• Title/Summary/Keyword: Rate constant D-value

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A Study on the System Principle of PID Module Implementation (PID Module 구현 원리 시스템에 대한 연구)

  • 위성동;김태성;최창주;권병무
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.183-192
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    • 1999
  • The derivative equation measured of a ${\Delta}MV=Kp*{(EVn-EVn-1)+\frac{1}{Ki/S}* EVn+(Kd/S)*(2PVn-1-PVn-PVn-1)}$ is used on the machine apparatus of industrial field, but this par doesn\`t able to educate now, because we didn\`t have the implementation device of PID module, so the principle implementation system of the PID Module is manufactured and developed. Through this system, the implementation system of PID Module is practiced with that the SV and the set of P, I, D is set on the derivative equation measured of PID. A things to be known of this experiment result is flow. 1)PID module is known that had to be used with the module of A/D and D/A. 2) In process of PV is approached to the SV to follow Kp, Ti and Td to cause a constant of set value on the $MVp=Kp*EV, MV=\frac{1}{Ki}{\int}EVdt, MVd=Td\frac{d}{dt}EV$, the variable rate of E and Kp, Td, Ti in that table 1 is analysed, is same as flow. (1)If Kp is high, PV is near fast to the SV, but Kp is small, PV is near slowly to the SV. (2)If Ki is shot, PV is close fast to the SV, but Ti is high, PV is close slowly to the SV (3)If Td is high, the variable rate of E press hardly when because it doesn\`t increase, but Td is small, the variable rate of E press not hardly, upper with 1), 2), PID module is supposed that be able to do the A/S and an implementation of that apparatus, and getting a success of aim that an engineer want, on control of temperature, tension, velocity, amount of flow, power of wind end so on, to get the principle of automatic implementation in industrial field with cooperation of A/D and D/A module.

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A Reproducible High Etch Rate ICP Process for Etching of Via-Hole Grounds in 200μm Thick GaAs MMICs

  • Rawal, D.S.;Agarwal, Vanita R.;Sharma, H.S.;Sehgal, B.K.;Muralidharan, R.
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.8 no.3
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    • pp.244-250
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    • 2008
  • An inductively coupled plasma etching process to replace an existing slower rate reactive ion etching process for $60{\mu}m$ diameter via-holes using Cl2/BCl3 gases has been investigated. Process pressure and platen power were varied at a constant ICP coil power to reproduce the RIE etched $200{\mu}m$ deep via profile, at high etch rate. Desired etch profile was obtained at 40 m Torr pressure, 950 W coil power, 90W platen power with an etch rate ${\sim}4{\mu}m$/min and via etch yield >90% over a 3-inch wafer, using $24{\mu}m$ thick photoresist mask. The etch uniformity and reproducibility obtained for the process were better than 4%. The metallized via-hole dc resistance measured was ${\sim}0.5{\Omega}$ and via inductance value measured was $\sim$83 pH.

A Study on Kernel Size Adaptation for Correntropy-based Learning Algorithms (코렌트로피 기반 학습 알고리듬의 커널 사이즈에 관한 연구)

  • Kim, Namyong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.2
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    • pp.714-720
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    • 2021
  • The ITL (information theoretic learning) based on the kernel density estimation method that has successfully been applied to machine learning and signal processing applications has a drawback of severe sensitiveness in choosing proper kernel sizes. For the maximization of correntropy criterion (MCC) as one of the ITL-type criteria, several methods of adapting the remaining kernel size ( ) after removing the term have been studied. In this paper, it is shown that the main cause of sensitivity in choosing the kernel size derives from the term and that the adaptive adjustment of in the remaining terms leads to approach the absolute value of error, which prevents the weight adjustment from continuing. Thus, it is proposed that choosing an appropriate constant as the kernel size for the remaining terms is more effective. In addition, the experiment results when compared to the conventional algorithm show that the proposed method enhances learning performance by about 2dB of steady state MSE with the same convergence rate. In an experiment for channel models, the proposed method enhances performance by 4 dB so that the proposed method is more suitable for more complex or inferior conditions.

A Study on the Stress Ratio effect of Metal Matrix Composites on Fatigue Crack Growth Behavior (금속기복합재료의 피로균열성장거동에 대한 응력비 영향에 관한 연구)

  • Choi, Yong-Bum;Huh, Sun-Chul;Yoon, Han-Ki;Park, Won-Jo
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2002.05a
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    • pp.155-160
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    • 2002
  • Metal matrix composites had generated a lot of interest in recent times because of significant in specific properties. It was also highlighted as the materials of frontier industry because strength, heat-resistant, corrosion-resistant, wear-resistant were superiored. In this study the strength properties of $Al_{18}B_4O_{33}/AC4CH$ were represented mixing the binder of $Al_2O_3$ and $TiO_2$. It was also fabricated by squeeze casting. $Al_{18}B_4O_{33}/AC4CH$ was fabricated at the melt temperature of $760^{\circ}C$ the perform temperature of $700^{\circ}C$ and mold temperature of $200^{\circ}C$ under the pressure of 83.4MPa and observed SEM. Fatigue crack growth rate tests on compact tension specimen(half-size) of thickness 12.5mm were conducted by using sinusoidal waveform. Compact tension specimens(half-size) were used and fatigue crack growth rate da/dN and stress intensity factor range ${\Delta}K$ were analyzed concerning to the R value of 0.1 and 0.05. In order to find out the value of ${\Delta}K$, load amplitude constant method was applied by the standard fatigue testing method describes in ASTM E647-95a. As the results of this study, Fatigue crack growth rate increased with in creasing the load ratio, Consequently, At equivalent stress intensity factors, the fatigue crack growth rates in MMC were faster than those of AC4CH alloy. then the fatigue life and the fatigue crack growth rate was investigated using scanning election microscopy(SEM)

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A Evaluation on the Effect of Vibration for the Application of PEMFC Stack to Unmanned Aircraft (고분자 전해질 연료전지 스택의 무인기 적용을 위한 진동 영향 평가)

  • KANG, JUN-YOUNG;OH, GUN-WOO;KIM, MIN-WOO;LEE, JUNG-WOON;LEE, SEUNG-KUK
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.6
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    • pp.587-595
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    • 2018
  • Recently, research is being conducted to use a fuel cell as a power source of unmanned aircraft. However, safety standards about applying fuel cells to unmanned aircraft are insufficient. In this paper, to improve the safety of the fuel cells for unmanned aircraft is experimentally studied. For this reason, standards for safety of fuel cells were analyzed. And influence of vibration among the evaluation items related to the safety of the fuel cell for unmanned aircraft was discussed. In order to, at constant intervals, vibration was applied to the fuel cell, then the performance was measured, the measurement items were gas tightness, polarization curve, frequency response analysis (FRA). A total of 220 hours was experimented at 20 hour intervals. the result of vibration test, gas leakage rate was a maximum of -0.04826 kPa/min and Polarization curve reached a maximum of 1.0103 times of the initial value, the charge transfer resistance reached a maximum of 1.0104 times of the initial value. This research indicate that performance of fuel cell is affected by vibration and this study is expected to contribute to the safety of fuel cell for unmanned aircraft.

Characteristics of Anaerobic Degradation on Dewatered Liquid of Household Food Waste. (음식물쓰레기 탈수액의 혐기성 생분해 특성)

  • Kim, Woo-Sung;Seo, Jeoung-Yoon;Lee, Young-Hyeong
    • Korean Journal of Environmental Agriculture
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    • v.17 no.3
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    • pp.234-238
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    • 1998
  • Anaerobic degradation characteristics of dewatered liquid of household food waste including methane conversion efficiency and degradation kinetics were studied in an anaerobic batch reactor of 5 L volume. The ultimate methane production for dewatered liquid of household food waste tested was over 0.31L $CH_4/L{\cdot}dewatered$ liquid of household food waste. The kinetic constant of dewatered liquid of household food waste tested was $0.223d^{-1}/L$. The kinetic behavior of anaerobic degradation was described as a first order series reaction. The determinant of rate-limiting step(DR) that is balanced out from the rates of reaction steps was defined by the logarithmic difference of the maximum acidification rate and the maximum methanation rate. Anaerobic degradation characteristics of organic materials were evaluated by the value of DR. The DR of dewatered liquid of household food waste tested was 1.17.

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Microcomputer-aided Fermentation System for High Density Fed-Batch Cultivation (마이크로컴퓨터를 이용한 고농도 유가배양시스템)

  • 이형준;이계호허윤행
    • KSBB Journal
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    • v.5 no.3
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    • pp.307-313
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    • 1990
  • A microcomputer-aided fermentation system was constructed for high density fed-batch culture using dissolved oxygen(DO) as a substrate feeding indicator. DO signal was processed prior to aquisition to computer. Agitation speed and oxygen flow rate was changed stepwisely to maintain DO value at a constant level. Agitation speed was controlled by the output signal of D/A converter. Oxygen flow rate was controlled by a flow rate control valve connected to a stepping motor. Substrate was fed with a feeding pump operated by the abrupt increase of DO signal. Methylobacillus sp. SK1 was cultivated to test the system and 16.53g/l of cell density was obtained after 10 hr.

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A Study on the Ionic Dissociation Rate of $\alpha$-Chlorobenzyl Ethyl Ether by Dynamic NMR Spectroscopy-Chlorobenzyl Ethyl Ether by Dynamic NMR Spectroscopy (動的 NMR에 依한 $\alpha$-Chlorobenzyl Ethyl Ether의 이온解離速度에 關한 硏究)

  • Chang-Yol Kim
    • Journal of the Korean Chemical Society
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    • v.24 no.1
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    • pp.44-52
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    • 1980
  • Ionic dissociation rates of $\alpha$-chlorobenzyl ethyl ether in each solvent of toluene-$d_8$ and carbon tetrachloride were measured by the method of dynamic NMR spectroscopy. The spin system of these 1H NMR spectra was $AB_3$. The theoretical spectrum was calculated by computer simulation of dynamic NMR spectra, which agreed very well with observed spectra. From this computer simulation, the ionic dissociation rate constant k was obtained, and by Eyring plot with it, slope and intercept length was gained, from which kinetic parameters were calculated.The easiness of ionic dissociation depended upon solvent polarity. Activation enthalpy was 4.7 kcal/mole in toluene-$d_8$, 10.7 kcal/mole in carbon tetrachloride, and activation entropy was -35. 8 e.u. in toluene-$d_8$, -14.4 e.u. in carbon tetrachloride. It was understood that though the ${\Delta}H^{neq}$ value was small, this ionic dissociation had an easier procession in nonpolar solvents with increasing temperatures. Considering that the ionic dissociation could be thought as the first step of $S_N1$ mechanism, attention might be paid to the results that the value of ${\Delta}S^{neq}$ had a large negative value in comparison with a small ${\Delta}H^{neq}$.

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Hydrolysis of p-Nitrophenyl Carboxylic Ester in N,N-Dimethyl-N-dodecyl-N-(2-methylbenzimidazoyl) Ammonium Chloride Micellar Solution (N,N-Dimethyl-N-Dodecyl-N-(2-methylbenzimidazoyl) Ammonium Chloride 미셀 용액속에서 p-Nitrophenyl Carboxylic Ester의 가수분해)

  • Kim, Jeung-Bea;Kim, Hak-Yoon
    • Journal of Environmental Science International
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    • v.17 no.5
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    • pp.509-516
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    • 2008
  • New functional surfactant, N,N-dimethyl-N-dodecyl-N-(2-methyl benzimidazoyl) ammonium chloride(DDBAC) having benzimidazole(BI) functional group have been synthesized and the critical micellar concentration of DDBAC measured by surface tentiometry and electric conductivity method was $8.9{\times}10^{-4}M$. Micellar effects in DDBAC functional surfactant solution on the hydrolysis of p-nitrophenylacetate(p-NPA), p-nitro-phenylpropionate(p-NPP) and p-nitrophenylvalerate(p-NPV) were observed with change of various pH (Tris-buffer). The pseudo first rate constants of hydrolysis of p-NPA, p-NPP and p-NPV in optimum concentration of DDBAC solution increase to about 160, 280 and 600 times, respectively, as compared with those of aqueous solution at pH 8.00(Tris-buffer). It is considered that benzimidazole functional moiety accelerates the reaction rates of hydrolysis because they act as nucleophile or general base. In optimum concentration of DDBAC solution, the rate constants of hydrolysis of p-NPP and p-NPV increase to about 1.5 and 3.0 times, respectively, as compared with that of p-NPA. It means that the more the carbon numbers of alkyl group of substrates, the larger the binding constants between DDBAC micelle and substrates are. To know the hydrolysis mechanism of p-NPCE(p-NPA, p-NPP and p-NPV), the deuterium kinetic isotope effects were measured in $D_2O$ solutions. Consequently the pseudo first order rate constant ratios in $H_2O$ and $D_2O$ solution, $k_{H_2O}/k_{D_2O}$, were about $2.8{\sim}3.0$ range. It means that the mechanism of hydrolysis were proceeded by nucleophile and general base attack in approximately same value.

A Robust Acoustic Echo Canceler with Stepsize Predictor for Environment Noise (주변 노이즈에 강건한 Stepsize 예측기를 갖는 음향 반향 제거기)

  • Lee, Se-Won;Kang, Hee-Hoon;Lee, Won-Seok
    • Journal of the Institute of Electronics Engineers of Korea TE
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    • v.39 no.2
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    • pp.44-50
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    • 2002
  • Conventional acoustic echo cancelers using ES(Exponentially weighted Stepsize) algorithm have simple operational configuration and fast convergence speed batter then NLMS algorithm, but they are very weak in external noise because ES algorithm updates filter taps using an average energy reduction rate of room impulse response in specific acoustical condition. So, a new configuration of acoustic echo canceler with stepsize generator and selector is proposed in this thesis. The proposed stepsize generator and selector improve conventional acoustic echo canceler's weakness in external noise and improve the system robustness. The stepsize generator generates additional stepsize value using moving averager, which is the residual noise energy of error signal multiplied by constant ${\gamma}$. The stepsize selector selects the stepsize value that has better performance in an acoustic echo canceler using a coefficient decision factor ${\Delta}_{differ}$ The simulation results show that the proposed algorithm reduces residual error by 5[dB] to 10[dB], improves misadjustment regardless of external noise's SNR.