• 한국운동역학회지
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• 제19권3호
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• pp.581-592
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• 2009

본 연구는 일반운동화와 스프링신발의 운동역학적 분석을 통해 일상적인 보행에서 스프링신발이 갖는 특성을 알아보기 위해 실시하였다. 이를 위해 정상족궁인 30-40대 여성 12명을 대상으로 2종류의 실험용 신발(스프링신발)과 비교용 신발(일반운동화)을 착용시킨 후 1.7m/s의 보행속도에서 지면반력기와 EMG, 적외선 카메라를 이용한 운동 역학적 분석을 실시하였다. 분석 결과 지면반력 분석에서는 제 1정점과 제 2정점에서 실험용신발이 일반운동화에 비해 큰 전후성분값을 나타냈다. 근전도분석에서는 대퇴직근의 활동이 스프링 신발을 신었을 때 증가하는 것으로 나타났다. 후족각에서 스프링 신발이 착지 시와 제1정점간에 일반화보다 크며 발목 관절을 중심으로 내측으로 회전하는 회내 운동을 적절하게 제어 하면서 이지 시에 후족 각의 감소에 영향을 미치는 것으로 나타났다. 따라서 스프링신발은 일반 신발에 비해 보행 시 무릎 신전근들의 근력 향상에는 도움을 줄 수 있을 것으로 판단된다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.333-333
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• 2011

We studied the H/D exchange kinetics of pure and acid dopped water-ice film by using the techniques of reactive ions scattering (RIS) and low energy sputtering (LES) with low kinetic energy cesium ion beam (<35 eV). From RIS, neutral water isotopomers were detected in the form of cesium-molecule ion clusters, $CsX^+$ (X= $H_2O$, HDO, $D_2O$). Ionic species, like $H_3O^+$, $DH_2O^+$, $D_2HO^+$, $D_3O^+$, adsorbed on the surface were ejected via LES process. Those techniques allowed us to trace the isotopomeric populations of water-ice film. To show the catalytic effect of excess proton in the H/D exchange reaction, our study was conducted with two types of water-ice films. In film 1, about 0.5 BL of $H_2O$ was adsorbed on HCl (0.1 ML) dopped $D_2O$ (8 BL) film. In film 2, similar amount of $H_2O$ used in film 1 was adsorbed on pure $D_2O$ film. Kinetic data were obtained from each film type for 90-110 K (film 1) and 110-130 K (film 2) and fitted with numerically integrated lines. Through the Arrhenius plot of kinetic coefficient deduced from fitting of the H/D exchange reaction, the activation energy of film 1 and 2 were estimated to be $10{\pm}3kJmol^{-1}$ and $17{\pm}4kJmol^{-1}$. This activation barrier difference could be understood from detailed pictures of H/D exchange. In film 2, both the formation of ion pair, $H_3O^+$ and OH. and proton transfer were needed for the H/D exchange. However, in film 1, only proton transfer was necessary but ion pair formation was not, so this might reduce the activation energy.

• 한국자동차공학회논문집
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• 제14권3호
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• pp.125-132
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• 2006

Transient kinetics of $NH_3$ adsorption/desorption and of SCR(selective catalytic reduction) of NO with $NH_3$ were studied over vanadium based catalysts, such as $V_2O_5/TiO_2$ and $V_2O_5-WO_3/TiO_2$. In the present catalytic reaction process, NO adsorption is neglected while $NH_3$ is strongly chemisorbed on the catalytic surface. Accordingly, it is ruled out the possibility of a reaction between strongly adsorbed $NH_3$ and NO species in line with the hypothesis of an Eley-Rideal mechanism. The present kinetic model assumes; (1) non-activated $NH_3$ adsorption, (2) Temkin-type $NH_3$ coverage dependence of the desorption energy, (3) non-linear dependence of the SCR reaction rate on the $NH_3$ surface coverage. Thus, the surface heterogeneity for adsorption/desorption of $NH_3$ is taken into account in this model. The present study extends the pure chemical kinetic model based on a powdered-phase catalytic system to the chemico-physical one applicable to a realistic monolith reactor.

• 한국식품영양과학회지
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• 제22권6호
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• pp.785-791
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• 1993

변온 조건하에서 백미를 저장했을때 수분활성에 따른 과당의 변화를 고찰한 결과를 요약하면 다음과 같다. 과당은 저장 초기에 0차반응으로 증가하다가 일정시간 이후 1차반응으로 감소하였다. 반응속도는 수분 활성과 자장온도가 높을수록 빨랐고, 각 수분활성에서의 활성화에너지는 과당 증가시 10.76~19.56, 감소시는 4.53~8.40kcal/mole이었다. 그리고 $Q_{10}$값은 증가시 1.74~2.74, 감소시는 1.26~1.54였다. Accelerated shelf-life test로 부터 구한 $25^{\circ}C$에서의 shelf-life는 수분활성 (0.44, 0.52, 0.65, 0.75)에 따라 252, 212, 193, 162일의 범위였으며, 온도와 수분활성이 증가함에 따라 단축되었다. 변온조건에서의 실측치와 예측치를 비교한 결과 유효 온도차는 과당 증가시 0.49~2.52, 감소에서는 1.03~2.02의 차이를 보였다.

• Korean Chemical Engineering Research
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• 제56권2호
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• pp.275-280
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• 2018

Methyl ester derived from coconut oil is very interesting to study since it contains free-fatty acid with chemical structure of medium carbon chain ($C_{12}-C_{14}$), so the methyl ester obtained from its part can be a biodiesel and another partially into biokerosene. The use of heterogeneous catalysts in the production of methyl ester requires severe conditions (high pressure and high temperature), while at low temperature and atmospheric conditions, yield of methyl ester is relatively very low. By using microwave irradiation trans-esterification reaction with heterogeneous catalysts, it is expected to be much faster and can give higher yields. Therefore, we studied the production of methyl ester from coconut oil using CaO catalyst assisted by microwave. Our aim was to find a kinetic model of methyl ester production through a transesterification process from coconut oil assisted by microwave using heterogeneous CaO catalyst. The experimental apparatus consisted of a batch reactor placed in a microwave oven equipped with a condenser, stirrer and temperature controllers. Batch process was conducted at atmospheric pressure with a variation of CaO catalyst concentration (0.5; 1.0; 1.5; 2.0, 2.5%) and microwave power (100, 264 and 400 W). In general, the production process of methyl esters by heterogeneous catalyst will obtain three layers, wherein the first layer is the product of methyl ester, the second layer is glycerol and the third layer is the catalyst. The experimental results show that the yield of methyl ester increases along with the increase of microwave power, catalyst concentration and reaction time. Kinetic model of methyl ester production can be represented by the following equation: $-r_{TG}=1.7{\cdot}10^6{_e}{\frac{-43.86}{RT}}C_{TG}$.

• 대한화학회지
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• 제37권8호
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• pp.695-701
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• 1993

25$^{\circ}C$에서 메탄올, 에탄올, 아세톤 이성분 혼합수용액과 물, 메탄올에서의 가용매분해반응 속도 상수를 결정하고, 이들 속도자료를 Grunwald-Winstein 식과 Kivinen 관계식을 이용하여 해석하였다. 또한 물과 메탄올에서의 속도론적 용매 동위원소 효과와 알코올-물 혼합용매계에서 생성물 선택성 값을 결정하였다. 염화 2-티오펜술포닐의 가용매 분해반으에 대한 속도론적 용매 동위원소 효과는 메탄올과 물에서 각가 2.24와 1.47이었다. 에탄올-물에서의 술포닐 에스테르 형성에 대한 선택성 값은 최대값을 나타내었다. 메탄올과 물에서의 속도론적 용매 동위원소 효과, 알코올 수용액에서의 선택성 자료와 용매효과로부터, 본 연구에서의 반응은 극성이 낮은 용매계에서는 일반염기 촉매반응과 또는 S$_A$N 반응이 유리하고, 극성이 큰 용매계에서는 S$_N$2 반응의 유리한 반응으로 진행되는 것으로 제안하였다.

• 한국운동역학회지
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• 제15권1호
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• pp.259-274
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• 2005

The purpose of this study was to compare the kinematic and kinetic parameters of lower extremity joints between novice and experienced sports aerobic dancers during two heights of depth jumps. Four male dancers were participated in this study and they performed 40cm and 60cm height depth jump three times, respectively. Four ProReflex MCU cameras (100frame/sec) and a Kistler force plate (1000Hz) were used for data collection. The results indicated that the duration of contact phase of experienced group was shorter than that of novice group regardless of jump height. For minimum angle of hip, knee, and ankle joints, the novice group had tendency to decrease the angle but the experienced group had increased the joint angle with jump height. There was no difference of total ground reaction force between the groups but the reaction force had tendency to increase with jump height. Thus, this study implied that repetition of jump and landing may induce joint related injury and further study such as. EMG analysis of lower extremity can be needed to verify the relationship between injury and ground reaction force.

• 공업화학
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• 제5권6호
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• pp.967-974
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• 1994

DGEBA(Diglycidyl ether of bisphenol A)/MDA(4, 4' -methylene dianiline)/MN(Malononitrile)/HQ(Hydroquinone)계의 경화 반응속도론을 differential scanning calorimetry(DSC)의 승온적 방법(dynamic runs)에 의해 Barrrett method와 Integral method로 연구하였다. 활성화 에너지, pre-exponential factor와 같은 kinetic parameter들이 구하여 졌으며 반응 차수는 본계가 n차 반응 속도식에 적용된다는 가정하에 추정되었다. MN(Malononitrile)은 본 반응의 사슬 연장제로, HQ(Hydroquinone)은 반응 가속제 또는 촉매로 도입되었다.

• Carbon letters
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• 제12권4호
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• pp.229-235
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• 2011

Isotactic polyacrylonitrile (PAN) with triad isotacticity of 0.53, which was determined by $^{13}C$ NMR, using dialkylmagnesium as an initiator, was successfully synthesized. Isothermal treatment of iso-PAN was conducted in air at 200, 220, 250 and $280^{\circ}C$. Structural evolutions and chemical changes were studied with Fourier transformation infrared and wide-angle X-ray diffraction during stabilization. A new parameter $CNF={I_{2240cm}}^{-1}/ ({I_{1595cm}}^{-1}+f^*{I_{1595cm}}^{-1})$ was defined to evaluate residual nitrile groups. Crystallinity and crystal size were calculated with X-ray diffraction dates. The results indicated that the nitrile groups had partly converted into a ladder structure as stabilization proceeded. The rate of reaction increased with treatment temperature; crystallinity and crystal size decreased proportionally to pyrolysis temperature. The iso-conversional method coupled with the Kissinger and Flynn-Wall-Ozawa methods were used to determine kinetic parameters via differential scanning calorimetry analysis with different heating rates. The active energy of the reaction was 171.1 and 169.1 kJ/mol, calculated with the two methods respectively and implied the sensitivity of the reaction with temperature.

• 한국환경과학회지
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• 제9권2호
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• pp.165-171
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• 2000

A kinetic study for anion exchange was performed for commercially available Cl- type anion exchange resin in use to remove nitrate in water. The obtained results from the batch reactor were applied to the Langmuir and Freundlich models. The constants for Lagmuir model were qmax =29.82 and b=0.202, and for Freundlich model were K=5.509 and n=1.772. Langmuir model showed betterfit than Frendlich model for the experimental results. Ion exchange reaction rate was also calculated and the the approximate first-order reaction, rate constant k1 was 0.16 L/mg.hr. Effective diffusion coefficient was obtained in the range from $9.67$\times$10^{-8} cm^2/sec$ for initial concentration change, and from $6.09$\times$10^{-7} to 3.98$\times$10^{-6} cm^2/sec$ for reaction temperature change. Activation energy during the diffusion was calculated as 26 kcal/mol.