• Korean Journal of Materials Research
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• v.24 no.9
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• pp.488-494
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• 2014

The effect of tungsten (W) addition on the hardenability of low-carbon boron steels was investigated using dilatometry, microstructural observations and secondary ion mass spectroscopy. The hardenability was discussed with respect to transformation behaviour aspects depending on the segregation and precipitation of boron at austenite grain boundaries. A critical cooling rate producing a hardness corresponding to 90 % martensite structure was measured from a hardness distribution plot, and was used as a criterion to estimate hardenability at faster cooling rates. In the low-carbon boron steel, the addition of 0.50 wt.% W was comparable to that of 0.20 wt.% molybdenum in terms of critical cooling rate, indicating hardenability at faster cooling rates. However, the addition of 0.50 wt.% W was not more effective than the addition of .0.20 wt.% molybdenum at slower cooling rates. The addition of 0.20 wt.% molybdenum completely suppressed the formation of eutectoid ferrite even at the slow cooling rate of $0.2^{\circ}C/s$, while the addition of 0.50 wt.% W did not, even at the cooling rate of $1.0^{\circ}C/s$. Therefore, it was found that the effect of alloying elements on the hardenability of low-carbon boron steels can be differently evaluated according to cooling rate.

• Journal of the Korean Wood Science and Technology
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• v.51 no.2
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• pp.98-108
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• 2023

In this study, the boards were manufactured according to the mandarin peels addition rate using sawdust and mandarin orange peel. After that, the mechanical properties and density profile of ceramics prepared by conditions through resin impregnation process and carbonization process were investigated. The bending and compression strengths of ceramics tended to increase as the resin impregnation rate increased. When the resin impregnation rate was 70%, the highest values were 8.58 MPa and 14.77 MPa, respectively. Also, the mechanical properties of ceramics according to carbonization temperature showed the highest values at 1,200℃ for bending strength of 11.09 MPa and compression strength of 17.20 MPa. The bending strength and compression strength according to the mandarin peels addition rate showed the highest values at 8.62 MPa and 14.16 MPa, respectively, when the mandarin orange peel addition rate was 5%. The mechanical properties tended to decrease when the addition rate of mandarin orange was increased. The density profile of ceramics showed a similar tendency to the mechanical properties. It can be seen that the density distribution from the surface layer to the center layer is more uniform as the resin impregnation rate and carbonization temperature increase and the mandarin peels addition rate decreases.

• Journal of Korea Foundry Society
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• v.17 no.4
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• pp.347-355
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• 1997

It is well known that the coarse primary Si in hypereutectic Al-Si alloys deteriorate castability, machinability, and mechanical properties. So, many treatment has been tried to refine the primary Si increasing cooling rate and adding refinement agent. Therefore. the purpose of our work was the observation of the effect on the refinement of primary Si and the analysis of the trend to apply to the casting process by changing the amount of P addition and the cooling rate while fixing the temperature at $750^{\circ}C$ of P addition and the type of AlCuP. In the condition of amount of P addition was fixed, primary Si was finer as cooling rate increased but in case of cooling rate was fixed, the effect of refinement was resisted as incersed the amount of P addition. At a relatively slow cooling rate of $22^{\circ}C/sec$, refinement was governed by the amount of P addition rather than cooling rate. At elevated cooling rate of $51^{\circ}C/sec$ and $99^{\circ}C/sec$, the undercooling due to faster cooling rate promoted nucleation of primary Si rather than P addition more significantly.

• Proceedings of the Korean Journal of Food and Nutrition Conference
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• 2000.12a
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• pp.49-49
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• 2000

Influence of onion on the quality characteristics of strawberry jam substituted with 50% fructo-oligosaccharide for sucrose was investigated. Fructo-oligosaccharide strawberry jams with 10, 20, 30, 40% onion in place of strawberry were prepared, and their moisture content, pH, total acidity, color, spread. sweetness, reducing sugar, residual anthocyanin, instrumental texture and sensory characteristics were evaluated. Moisture content of fructo-oligosaccharide strawberry jams with onion was lower than that of strawberry-only control jam with an exception of 10% onion jam. As the addition rate of onion increased, pH increased, total acidity decreased. The lightness and redness decreased with addition of onion, while yellowness was increased. As the addition rate of onion increased, spreadmeter value increased. The sweetness of fructo-oligosaccharide strawberry jams decreased with addition of onion. More of onion added, reducing sugar content of fructo-oligosaccharide strawberry jams decreased. As the addition rate of onion increased, residual anthocyanin of fructo-oligosaccharide strawberry jams decreased. As the addition rate of onion increased. instrumental texture measured in 25% strain, hardness, fracturability, adhesiveness, gumminess, chewiness, resilience of fructo-oligosaccharide strawberry jams decreased, while springiness, cohesiveness of fructo-oligosaccharide strawberry jams with onion was higher than that of strawberry-only control jam with an exception of 10% onion jam. As the addition rate of onion increased, instrumental texture measured in 30% strain, hardness, adhesiveness, gumminess. chewiness, resilience of fructo-oligosaccharide strawberry jams was lower than that of strawberry-only control jam with an exception of 10% onion jam, while fracturability of fructo-oligosaccharide strawberry jams decreased with addition of onion, springiness, cohesiveness of fructo-oligosaccharide strawberry jams increased with addition of onion. In sensory evaluation, as the addition rate of onion increased, sensory evaluation of fructo-oligosaccharide strawberry jams decreased, obtained fairly good score to 10, 20% onion jam.

• Journal of the Korea Institute of Building Construction
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• v.7 no.4
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• pp.117-124
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• 2007

Focused on the material-related aspect for enhancing the durability of concrete, the present study analyzed the effect of glycol ether admixture, which is a chemical admixture that can compact the structure of concrete by entraining air inside the concrete, on the basic physical properties and durability characteristic of the concrete. In analyzing the results of experiment, we examined the basic physical properties and durability characteristic of concrete according to addition rate based on OPC and selected the optimal addition rate. In addition, with the optimal addition rate, we added glycol ether admixture to concrete, which contained fly ash used as binder and high-performance water reducing agent for reducing the unit quantity, and examined changes in the characteristics of the concrete. According to the result, the optimal addition rate of glycol ether admixture was 3% of the unit quantity of cement, and the addition of binder and chemical admixture did not have a significant effect on unhardened concrete but reduced the air content. In addition, concrete showed resistance performance of around 30% to carbonation and around 40% to drying shrinkage. In addition, as for resistance to freezing and thawing, the relative dynamic modulus of elasticity was over around 85% through atmospheric curing. These performances prove the effect.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.11a
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• pp.845-848
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• 2006

This study sought to investigate the characteristics of cellular concrete, such as porosity, strength and density, according to the cell addition rate. Based on the result, it examined the application to a cellular concrete panel. Porosity was found to increase according to the cell addition rate, measuring continuous porosity of 42% and 47%, and total porosity of 61% and 66%. In terms of cell addition rate, measurements were 7% and 11% respectively. Compressive strength represented 5.0MPa, 3.8MPa and 2.8 MPa in terms of 7%, 9% and 11% respectively, decreasing 1 MPa of strength according to every 2% increase of cell addition rate. Density showed 0.55, 0.44 and 0.36 in terms of 7%, 9% and 11% respectively, decreasing 1.0 MPa according to every 2% increase of cell addition rate proportionally. In addition the sandwich panel of cellular concrete which was fabricated during this research was found to be relatively heavy and non-flammable with an excellent strength of 4.0 MPa. Compared with a light concrete panel, considering the compressive strength that accountsfor 10 MPa, it appeared relatively low in strength. However it would be excellent for application due to the light density of only 0.4 MPa.

• Journal of the Korean Chemical Society
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• v.12 no.3
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• pp.106-113
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• 1968

The rate-constants of the nucleophilic addition reaction of n-butylmercaptan to 3,4-methylenedioxy-${\beta}$-nitrostyrene were determined at various acidic pH and a rate equation which can be applied over wide pH range was obtained. From this equation, one may conclude that this reaction is started by addition of mercaptan molecule below pH 3, while above pH 6, the overall rate of addition is almost only depend upon the concentration of nitrostyrene and the mercaptide ion. At pH 3∼6, the complex mechanism of this addition reaction can also be fully explained by the rate equation.

• Bulletin of the Korean Chemical Society
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• v.12 no.3
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• pp.301-303
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• 1991

The rate constants for the nucleophilic addition of thiophenol to $\alpha$, N-diphenylnitrone and it's derivatives (p-$OCH_3$, p-Cl, p-$NO_2$) were determined from pH 3.0 to 13.0 by UV spectrophotometry and rate equations which can be applied over a wide pH range were obtained. On the basis of rate equation, general base and substituent effect a plausible addition mechanism of thiophenol to ${\alpha}$, N-diphenylnitrone was proposed: At high pH, the addition of sulfide ion to carbon-nitrogen double bond was rate controlling, however, in acidic solution, reaction was proceeded by the addition of thiophenol molecule to carbon-nitrogen double bond after protonation at oxygen of ${\alpha}$, N-diphenylnitrone.

• Bulletin of the Korean Chemical Society
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• v.18 no.4
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• pp.374-379
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• 1997

The rate constants for the nucleophilic addition of thiophenol derivatives (p-OCH3, H, p-CH3, m-CH3, p-Br and p-NO2) to 4'-[N-(9-acridinyl)]-1'-(N-methanesulfonyl)-3'-methoxyquinonediimide (AMQD) were determined by ultraviolet spectrophotometer in water at 5 ℃, and rate equations which can be applied over a wide pH range were obtained. On the basis of pH-rate profile, Bronsted plot, adduct analysis, general base catalysis and substituent effect, a plausible mechanism of this addition reaction was proposed: Below pH 2.5, the reaction proceeded by the addition of thiophenol molecule to 6'-position of quinonoid after protonation at the acridinyl nitrogen. Above pH 6.2, the addition of sulfide anion to 6'-position of quinonoid was rate controlling. However, in the range of pH 3.0-6.0, these two reactions occured competively.

• Journal of the Korean Chemical Society
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• v.16 no.4
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• pp.232-240
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• 1972

The rate constants for the addition reaction of n-butylmercaptan to ethylacrylate have been measured by iodometry and for the proposed reaction mechanism a rate equation which can be applied over wide pH range was derived. From this rate equation, one may conclude that the reaction is started by addition of n-butylmercaptan molecule below pH 4. However, above pH 7, this addition reaction is proceeded by the n-butylmercaptide ions. At pH 4-7, the complex addition reaction mechanism can also be revealed by this rate equation.