• Title/Summary/Keyword: Rate Constant

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Prediction of Concrete Strength by a Modified Rate Constant Model (수정 반응률 상수 모델에 의한 콘크리트의 강도의 예측)

  • 한상훈;김진근
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.155-158
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    • 1999
  • This paper discusses the validity of models to predict the compressive strength of concrete subjected to various temperature histories and the shortcomings of existing rate constant model and apparent activation energy concept. Based on the discussion, a modified rate constant model is proposed. The modified rate constant model, in which apparent activation energy is a nonlinear function of curing temperature and age, accurately estimates the development of the experimental compressive strengths by a few researches. Also, the apparent activation energy of concrete cured with high temperature decreases rapidly with age, but that cured with low temperature decreases gradually with age. Finally a generalized model to predict apparent activation energy and compressive strength is proposed, which is based on the regression results.

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A Study on the River Discharge Measurement Techniques (하천유량 측정기법에 관한 연구)

  • 김성원;지홍기
    • Journal of Environmental Science International
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    • v.7 no.6
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    • pp.793-801
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    • 1998
  • In this study, the Dilution Method is used to measure river discharge through the hydraulic model test. the dilution method is divided into Constant-Rate-Infection Method and Slug-Injection Method in the river discharge measurement techniques. When the dilution method is applied in the hydraulic model flume, it is analyzed that the estimated error of constant-rate-injection method is less than that of the slug-in-jection method, and the result shows that floodflow analysis is more efficient than lowflow analysis as compared observed discharge with calculated discharge. The result of statistical error analysis shows that the constant-rate-injection method is appropriate technique for the measurement of the river discharge. Therefore, the dilution method among the river discharge measurement techniques can be applied for the river basin which can't be measured with current meter or unsteady-flow regime in the urban-small drainage or hydraulic structure equipment area and can be obtained more exact results than any other discharge measurement techniques.

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Theoretical Calculation of Parabolic Rate Constant for High-Temperature Oxidation of Metals (금속의 고온 산화동안 포물선 속도상수의 이론적 계산)

  • Kim, Insoo;Cho, Weol Dong
    • Journal of the Korean Society for Heat Treatment
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    • v.14 no.5
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    • pp.282-285
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    • 2001
  • Based on the mass balance of anion and cation fluxes, the parabolic rate constant ($K_p$) of oxide grown during the high-temperature oxidation of metal is theoretically calculated. It is assumed that the diffusion of oxygen anion and metal cation through oxide scale obeys the Fick's 1st law, the growth of oxide is controlled by the diffusion of ions, electrical potential gradient as driving force for diffusion of ions is ignored, and oxidation occurs within an existing oxide layer. Then, the parabolic rate constant can be expressed by $K_p=[2{\rho}_{MmOn}{M^2}_{MmOn}(mD_oC_o{^e}+nD_MC_M{^e})/nm]$.

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A New Damping Circuit With a Constant Damping Rate for RFID Applications (RFID 응용을 위한 일정한 감폭율을 갖는 새로운 감폭회로)

  • 오원석;이상훈;이강명;박종태;유종근
    • Proceedings of the IEEK Conference
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    • 2000.06b
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    • pp.125-128
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    • 2000
  • In this paper, we report a new damping circuit with a constant damping rate for RFID applications. The proposed damping circuit is used along with a over-voltage limiter and exhibits almost constant damping rates when the distance between the reader and the transponder varies. This results in keeping the power supply voltage of the transponder constant and in improved reading distances.

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Evaporation Rate of Lead in Molten Copper Alloy by Gas Injection (가스취입에 의한 용융 동 합금 중 납의 증발속도)

  • Kim, Hang-Su;Jeong, Seong-Yeop;Jeong, U-Gwang;Yun, Ui-Han;Son, Ho-Sang
    • Korean Journal of Materials Research
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    • v.12 no.1
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    • pp.68-74
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    • 2002
  • The lead has to be removed for the recycling of copper alloy. The lead cannot be removed from the copper alloy by oxidation. It can be removed by the evaporation because of its high vapor pressure. However, rare information is found on removal of lead from copper alloy. The purpose of present work is to provide a fundamental knowledges on the removal of lead from the copper alloy by evaporation. Gas injection was made in molten copper alloy, and the evaporation rate of lead was measured. The influence of Ar gas flow rata(2~4 L/min), initial contents of lead(2~4wt%Pb), temperature(1200~140$0^{\circ}C$) was investigated based on the thermodynamic and the kinetics. The rate constant is increased with increasing flow rate of Ar and temperature. Though amount of lead removed is increased with higher initial lead concentration, the rate constant is not changed significantly. The activation energy is estimated from the temperature dependence of the rate constant. Also removal of lead from the copper by adding chloride was made for the comparison.

Estimation of NO$_2$ Source Generation and Ventilation rate in Residence by Multiple Measurements

  • Won Ho, Yang;Gi Yeong, Lee
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.05a
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    • pp.155-160
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    • 2003
  • Indoor air quality can be affected by indoor sources, ventilation, decay and outdoor levels. Although technologies exist to measure these factors, direct measurements are often difficult. The purpose of this study was to develop an alternative method to characterize indoor environmental factors by multiple indoor and outdoor measurements. Daily indoor and outdoor $NO_2$ concentrations were measured for 30 consecutive days in 28 houses in Brisbane, Australia, and for 21 consecutive days in 37 houses in Seoul, Korea. Using a mass balance model and regression analysis, penetration factor (ventilation rate divided by the sum of ventilation rate and deposition constant) and source strength factor (source strength divided by the sum of ventilation rate and deposition constant) were calculated using multiple indoor and outdoor measurements. Subsequently, the ventilation rate and $NO_2$ source strength were estimated. Geometric means of ventilation rate were 1.44 ACH in Brisbane, assuming a residential $NO_2$ deposition constant of 1.05 $hr^{-1}$, and 1.36 ACH in Seoul, with the measured residential $NO_2$ deposition constant of 0.94 $hr^{-1}$. Source strengths of $NO_2$ were 15.8 $\pm$ 18.2 ${\mu}g$/$m^3$.hr and 44.7 $\pm$ 38.1${\mu}g$/$m^3$.hr in Brisbane and Seoul, respectively. In conclusion, indoor environmental factors were effectively characterized by this method using multiple indoor and outdoor measurements.

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Fluorescence Quenching of Coumarin Laser Dyes by N,N-dimethylaniline (N,N-dimethylaniline에 의한 Coumarin 색소분자의 형광 소광)

  • Park, Guk Hee;Kang, Tai Jong
    • Journal of the Korean Chemical Society
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    • v.42 no.1
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    • pp.22-27
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    • 1998
  • Fluorescence quenching of coumarin 153 and coumarin 481 with N,N-dimethylaniline in various solvents was investigated. Quenching rate constants are related to diffusion-limited rate constants to some extent. It is noted that smaller discrepancy was observed between the diffusion-limited rate constant and the experimental quenching rate constant when the stick boundary condition rather than the slip boundary condition was applied for estimating the diffusion coefficients. In nonpolar solvent like cyclohexane fluorescence quenching is adequately explained by the diffusion controlled process within the experimental error, but in acetonitrile the quenching rate constant was estimated to be consistently smaller than the diffusion limited rate constant. This may suggest that fluorescence quenching of coumarin dyes be affected not only by the molecular diffusion but also by the intramoleccular process such as charge separation.

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Estimation of Nitrogen Dioxide Source Generation and Ventilation Rate in Residence Using Multiple Measurements in Korea

  • Chung, Moon-Ho;Yang, Won-Ho
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2004.12a
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    • pp.45-50
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    • 2004
  • Indoor air quality can be affected by indoor sources, ventilation, decay and outdoor levels. Alt hough technologies exist to measure these factors, direct measurements are often difficult. The purpose of this study was to develop an alternative method to characterize indoor environmental factors by multiple indoor and outdoor measurements. Daily indoor and outdoor NO2 concentrations were measured for 30 consecutive days in 28 houses in Brisbane, Australia, and for 21 consecutive days in 37 houses in Seoul, Korea. Using a mass balance model and regression analysis, penetration factor (ventilation rate divided by the sum of ventilation rate and deposition constant) and source strength factor (source strength divided by the sum of ventilation rate and deposition constant) were calculated using multiple indoor and outdoor measurements. Subsequently, the ventilation rate and NO2 source strength were estimated. Geometric means of ventilation rate were 1.44 ACH in Brisbane, assuming a residential NO2 deposition constant of 1.05 hr-1, and 1.36 ACH in Seoul, with the measured residential NO2 deposition constant of 0.94 hr-1. Source strengths of N02 were 15.8 ${\pm}$ 18.2 ${\mu}$g/m3${\cdot}$hr and 44.7 ${\pm}$ 38.1 ${\mu}$g/m3${\cdot}$hr in Brisbane and Seoul, respectively. In conclusion, indoor environmental factors were effectively characterized by this method using multiple indoor and outdoor measurements.

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Drying Characteristics of Plating Sludge by Microwave (마이크로파 가열에 의한 도금슬러지 건조특성)

  • 문경환;손종렬;김덕찬
    • Journal of environmental and Sanitary engineering
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    • v.13 no.1
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    • pp.9-15
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    • 1998
  • Microwave heating and drying processes have been well established in various industrial applications. Feasibilities of successful application of microwave drying to many material have been shown on the laboratory or pilot-plant scale. The microwave drying behavior of plating sludge are considered in this paper. The plating sludge containing 70%, 80% and 90% water exposed to microwave power at 2,450 MHz, 700W. An experimental microwave drying apparatus was designed and constructed to monitor weight loss during drying. By studying the drying characteristic curve, the moisture in sludge was almost classified into two categories : free moisture and intestinal moisture. And the critical moisture contents at which the drying rate ceases to be constant were from 10.1 to 10.5%. A simple drying model is proposed which may be used to describe drying behavior of plating sludge. The constant rate and the falling rate periods in microwave drying were addressed separately. From the eqation of constant rate period the drying rate constants decreased exponentially with increasing depth. Microwave heating compared with conventional heating offered higher heating rates from 9 to 16 times. Therefore, microwave drying process can be effective in removing moisture from plating sludge.

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A Study on Jet Characteristic using a Coanda Effect in a Constant Expansion Rate Nozzle (코안다 효과를 이용한 제트 특성에 관한 연구)

  • Lee, Dong-Won;Lee, Sak;Kim, Byung-Ji;Kwon, Soon-Bum
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.35 no.8
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    • pp.706-713
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    • 2007
  • The jet structure issuing from a conventional convergent nozzle of variable expansion rate is compared with the result from the nozzle of a constant expansion rate using a normal type annular slit. In experiments, to investigate the jet characteristics between the two cases of jet, the mean velocity of nozzle exit is fixed to be 90m/s, the pressures along the jet axis and radial directions are measured by a scanning valve system moving with 3-axis auto-traverse unit, and the velocity distribution obtained by calculation from the measured static and total pressures is compared. Also to obtain the highly stable and convergence jets, it is turned out that the flow through a nozzle of constant expansion rate using the Coanda effect with an annular slit is the most preferable than that case through variable expansion rate nozzle. Furthermore, it is found that the pressure drop along the nozzle for the constant expansion rate nozzle is small relatively against to the case of variable expansion rate nozzle.