• 한국항행학회논문지
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• 제20권5호
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• pp.482-489
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• 2016

방사선 환경에서 광섬유형광체를 이용하면 감마선을 광다이오드로 검출할 수 있다. 이와 같이 감지된 전류를 전압으로 변환하여 신호 처리하는 장치를 전류모듈 또는 TIA라 하며, 선형적으로 변환시키는 것이 아주 중요하다. 본 연구에서는 변환선형성이 우수하고 잡음이나 옵세트 전압을 최소화하는 미세전류모듈을 연구하여 제품을 개발하였다. 또한 본 논문에서는 전류-전압 변환기인 미세전류모듈을 개발 및 제작함에 있어서 정밀도와 정확도를 요하는 전류모듈을 연구, 개발, 제작하는 과정에 많은 노력을 기울였다. 미세전류모듈의 이론을 정립한 후 회로를 개발하고 그 전류모듈을 테스트한 결과 전류-전압 변환의 선형성이 기존의 문헌에 제시된 제품들과 비교하여 광범위에 걸쳐서 크게 향상되었음을 확인하였다. 관계기관의 입회 하에 본 제품을 실제 감마선 존재 환경에서 테스트 및 적용해본 결과 관련 요건에 적합함을 인정받았다.

• Journal of Radiation Protection and Research
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• 제41권2호
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• pp.179-183
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• 2016

Background: As an important detecting device, TLD is a widely used in the radiation monitoring. It is essential for us to study the property of detecting element. The aim of this study is to calculate the thermo-luminescence efficiency of TL elements. Materials and Methods: A batch of thermo-luminescence elements were irradiated by the filtered X-ray beams of average energies in the range 40-200 kVp, 662 keV $^{137}Cs$ gamma rays and then the amounts of lights were measured by the TL reader. The deposition energies in elements were calculated by theory formula and Monte Carlo simulation. The unit absorbed dose in elements by photons with different energies corresponding to the amounts of lights was calculated, which is called the thermo luminescent efficiency (${\eta}^{(E)}$). Because of the amounts of lights can be calculated by the absorbed dose in elements multiply ${\eta}^{(E)}$, the ${\eta}^{(E)}$ can be calculated by the experimental data (the amounts of lights) divided by absorbed dose. Results and Discussion: The deviation of simulation results compared with theoretical calculation results were less than 5%, so the absorbed dose in elements was calculated by simulation results in here. The change range of ${\eta}^{(E)}$ value, relative to 662 keV $^{137}Cs$ gamma rays, is about 30% in the energy range of 33 keV to 662 keV, is in accordance by the comparison with relevant foreign literatures. Conclusion: The ${\eta}^{(E)}$ values can be used for updating the amounts of lights that are got by the direct ratio assumed relations with deposition energy in TL elements, which can largely reduce the error of calculation results of the amounts of lights. These data can be used for the design of individual dosimeter which used TLD-2000 thermo-luminescence elements, also have a certain reference value for manufacturer to improve the energy-response performance of TL elements by formulation adjustment.

• Carbon letters
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• 제12권4호
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• pp.236-242
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• 2011

The oxyfluorination effects of activated carbon nanofibers (OFACFs) were investigated for $CO_2$ storage. Electrospun CFs were prepared from a polyacrylonitrile/N,N-dimethylformamide solution via electrospinning and heat treatment. The electrospun CFs were chemically activated in order to generate the pore structure, and then oxyfluorination was used to modify the surface. The samples were labeled CF (electrospun CF), ACF (activated CF), OFACF-1 ($O_2:F_2$ = 7:3), OFACF-2 ($O_2:F_2$ = 5:5) and OFACF-3 ($O_2:F_2$ = 3:7). The functional group of OFACFs was investigated using X-ray photoelectron spectroscopy analysis. The C-F bonds formed on surface of ACFs. The intensities of the C-O peaks increased after oxyfluorination and increased the oxygen content in the reaction gas. The specific surface area, pore volume and pore size of OFACFs were calculated by the Brunauer-Emmett-Teller and density functional theory equation. Through the $N_2$ adsorption isotherm, the specific surface area and pore volume slightly decreased as a result of oxyfluorination treatment. Nevertheless, the $CO_2$ adsorption efficiency of oxyfluorinated ACF improved around 16 wt% due to the semi-ionic interaction effect of surface modificated oxygen functional groups and $CO_2$ molecules.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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• pp.158-158
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• 2012

A new kind of organic-inorganic hybrid polymer, poly(tetraphenyl)silole siloxane (PSS), was invented and synthesized for realization of its unique charge trap properties. The organic portions consisting of (tetraphenyl)silole rings are responsible for electron trapping owing to their low-lying LUMO, while the Si-O-Si inorganic linkages of high HOMO-LUMO gap provide the intrachain energy barrier for controlling electron transport. Such an alternation of the organic and inorganic moieties in a polymer may give an interesting quantum well electronic structure in a molecule. The PSS thin film was fabricated by spin-coating of the PSS solution in THF organic solvent onto Si-wafer substrates and curing. The electron trapping of the PSS thin films was confirmed by the capacitance-voltage (C-V) measurements performed within the metal-insulator-semiconductor (MIS) device structure. And the quantum well electronic structure of the PSS thin film, which was thought to be the origin of the electron trapping, was investigated by a combination of theoretical and experimental methods: density functional theory (DFT) calculations in Gaussian03 package and spectroscopic techniques such as near edge X-ray absorption fine structure spectroscopy (NEXAFS) and photoemission spectroscopy (PES). The electron trapping properties of the PSS thin film of quantum well structure are closely related to intra- and inter-polymer chain electron transports. Among them, the intra-chain electron transport was theoretically studied using the Atomistix Toolkit (ATK) software based on the non-equilibrium Green's function (NEGF) method in conjunction with the DFT.

• 천문학회지
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• 제48권2호
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• pp.155-164
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• 2015

In Kang (2015) we calculated the acceleration of cosmic-ray electrons at weak spherical shocks that are expected to form in the cluster outskirts, and estimated the diffuse synchrotron radiation emitted by those electrons. There we demonstrated that, at decelerating spherical shocks, the volume integrated spectra of both electrons and radiation deviate significantly from the test-particle power-laws predicted for constant planar shocks, because the shock compression ratio and the flux of inject electrons decrease in time. In this study, we consider spherical blast waves propagating through a constant density core surrounded by an isothermal halo with ρ ∝ r⁻ⁿ in order to explore how the deceleration of the shock affects the radio emission from accelerated electrons. The surface brightness profile and the volumeintegrated radio spectrum of the model shocks are calculated by assuming a ribbon-like shock surface on a spherical shell and the associated downstream region of relativistic electrons. If the postshock magnetic field strength is about 0.7 or 7 µG, at the shock age of ∼ 50 Myr, the volume-integrated radio spectrum steepens gradually with the spectral index from α_inj to α_inj + 0.5 over 0.1–10 GHz, where α_inj is the injection index at the shock position expected from the diffusive shock acceleration theory. Such gradual steepening could explain the curved radio spectrum of the radio relic in cluster A2266, which was interpreted as a broken power-law by Trasatti et al. (2015), if the relic shock is young enough so that the break frequency is around 1 GHz.

• 한국음향학회지
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• 제32권2호
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• pp.116-123
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• 2013

본 논문은 시변 해수면을 생성하고 KA(Kirchhoff Approximation) 기반으로 산란계수를 시뮬레이션하여 결정론적 모델인 벨홉 임펄스 응답에 적용함으로써 시변동성 채널을 생성한다. 1D Pierson-Moskowitz 해수면 스펙트럼과 가우시안 상관 함수를 이용하여 일정한 속도로 변화하는 시 변동성 해수면을 사용하였다. 산란계수는 벨홉의 채널 임펄스 응답의 신호 응답 강도에 적용한다. 실제 실측 데이터에서 해수면 반사 성분을 분리하여 시 변동성 특성에 대한 도플러 파워 스펙트럼을 구하고, 해수면 산란계수 시뮬레이션의 결과와 비교하여 해수면에 사용된 가우시안 상관 함수의 상관 시간을 추정하였다. 최종적으로 생성된 시변동성 채널에 수동 시역전 통신 시나리오를 가정하고 기법을 적용하여 비트에러율 및 채널응답 상관계수 시뮬레이션을 수행하였다.

• 대한화학회지
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• 제34권3호
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• pp.232-238
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• 1990

Zn의 생화학적 역할을 연구하기 위하여, 간단한 모델시스템을 설정하였다. 즉, Zn가 리간드인 $OH_2나 NH_3$와 배위결합을 이루거나 carboxypeptidase A (CPA)의 기질에 해당하는 펩티드의 O=C-와 배위결합을 할 때, 그 기하학적 구조 및 net atomic charge의 변화를 조사하였다. Double Zeta basis set를 사용한 ab initio HF-SCF 계산에 의하면, Zn는 이들 리간드의 O-H, N-H, O=C-를 매우 polar하게 만든다. 특히, 펩티드의 탄소는 친전자성이 매우 증가하여, nucleophile의 공격을 용이하게 받을 수 있을 것으로 예측되었다. 또한, CPA에서 Zn 주위에 있는 리간드의 분자배위 상태를 조사하기 위하여, CPA+glycyltyrosine complex에 관한 molecular mechanics방법을 적용하였다. 이 결과를 X-ray 결과와 비교하였을 때, Zn는 4배위 결합 이외에 물분자도 관여할 것으로 예측된다.

• 한국광학회지
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• 제18권1호
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• pp.19-23
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• 2007

원리적인 다양한 장점에도 불구하고 취급이 복잡하고 고차 연립방정식으로 표현되는 현실적 제한으로 인하여 실제 설계과정에서 잘 적용하지 않는 자이델 3차 수차를 이용하여 구한 코마수차 계수식으로부터 근사적인 제로조건을 만족하는 유한 물체거 리를 갖는 코마수차가 제거된 2반사경계의 초기설계에 유용한 곡률선형방정식을 유도하고 그 특징을 조사한다. 즉 주경과 부경의 곡률, 주경과 부경사이의 거리, 유효초점거리로 표현된 변형된 코마수차계수로부터 코마수차계수가 제거되는 조건에서 설계변수를 구하기 위해 전산수치해석 후 나온 데이터를 기반으로 주경과 부경사이의 선형관계가 나타나는 곡률선형방정식을 구하는 것이다. 이는 유한 물점의 코마수차가 보정된 2 반사경계에서 약간의 대수적인 계산만으로 최적화의 초기 입력 데이터를 손쉽게 구할 수 있는 것을 의미한다.

• Bulletin of the Korean Chemical Society
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• 제31권4호
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• pp.881-886
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• 2010

A novel Schiff base N-(2,4-dinitro-phenyl)-N'-(1-phenyl-ethylidene)-hydrazine has been synthesized and structurally characterized by X-ray single crystal diffraction, elemental analysis, IR spectra and UV-vis spectrum. The crystal belongs to monoclinic with space group P21/n. The molecules are connected via intermolecular O-$H{\cdots}O$ hydrogen bonds into 1D infinite chains. The crystal structure is consolidated by the intramolecular N-$H{\cdots}O$ hydrogen bonds. weak intermolecular C-$H{\cdots}O$ hydrogen bonds link the molecules into intriguing 3D framework. Furthermore, Density functional theory (DFT) calculations of the structure, stabilities, orbital energies, composition characteristics of some frontier molecular orbitals and Mulliken charge distributions of the title compound were performed by means of Gaussian 03W package and taking B3LYP/6-31G(d) basis set. The time-dependent DFT calculations have been employed to calculate the electronic spectrum of the title compound, and the UV-vis spectra has been discussed on this basis. The results show that DFT method at B3LYP/6-31G(d) level can well reproduce the structure of the title compound.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 하계학술대회 논문집
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• pp.783-786
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• 2000

In this paper, physical properties and dielectric characteristics of LLDPE and EVA which are used as a blending material to improve PE's performance are studied. LLDPE of 0.92[g/cm3] and EVA with the EVA contents of 12.5[%1 were selected as specimens, and X-ray diffraction(XRD) are used to analysis physical properties. We measured dielectric constant with the frequency range from 20[Hz] to 1 [MHz], applied voltage 6[V] and the temperature from 25[$^{\circ}C$] to 110[$^{\circ}C$]. From XRD, LLDPE has a crystallinity of 53[%] and, 46[%] for EVA. LLDPE has as low tan$\delta$ as of 10$^{-3}$ ~10$^{-4}$ and inflection point near 500[Hz]. At frequency region lower than 500[Hz], tan$\delta$ decreases with frequency and increases with temperature and it is considered to be caused by conductive carriers within specimen. Over 500[Hz], it is the reverse and we thought that it was caused by decrease of relaxation time due to Debye theory, EVA has tan$\delta$with the values of 10$^{-2}$ ~10$^{-3}$ , which is higher than that of LLDPE, and it has inflection point at 60[Hz]. It is shown that Dielectric characteristics of EVA are similar to LLDPE's.