• Title/Summary/Keyword: Rate Law

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The Kinetics Study of Ozone with Sulfur Dioxide in the Gas Phase (기체 상태에서의 오존과 아황산가스의 반응연구)

  • Young Sik Kwon
    • Journal of the Korean Chemical Society
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    • v.35 no.2
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    • pp.111-118
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    • 1991
  • The kinetic of the gas phase reactions of ozone(0.5 torr) with sulfur dioxide was studied. The SO2 reaction was conducted in the 7∼22 torr range at 90∼155$^{\circ}$C. The reaction rate was faster than the reaction rate of O$_3$ in the presence of CO$_2$ alone. The reaction of O$_3$ with SO$_2$ follows the rate law: -d(O$_3)/dt=k_0(SO_2)(M)(O_3)+2k _1(SO_2)(O_3$). The first term of this rate law arises from a third order molecular reaction predominating in the lower temperature range and gave a rate constant k$_0$ = (9.35 $\pm$ 8.6) ${\times}$ 10$^9$e$^{-(11.05{\pm}2.04)kcal/RT}(M^{-2}s^{-1}$). The second term of the above rate law derived from a second order thermal decomposition reaction which was the major part of the reaction and gave a rate constant k$_0 =(9.35{\pm}8.6){\times}10^9e^{-(11.05{\pm}2.04)kcal/RT}(M^{-2}s^{-1}$). The overall reaction proceeds with kinetics of complex order composed mainly of second order and third order components.

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Oxidation Study on the Fabrication of Fe-36Ni Oxide Powder from Its Scrap

  • Yun, Jung Yeul;Park, Man Ho;Yang, Sangsun;Lee, Dong-Won;Wang, Jei-Pil
    • Journal of Powder Materials
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    • v.20 no.1
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    • pp.48-52
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    • 2013
  • A study of oxidation kinetic of Fe-36Ni alloy has been investigated using thermogravimetric apparatus (TGA) in an attempt to define the basic mechanism over a range of temperature of 400 to $1000^{\circ}C$ and finally to fabricate its powder. The oxidation rate was increased with increasing temperature and oxidation behavior of the alloy followed a parabolic rate law at elevated temperature. Temperature dependence of the reaction rate was determined with Arrhenius-type equation and activation energy was calculated to be 106.49 kJ/mol. Based on the kinetic data and micro-structure examination, oxidation mechanism was revealed that iron ions and electrons might migrate outward along grain boundaries and oxygen anion diffused inward through a spinel structure, $(Ni,Fe)_3O_4$.

Influences of Electrochemical Vapor Deposit Conditions Growth Rate and Characteristics of YSZ Thin Films (I) (YSZ 박막의 성장속도와 특성에 미치는 전기화학증착 조건의 영향(I))

  • 박동원;전치훈;강대갑;최병진;김대룡
    • Journal of the Korean Ceramic Society
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    • v.33 no.1
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    • pp.25-34
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    • 1996
  • Yttria stabilized zirconia (YSZ) thin films were prepared by the electrochemical vapor deposition (EVD) method on the porous Al2O3 substrates which were fabricated by different substrate thickness and porosity. Film growth rates decreased with increase on the substrate thickness and porosity and obeyed a parabolic rate law. Activa-tion energy calculated from the parabolic rate onstants was 69.9 kcal/mol. With increase on the deposition time, monoclinic phase was appeared and then disappeared. YSZ penetrated deeply into substrates when the EVD temperature decreased. Electrical conductivity of the films was 0.09 S/cm at 100$0^{\circ}C$ similar to the value of YSZ single crystal.

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Current Status for Resources Recycling in Korea (자원리싸이클링의 현황과 전망)

  • Oh Jae-Hyun;Kim Sung-Don;Kim Joon-Soo
    • Resources Recycling
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    • v.12 no.5
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    • pp.3-9
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    • 2003
  • In order to prospect current recycling status in Korea, legislative system and policies relating to recycling, wastes generation and recycling rate were reviewed. Approximately 260,400 ton/day of wastes was generated in 2001. 48,400 ton/day of household waste and 212,000 ton/day of industrial waste. During the last ten years, waste management laws such as waste disposal law, recycling law and environment friendly industry law were prepared. In this article, concerning over waste generation and recycling, recycling law, Extended Producer Responsibility System and the problems and technological developments associated with recycling were summarized.

Finite-Time Convergent Guidance Law Based on Second-Order Sliding Mode Control Theory

  • Ji, Yi;Lin, Defu;Wang, Wei;Lin, Shiyao
    • International Journal of Aeronautical and Space Sciences
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    • v.18 no.4
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    • pp.697-708
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    • 2017
  • The complex battlefield environment makes it difficult to intercept maneuvering targets for guided missiles. In this paper, a finite-time convergent (FTC) guidance law based on the second-order sliding mode (SOSM) control theory is proposed to achieve the requirements of stability, accuracy and robustness. More specifically, a second-order sliding mode observer (SMOB) is used to estimate and compensate for the total disturbance of the controlled system, while the target acceleration is extracted from the line-of-sight (LOS) angle measurement. The proposed guidance law can drive the LOS angular rate converge to zero in a finite time, which means that the missile will accurately intercept the target. Numerical simulations with some comparisons are performed to demonstrate the superiority of the proposed guidance law.

A Study of Delay Interest in International Arbitral Awards (국제중재판정의 지연이자에 관한 고찰)

  • Kim, Joongi
    • Journal of Arbitration Studies
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    • v.31 no.1
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    • pp.55-81
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    • 2021
  • Awarding interest in international arbitration remains one of the most challenging areas for tribunals and parties given the myriad of issues that arise. This article seeks to provide an overview of how international arbitral tribunals grant delay interest. It reviews the various issues that international arbitral tribunals face concerning pre-award and post-award interest, determining the appropriate interest rate, surrounding simple or compound interest, and the complex issue of choice of law. A comparative context is provided by surveying the laws of major jurisdictions from both the common law and civil law and the regulations of leading arbitral institutions. It concludes with a review of the law, jurisprudence, and practice in Korea related to delay interest and how Korean tribunals under the KCAB Domestic and International Rules have determined delay interest in recent years.

An Effective Clipped Companding Scheme for PAPR Reduction of OFDM Signals (OFDM 신호의 PAPR 감소를 위한 효과적인 Clipped Companding 기법)

  • Kim, Jae-Woon;Shin, Yo-An
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.32 no.10C
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    • pp.1010-1018
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    • 2007
  • In this paper, we propose a companding scheme to effectively reduce PAPR (Peak-to-Average Power Ratio) of the OFDM (Orthogonal frequency Division Multiplexing) signals. The proposed scheme is basically based on the companding scheme to consider both complexity and Bit Error Rate (BER) performance, and composed of the clipping followed by the companding scheme. In the first step of the proposed scheme, some of peak signals which do not influence the BER even without them, are clipped. In the second step, the proposed scheme utilizes the ${\mu}-law$ companding to effectively reduce the PAPR. Simulation results show that the proposed clipped companding scheme can provide more PAPR reduction without degradation of the BER performance, as compare to the conventional ${\mu}-law$ companding.

On the Tail Series Laws of Large Numbers for Independent Random Elements in Banach Spaces (Banach 공간에서 독립인 확률요소들의 Tail 합에 대한 대수의 법칙에 대하여)

  • Nam Eun-Woo
    • The Journal of the Korea Contents Association
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    • v.6 no.5
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    • pp.29-34
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    • 2006
  • For the almost certainly convergent series $S_n=\sum_{i=1}^nV-i$ of independent random elements in Banach spaces, by investigating tail series laws of large numbers, the rate of convergence of the series $S_n$ to a random variable s is studied in this paper. More specifically, by studying the duality between the limiting behavior of the tail series $T_n=S-S_{n-1}=\sum_{i=n}^{\infty}V-i$ of random variables and that of Banach space valued random elements, an alternative way of proving a result of the previous work, which establishes the equivalence between the tail series weak law of large numbers and a limit law, is provided in a Banach space setting.

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Variable stability system control law development for in-flight simulation of pitch/roll/yaw rate and normal load

  • Ko, Joon Soo;Park, Sungsu
    • International Journal of Aeronautical and Space Sciences
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    • v.15 no.4
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    • pp.412-418
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    • 2014
  • This paper describes the development of variable stability system (VSS) control laws for the KFA-i to simulate the dynamics of KFA-m aircraft. The KFA-i is a single engine, Class IV aircraft and was selected as an in-flight simulator (IFS) aircraft, whereas the KFA-m is a simulated aircraft that is based on the F-16 aircraft. A 6-DoF math model of KFA-i aircraft was developed, linearized, and separated into longitudinal and lateral motion for VSS control law synthesis. The KFA-i aircraft has five primary control surfaces: two flaperons, two all movable horizontal tails, and one rudder. Flaperons are used for load control, the horizontal tails are used for pitch and roll rate control, and the rudder is used for yaw rate control. The developed VSS control law can simulate four parameters of the KFA-m aircraft simultaneously, such as pitch, roll, yaw rates, and load. The simulation results show that KFA-i follows the responses of KFA-m with high accuracy.

Reinterpretation of Okun's law on Korean Economy (오쿤의 법칙(Okun's law)에 대한 재해석)

  • Yoo, Gyeongjoon;Ryu, Deockhyun
    • Journal of Labour Economics
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    • v.35 no.1
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    • pp.89-109
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    • 2012
  • This paper evaluate the robustness of the Okun relationship based on Korean data for 1979~2008. For estimating a natural unemployment rate, this study uses time series econometric methodologies. This paper finds some interesting results; first of all, a bench mark estimates of Okun's ${\beta}$ range from 2 to 4 with different methodologies. This is a little bit higher scale than that of Lee(2000)'s results, which estimated the Okun's coefficient on the advanced countries' 1955~1996. Secondly, we test an asymmetric behavior of unemployment rate on business cycle. But the results are mixed. Finally we cannot find the evidence of structural break for the periods of 1979~80 and 1997~98 crises.

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