• Title/Summary/Keyword: Reaction model

Search Result 2,852, Processing Time 0.031 seconds

Torque and Force Measurement of a Prototype HAU Reaction Wheel and the Effect of Disturbance on the Attitude Stability of Spacecraft

  • Oh, Hwa-Suk;Kwon, Jae-Wook;Lee, Hyunwoo;Nam, Myung-Ryong;Park, Dong-Jo
    • Journal of Mechanical Science and Technology
    • /
    • v.15 no.6
    • /
    • pp.743-751
    • /
    • 2001
  • A Prototype reaction wheel, named the Hankuk Aviation University (HAU) reaction wheel, has been developed for KAISTSAT satellite series. Torque and force disturbances are inherent in reaction wheels, and thus the force and torque characteristics should be examined for every newly developed reaction wheel. The torque and force disturbance noises in the prototype HAU reaction wheel are measured with a torque-measuring table developed for the present study. A new measuring procedure based on a simple principle is applied for the measurements. The frequency characteristics of the torque and force noises are analyzed by examining the power spectral density. The effect of the torque noise on the attitude stability is also examined through numerical simulations with a single-axis attitude model. The noise-induced attitude error and jitter and found to be well below the specified error limits for the KAISTSAT satellite series.

  • PDF

Generation of Sesame Flavor by the Thermal Reaction Technique

  • Yoo, Seung-Seok
    • Food Science and Biotechnology
    • /
    • v.16 no.1
    • /
    • pp.110-115
    • /
    • 2007
  • In this study we investigated the volatile compounds that are generated in sesame and contribute to its characteristic flavor. Different reaction systems were used to examine how certain amino acids influenced flavor profiles, and also to evaluate the effects of sugar types on the distribution of those volatile compounds. The volatiles that were generated in each reaction system were selectively isolated and analyzed by gas chromatography and gas chromatography-mass spectrometry, respectively. Among the 20 identified compounds, nitrogen-containing alkylpyrazines were found to be the predominant volatiles. The alkylpyrazine amounts varied across the different model systems, with the total yield being highest in the arginine reaction mixture, followed by the alanine, serine, and lysine mixtures. In general, fructose generated the most extensive amount of volatiles compared to glucose and sucrose. However, the yield of specific flavor compounds varied according to the type of sugar used. Finally, the results clearly showed that a reaction temperature of $135^{\circ}C$ and a reaction time of 20 min generated the highest amount of volatile compounds.

Evaluation of an Education Program for Public Health Service Workers in Public Hospitals: Learning Achievement and Satisfaction Levels (공공병원 공공보건의료사업 담당자를 위한 교육프로그램이 학습목표 성취도와 교육반응도에 미치는 효과)

  • Hwang, Eun-Jeong;Moon, Jung-Joo
    • Korean Journal of Health Education and Promotion
    • /
    • v.28 no.4
    • /
    • pp.27-37
    • /
    • 2011
  • Objectives: This study aims to evaluate the outcomes of an education program for public health service workers in public hospitals, utilizing the Kirkpatrick model. Methods: The study participants were 118 staff in 48 public hospitals. Of the stages in the Kirkpatrick model(reaction, learning, behavior, and result), reaction and learning stages were analyzed in this study. A 10-item self-evaluation questionnaire was used to measure satisfaction level for the reaction, and achievement of learning purposes for the learning. The education program consisted of general courses and special two tract courses(Tract A: chronic diseases, Tract B: health promotion). Results: The highest score for reaction was for Tract A(score=4.4), whilst the lowest score for reaction was for lecture(score=3.0). Learning achievement was significantly different between pre-education and post-education(p<0.01), except for health technicians. Conclusions: The results of this study could be utilized to develop effective systematic education programs for public health service workers in public hospitals.

Degradation of oxytetracycline by nano zero valent iron under UV-A irradiation: Chemical mechanism and kinetic

  • Hassanzadeh, Parisa;Ganjidoust, Hossein;Ayati, Bita
    • Advances in environmental research
    • /
    • v.3 no.1
    • /
    • pp.29-43
    • /
    • 2014
  • Pharmaceutical wastewater effluents are well known for their difficult elimination by traditional biotreatment methods and their important contribution to environmental pollution due to its fluctuating and recalcitrant nature. OTC is one of the nonbiodegradable antibiotics that makes antibiotic-resistant, so it can make be high risk for environment. NZVI can be a good choice for removal of OTC in aqueous solution. Response surface methodology (RSM) was used to optimize the amounts of NZVI and OTC to be used at pH 3 and under 200 W, UV-A irradiation. The responses were removal percent of absorption at 290 and 348 nm, TOC and COD of OTC. In the optimum condition, Linear model was performed 155 ppm of OTC were removed by 1000 ppm NZVI after 6.5 hours and the removal efficiency of absorption at 290 and 348 nm, TOC and COD were 87, 95, 85 and 89 percent, respectively. In the similar process, there is no organic compound after 14 hours. The parameters ORP, DO and pH were investigated for 6:30 hours to study the type of NZVI reaction in process. In the beginning of reaction, oxidation was the dominant reaction after 3 hours, photocatalytic reaction was remarkable. The mechanism of OTC degradation is proposed by HPLC/ESI-MS and four by products were found. Also the rate constants (first order kinetic chain reaction model) were 0.0099, 0.0021, 0.0010, 0.0049 and $0.0074min^{-1}$, respectively.

Response Surface Methodological Approach for Optimization of Enzymatic Synthesis of Sorbitan Methacrylate

  • Jeong, Gwi-Taek;Lee, Kyoung-Min;Kim, Hae-Sung;Lee, Woo-Tai;Sunwoo, Chang-Shin;Park, Don-Hee
    • 한국생물공학회:학술대회논문집
    • /
    • 2005.10a
    • /
    • pp.511-516
    • /
    • 2005
  • Sorbitan methacrylate was synthesized from sorbitan dehydrated from D-sorbitol using an immobilized lipase. To optimize the enzymatic synthesis of sorbitan methacrylate, response surface methodology was applied to determine the effects of five-level-four-factors and their reciprocal interactions on sorbitan methacrylate biosynthesis. A total of 30 individual experiments were performed, which were designed to study reaction temperature, reaction time, enzyme amount and substrate molar ratio. A statistical model predicted that the highest conversion yield of sorbitan methacrylate was 100%, at the following optimized reaction conditions: a reaction temperature of 43.06 $^{\circ}C$, a reaction time of 164.25 mins., an enzyme amount of 7.47%, and a substrate molar ratio of 3.98:1. Using these optimal factor values under experimental conditions in four independent replicates, the average conversion yield reached 98.7%${\pm}$1.2% and was well within the value predicted by the model.

  • PDF

Response Surface Methodological Approach for Optimization of Removal of Free Fatty Acid in Crude Oil

  • Jeong, Gwi-Taek;Lee, Kyoung-Min;Yang, Hee-Seung;Park, Seok-Hwan;Kim, Jae-Hoon;Kim, Do-Man;Park, Don-Hee
    • 한국생물공학회:학술대회논문집
    • /
    • 2005.10a
    • /
    • pp.904-909
    • /
    • 2005
  • To optimize the removal of free fatty acid in crude vegetable oil, response surface methodology was applied to determine the effects of five level-four factors and their reciprocal interactions on removal of free fatty acid. A total of 30 individual experiments were performed, which were designed to study reaction temperature, reaction time, catalyst amount and methanol amount. A statistical model predicted that the highest removal yield of free fatty acid was 99.8%, at the following optimized reaction conditions: a reaction temperature of 64.99$^{\circ}C$, a reaction time of 36.20 mins., an catalyst amount of 13.01% (w/v), and a methanol amount of 15% (v/v). Using these optimal factor values under experimental conditions in three independent replicates, the average removal yield was well within the value predicted by the model.

  • PDF

Fundamental Studies for the Adsorption Features of Malachite Green on Granular Activated Carbon (활성탄에 의한 말라카이트 그린 흡착 특성에 관한 기초연구)

  • Baek, Mi-Hwa;Choi, Young-Jin;Kim, Young-Ji;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
    • /
    • v.25 no.3
    • /
    • pp.459-463
    • /
    • 2009
  • The adsorption features of malachite green onto activated carbon have been investigated for its treatment from aqueous solution. The influential factors were examined the initial concentration of malachite green, reaction temperature, and pH. Under experimental conditions, adsorption equilibrium of malachite green was attained within 2 hr after the adsorption started. The adsorption reaction of malachite green followed the pseudo-second order rate model, and the adsorption rate constants(k2) decreased with increasing initial concentrations of malachite green. Adsorption behavior of malachite green on activated carbon was found to follow the Freundlich model well in the initial adsorbate concentration range. With increase in temperature, the adsorbed amount of malachite green at equilibrium increased, which indicate that the adsorption reaction was endothermic reaction. Thermodynamic parameters for malachite green adsorption reaction were estimated at varying temperatures, and in the pH range of 2-10, adsorption of malachite green increased.

Decarbonization Kinetics of Molten Iron by Ar+O2 Gas Bubbling (Ar+O2 혼합가스 취입에 의한 용철의 탈탄 반응속도)

  • Sohn, Ho-Sang;Jung, Kwang-Hyun
    • Korean Journal of Metals and Materials
    • /
    • v.47 no.2
    • /
    • pp.107-113
    • /
    • 2009
  • Molten iron with 2 mass % carbon content was decarbonized at 1823 K~1923 K by bubbling $Ar+O_2$ gas through a submerged nozzle. The reaction rate was significantly influenced by the oxygen partial pressure and the gas flow rate. Little evolution of CO gas was observed in the initial 5 seconds of the oxidation; however, this was followed by a period of high evolution rate of CO gas. The partial pressure of CO gas decreased with further progress of the decarbonization. The overall reaction is decomposed to two elementary reactions: the decarbonization and the dissolution rate of oxygen. The assumptions were made that these reactions are at equilibrium and that the reaction rates are controlled by mass transfer rates within and around the gas bubble. The time variations of carbon and oxygen contents in the melt and the CO partial pressure in the off-gas under various bubbling conditions were well explained by the mathematical model. Based on the present model, it was explained that the decarbonization rate of molten iron was controlled by gas-phase mass transfer at the first stage of reaction, but the rate controlling step was transferred to liquid-phase mass transfer from one third of reaction time.

Simulating reactive distillation of HIx (HI-H2O-I2) system in Sulphur-Iodine cycle for hydrogen production

  • Mandal, Subhasis;Jana, Amiya K.
    • Nuclear Engineering and Technology
    • /
    • v.52 no.2
    • /
    • pp.279-286
    • /
    • 2020
  • In this article, we develop a reactive distillation (RD) column configuration for the production of hydrogen. This RD column is in the HI decomposition section of the sulphur - iodine (SI) thermochemical cycle, in which HI decomposition and H2 separation take place simultaneously. The section plays a major role in high hydrogen production efficiency (that depends on reaction conversion and separation efficiency) of the SI cycle. In the column simulation, the rigorous thermodynamic phase equilibrium and reaction kinetic model are used. The tuning parameters involved in phase equilibrium model are dependent on interactive components and system temperature. For kinetic model, parameter values are adopted from the Aspen flowsheet simulator. Interestingly, there is no side reaction (e.g., solvation reaction, electrolyte decomposition and polyiodide formation) considered aiming to make the proposed model simple that leads to a challenging prediction. The process parameters are determined on the basis of optimal hydrogen production as reflux ratio = 0.87, total number of stages = 19 and feeding point at 8th stage. With this, the column operates at a reasonably low pressure (i.e., 8 bar) and produces hydrogen in the distillate with a desired composition (H2 = 9.18 mol%, H2O = 88.27 mol% and HI = 2.54 mol%). Finally, the results are compared with other model simulations. It is observed that the proposed scheme leads to consume a reasonably low energy requirement of 327 MJ/kmol of H2.

A Study of the Suitability of Combustion Chemistry in the EDC Model for the LES of Backdraft (백드래프트 현상의 LES를 위한 EDC 모델의 연소 화학반응기구 적합성 연구)

  • Myilsamy, Dinesh;Oh, Chang Bo;Han, Yong Shik;Do, Kyu Hyung
    • Fire Science and Engineering
    • /
    • v.31 no.4
    • /
    • pp.35-42
    • /
    • 2017
  • Large Eddy Simulation (LES) was peformed for the backdraft occurred in a compartment filled with high-temperature methane fuel using the Fire Dynamics Simulator (FDS) of version 6. The prediction performance of FDS, adopted the Eddy Dissipation Concept (EDC) combustion model with five different chemical reaction mechanisms, was evaluated. The temporal distributions of temperature, fuel mass fraction, velocity and pressure were discussed with numerical results and the pressure variation in time was compared with that of previous experiment. The FDS adopted the EDC model showed the possibility of LES for the backdraft phenomena. However, the prediction performance of the LES with EDC model strongly depended on the chemical reaction mechanism considered. It is necessary that the suitability of the chemical reaction mechanism should be validated in advance for LES with the FDS v6 to be applied to the simulation of backdraft.