• Title/Summary/Keyword: Re-oxidization

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Effects of the Re-oxidation Temperature and Time on the PTC Properties of Sm-doped BaTiO3 (Sm을 첨가한 BaTiO3계의 재산화 온도 및 시간에 따른 PTC 특성 변화)

  • Chung, Yong-Keun;Choi, Sung-Churl
    • Journal of the Korean Ceramic Society
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    • v.46 no.3
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    • pp.330-335
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    • 2009
  • We investigated the effects of the re-oxidation temperature and time on the positive temperature coefficient (PTC) of resistivity characteristics of Sm-doped $BaTiO_3$ sintered at $1200{\sim}1260^{\circ}C$ for 2 h in a reducing atmosphere (3% $H_2/N_2$), followed by re-oxidization processes in air, in which re-oxidization temperature and time were $600{\sim}1000^{\circ}C$ and $1{\sim}10$h, respectively. The result reveals that Smdoped (Ba,Ca)$TiO_3$ ceramics fired in a reducing atmosphere exhibit low PTC characteristics, whereas the sample re-oxidized at $800^{\circ}C$ for 1 h in air exhibit pronounced PTC characteristics. The room-temperature resistivity and jumping characteristics of resistivity (${\rho}_{max}/{\rho}25^{\circ}C$) decrease with Sm contents. The PTC characteristics with reoxidization time at $800^{\circ}C$ have improved about $2{\sim}3$ orders of magnitude whereas differed according to the sintering temperature. The 0.7 at% Sm-doped (Ba,Ca)$TiO_3$ samples reveal the best PTC characteristics in the present range of formula and processes.

A Study on the Thermal Degradation Properties of Epoxy Resin for Cast Resin Transformer (몰드변압기용 에폭시 수지의 열 열화특성에 관한 연구)

  • Lim, Kyung-Bum;Nam, Ki-Dong;Kim, Ki-Hwan;Park, Su-Hong;Hwang, Myung-Hwan
    • Fire Science and Engineering
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    • v.22 no.2
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    • pp.44-48
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    • 2008
  • In this paper, we measured a contact angle, surface resistivity and XPS to study the thermal aging characteristics of the epoxy resin for cast resin transformer. As a result of this experiment, we found that the contact angle increases up to $200^{\circ}C$ as it causes a re-crosslinking on the surface, but starts decreasing at $250^{\circ}C$ as it causes heat condensation. As a result of examining the oxygen/carbon peaks through the XPS analysis, we obtained a higher oxygen peak vs. carbon in the first untreated sample, but it showed the opposite trend after heat treatment. That rise in the carbon peak continued up to $200^{\circ}C$, but decreased again at the temperatures above. That's because it kept forming a stable surface structure up to $200^{\circ}C$ but its carbon combination got destroyed due to a rapid oxidization at $250^{\circ}C$. And a conduction path was formed easily with the hydrophile property caused by rapid surface activation.

Experimental Investigation on the Compression Behavior of Concrete Filled Circular FRP Tubes (콘크리트 충전 FRP 원통관의 압축거동에 관한 실험적 연구)

  • Joo, Hyung-Joong;Lee, Seung-Sik;Kim, Young-Ho;Park, Jong-Hwa;Yoon, Soon-Jong
    • Composites Research
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    • v.21 no.3
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    • pp.24-30
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    • 2008
  • Durability problems may arise in the concrete, which is one of the major construction materials, used in the construction field. Bridge piers and foundation piles are usually made with concrete and they are exposed to the moisture and hence the durability of the concrete reduced significantly due to oxidization of re-bar and icing of concrete. To mitigate such problems, FRP tube has been developed and the concrete filled FRP tube (CFFT) has been investigated to find the confinement effect which is provided additionally. It was reported that if the concrete is wrapped with FRP, strength and chemical resistance are improved significantly. In order to apply such a member in the construction field, structural behavior and applicable design guideline or design criteria must be thoroughly investigated. In the experimental investigation, the results are compared with the previous research results and the relationship which can predict the ultimate strength and strain is suggested. In addition, some comments found at the compression tests are given briefly.