T_c$ phase is very sluggish and c parameter of unit cell of high $T_c$ phase is about $37{\AA}$. High $T_c$ oxide superconductor with a $T_c$ above 100 K has been successfully prepared by solid state reaction method in BiSrCaCuO system by Pb adding. The microstructure related to the formation of the high $T_c$ phase has been investigated. As compared with YBCO compound, the formation reaction of the high $T_c$ requires long time heat treatment. It is due to the transformation from the low $T_c$ phase to high $T_c$ phase. The sintering just below the melting point of the calcined powder mixture is effective on the formation of the high $T_c$ phase in Pb-added BiSrCaCuO system. The growth of the high $T_c$ superconducting phase has a thin plate shape, which is characterized by the c parameter of $37{\AA}$. The formation of the high $T_c$ phases is delayed by the excessive addition of Pb. The lattice parameter(c) of the unit cell (both the low and high $T_c$ phases) is increased with increase of Pb.

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A Feasibility Study of Pulse Rate Per Respiration as an Indicator for the Reaction to Cold Stress (냉자극에 대한 맥율 변화 예비 연구)

  • Bae, Jang Han;Jeon, Young Ju;Kim, Hyunho;Kim, Jaeuk U.
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.28 no.6
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    • pp.668-673
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    • 2014
  • Cold and Heat pattern identification(CHPI) in traditional East Asian medicine(TEAM) is one of the major indicator to distinguish characteristics of disease and to determine treatment method. Basic parameters to determine CHPI include the pulse rate, respiration rate, and pulse power. Studies to associate physiological responses of human body by cold stress(CS) with CHPI in TEAM were rarely done so far. This study aims to explore the effects of cold stress on pulse signal via a feasibility study for three subjects and investigate some indices which can reflect autonomic nerve reaction(ANR). We measured radial pulse signals and respiration signal of the investigated subjects before the CS, during the CS which continues for 5 minutes, and immediately after the CS, respectively. Finally, we analyzed the pulse rate (P), respiration rate (R), pulse power, pulse depth, and pulse rate per respiration (P/R ratio). As a result, the P/R ratio showed a consistently decreasing tendency through the CS stimulation process, while other parameters behaved more complex and in subject-specific ways. It implies that, among candidate parameters, the P/R ratio is a simple but the most probable parameter that can be used as the ANR indicator. This result is also consistent with the theory in TEAM scripts, in which the P/R ratio is predicted to be a direct indicator for the CHPI. This pilot study shows that P/R ratio can be more appropriately associated with the ANR than heart rate or respiration rate alone. Extensive studies will be necessary to verify or confirm the P/R ratio as an appropriate and well defined parameter for ANR.

Theoretical Studies on Mechanism and Kinetics of the Hydrogen-Abstraction Reaction of CF3CH2CHO with OH Radicals

  • Ci, Cheng-Gang;Yu, Hong-Bo;Wan, Su-Qin;Liu, Jing-Yao;Sun, Chia-Chung
    • Bulletin of the Korean Chemical Society
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    • v.32 no.4
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    • pp.1187-1194
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    • 2011
  • The hydrogen abstraction reaction of $CF_3CH_2CHO$ + OH has been studied theoretically by dual-level direct dynamics method. Two stable conformers, trans- and cis-$CF_3CH_2CHO$, have been located, and there are four distinct OH hydrogen-abstraction channels from t-$CF_3CH_2CHO$ and two channels from c-$CF_3CH_2CHO$. The required potential energy surface information for the kinetic calculation was obtained at the MCG3-MPWB//M06-2X/aug-cc-pVDZ level. The rate constants, which were calculated using improved canonical transitionstate theory with small-curvature tunneling correction (ICVT/SCT) were fitted by a four-parameter Arrhenius equation. It is shown that the reaction proceeds predominantly via the H-abstraction from the -CHO group over the temperature range 200-2000 K. The calculated rate constants were in good agreement with the experimental data between 263 and 358 K.

A Study on Dynamic Modelling and Mass Properties Estimation of the Lunar Module (달 탐사선의 동역학 모델링 및 관성 모멘트 추정에 관한 연구)

  • Shim, Sang-Hyun;Kim, Kwang-Jin;Lee, Sang-Chul;Ko, Sang-Ho;Rhyu, Dong-Young;Ju, Gwang-Hyeok
    • Journal of the Korean Society for Aviation and Aeronautics
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    • v.18 no.4
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    • pp.30-37
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    • 2010
  • This paper deals with attitude determination and parameter estimation problems for a lunar module. For this we first derive equations of motion for the lunar module by considering allocation locations (configurations) of reaction thruster and a reaction wheel assembly. The lunar module is assumed as a rigid body. In order to include the effect of fuel sloshing on the dynamics of the lunar module, we model it as a spherical pendulum for a simple analysis. For estimating angular rates and moment of inertia of the module, we employ an extended Kalman filter and the least mean square algorithms, respectively. Finally we construct a dynamical model for the lunar module by combining all these elements.

Gasification reactivity of Chinese Shinwha Coal Chars with Steam (스팀을 이용한 중국산 신화 석탄 촤 가스화 반응에 관한 연구)

  • Kang, Min-Woong;Seo, Dong-Kyun;Kim, Yong-Tak;Hwang, Jung-Ho
    • Journal of the Korean Society of Combustion
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    • v.15 no.1
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    • pp.22-29
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    • 2010
  • In this study, carbon conversion was measured using an electronic mass balance. In a lab scale furnace, each coal sample was pyrolyzed in a nitrogen environment and became coal char, which was then gasified with steam under isothermal conditions. The reactivity of coal char was investigated at various temperatures and steam concentrations. The VRM(volume reaction model), SCM(shrinking core model), and RPM(random pore model) were used to interpret experimental data. For each model the activation energy(Ea), pre-exponential factor (A), and reaction order(n) of the coal char-steam reaction were determined by applying the Arrhenius equation into the data obtained with thermo-gravimetric analysis(TGA). According to this study, it was found that experimental data agreed better with the VRM and SCM for 1,000 and $1,100^{\circ}C$, and the RPM for 1,200 and $1,300^{\circ}C$. The reactivity of chars increased with the increase of gasification temperature. The structure parameter(${\psi}$) of the surface area for the RPM was obtained.

A Comparison of EEG Response between TV Advertisements focused on Information Transfer and Emotional Reaction (정보전달형 TV광고와 감성유발형 TV광고의 뇌파반응 비교)

  • Kim, Jeong-Ryong;Park, Ji-Su;Kim, Mi-Suk
    • Journal of the Ergonomics Society of Korea
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    • v.22 no.4
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    • pp.1-13
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    • 2003
  • This study has investigated psychological responses to various TV advertisements by using EEG(electroencephalogram). In particular, it was assumed that the brain wave would show different patterns depending upon the style of the advertisement that could be categorized into two such as 'information transfer' type and 'emotional reaction' type. Ten healthy males participated in the experiment. EEG signal was extracted from six lobes such as right and left frontal, right and left occipital, right and left temporal while the subjects were watching TV advertisements. Alpha and beta relative power spectrum, and beta/alpha parameter were calculated to compare two kinds of advertisement each other. Additionally, subjective questionnaire was used to examine subject's response by using adjective words and preference test. In result, significant differences were found in left frontal and right occipital lobe in terms of beta/alpha between two different advertisements. And, subjects showed different preference between two advertisements. It was shown that the current method could analyze the brain reaction to advertisement quantitatively, that presented the possibility of using it to marketing research.

Development of Optimal Chlorination Model and Parameter Studies (최적 염소 소독 모형의 개발 및 파라미터 연구)

  • Kim, Joonhyun;Ahn, Sooyoung;Park, Minwoo
    • Journal of Environmental Impact Assessment
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    • v.29 no.6
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    • pp.403-413
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    • 2020
  • A mathematical model comprised with eight simultaneous quasi-linear partial differential equations was suggested to provide optimal chlorination strategy. Upstream weighted finite element method was employed to construct multidimensional numerical code. The code was verified against measured concentrations in three type of reactors. Boundary conditions and reaction rate were calibrated for the sixteen cases of experimental results to regenerate the measured values. Eight reaction rate coefficients were estimated from the modeling result. The reaction rate coefficients were expressed in terms of pH and temperature. Automatic optimal algorithm was invented to estimate the reaction rate coefficients by minimizing the sum of squares of the numerical errors and combined with the model. In order to minimize the concentration of chlorine and pollutants at the final usage sites, a real-time predictive control system is imperative which can predict the water quality variables from the chlorine disinfection process at the water purification plant to the customer by means of a model and operate the disinfection process according to the influent water quality. This model can be used to build such a system in water treatment plants.

Disturbance-Observer-Based Robust H Switching Tracking Control for Near Space Interceptor

  • Guo, Chao;Liang, Xiao-Geng
    • International Journal of Aeronautical and Space Sciences
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    • v.15 no.2
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    • pp.153-162
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    • 2014
  • A novel robust $H_{\infty}$ switching tracking control design method with disturbance observer is proposed for the near space interceptor (NSI) with aerodynamic fins and reaction jets. Initially, the flight envelop of the NSI is divided into small subregions, and a slow-fast loop polytopic linear parameter varying (LPV) model is proposed, to approximate the nonlinear dynamic of the NSI, based on the Jacobian linearization and Tensor-Product (T-P) model transformation approach. A disturbance observer is then constructed, to estimate the modeled disturbance. Subsequently, based on the descriptor system method, a robust switching controller is developed, to ensure that the closed-loop descriptor system is stable with a desired $H_{\infty}$ disturbance attenuation level. Furthermore, the outcome of the proposed switching tracking control problem is formulated as a set of linear matrix inequalities (LMIs). Finally, simulation results demonstrate the effectiveness of the proposed design method.

Dynamic Model Parameter Estimation of Hydraulic Cylinder for Robot Manipulator Control (유압구동 로보트의 제어를 위한 유압 실린더 모델 파라미터 추정)

  • Choi, Myoung-Hwan
    • Journal of Industrial Technology
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    • v.16
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    • pp.113-121
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    • 1996
  • In the early developmental stages of robotics,hydraulics played an important role. As the power-to-weight ratio of electric motors increased, they eventually replaced hydraulic actuators in robot manipulators. Recently, however, task requirements have dictated that the manipulator payload capacity increase to accomodate greater payload, greater length, greater reaction forces, and hydraulic actusators are being studied as an effective form of robot actuation again. For efficient control of hydraulic actuators, the knowledge of its dynamic equation is essential. However, the dynamic equation of hydraulic actuators are nonlinear, and the dynamic coefficients are time varying. In this paper, an estimation algorithm of the dynamic coefficients of the hydraulic piston dynamics are formulated. Simulation results are presented to show the possibility of the parameter estimation.

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Optimization of Kiln Process Parameters of Low-Temperature Sintering Lightweight Aggregate by Response Surface Analysis (반응표면분석법에 따른 저온소성 경량골재의 킬른공정변수 최적화)

  • Lee, Han-Baek;Seo, Chee-Ho
    • Journal of the Korean Ceramic Society
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    • v.47 no.5
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    • pp.365-372
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    • 2010
  • This paper was to evaluate the influence of kiln process parameter(kiln angle, kiln rotating speed) of lightweight aggregate using waste glass and bottom ash with industrial by-products on thermal conductivity, density, water absorption, fracture load and porosity by response surface analysis. In the results of surface plot and contour plot, it has verified that kiln residence time of lightweight aggregate increase as kiln angle and rotating speed decreases. For this reason, pore size and quantity tend to increase by active reaction of forming agent. It seems to be that increase in pore size and quantity have caused decreasing density, fracture load and thermal conductivity, and increasing water absorption. In conclusion, optimization of kiln process parameter on thermal conductivity, density, water absorption, fracture load and porosity by response surface analysis are kiln angle 2.4646%, kiln rotating speed 40.7089 rpm.