• Title/Summary/Keyword: Rare metal

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Thermoluminescent Properties by the Cooling Temperature and Grain Size in the LiYSiO4 : La Phosphors (LiYSiO4: La 열형광체의 온도에 따른 열발광 특성)

  • Kim, Young-Kook
    • Korean Journal of Materials Research
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    • v.19 no.9
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    • pp.494-498
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    • 2009
  • The thermoluminescent phosphors of LiYSi$O_4$ containing rare earth metal(La) dopants of 1 wt.%5 wt.% were prepared, and their TL characteristics have been investigated as a function of parameters such as the doping level and the heating rate. The grain size and cooling temperature of the highly sensitive LiYSi$O_4$: La phosphors have been investigated. The glow curve of LiYSi$O_4$: La has two peaks ($P_1,\;P_2$), and the peak height ratio of the two peaks is called $P_2/P_1$; here, the main peak is $P_2$. Experimental results indicate that the peak height ratios of the glow curve for LiYSi$O_4$: La are clearly correlated with the grain size and cooling temperature. The maximum $P_2/P_1$ ratio 3.25, the maximum sensitivity was observed for a grain size between 100-150 ${\mu}m$. The intensity of the TL peak of the phosphors was linearly proportion to the dose of X-rays.

A study on the alexandrite-like cubic zirconia single crystal by skull melting method (스컬법에 의한 alexandrite-like cubic zirconia 단결정성장에 관한 연구)

  • 석정원;최종건
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.5
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    • pp.205-210
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    • 2003
  • Alexandrite-like cubic zirconia single crystals were grown by skull melting method. The R.F. generator (output power is 35 ㎾) used for skull melting was operated at 2 MHz. The grown crystals were doped with up to 1 or 1.5 wt% and 0.5 or 1 wt% of rare earth metal ion (Pr, Nd) on$ ZrO_2-Y_2O_3$ (12 mol%). The grown crystals were cut for slice (0.25 mm) and round brilliant (12 mm in diameter). The cut stones were heat treated in air and nitrogen at $1000^{\circ}C$ for 2 hours and their optical absorption spectra ($\lambda$ = 400∼700 nm) data were obtained.

A study on the revival of learning policy of Kwang-Hae-Kun (광해군조의 문예진흥 정책)

  • 강혜영
    • Journal of Korean Library and Information Science Society
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    • v.25
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    • pp.405-439
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    • 1996
  • During his reign, Kwang-Hae-Kun has done various works to promote literature and book acquisition. Among those works is the establishment of a special office called 'Tok Seo Dang' as he was enthroned in 1608, though it was demolished in 1622. And 'Seo Chuk Kyo In To Kam' was built to recover the scattered and lost books. He encouraged the people to collect and publish books by rewarding those who were engaged in a sort of library works. Their primary responsibility was to collect rare and essential resources, seek the material even in China and publish them using metal printing type. They even sought the diaries and newsletters which the individuals kept at their house. The collected materials were first copied and then kept in 'Shilok' shrine. Among the imported books are Dae Myung Hoi Chon, Chon Choo Sa Chon, Tong Kam Chan Yo, Du Si Tong Chon, Ok Hae, Mun Seon, Hak Hae, Lim Geo Man Rok and some were without titles. Majority of the compiled materials were medical books and geographies like Shin Cheung Tong Kak Yeu Chi Seung Ram, Tong Eui Po Kam, etc. Because of this strenuous effort, they were able to collect and retrieve lots of books and materials between 1608 and 1623. Majority of the published books were of Confucianism(13) which were followed by Political and Legal items(5), Historical documents(3), literature (3), etc. Regarding our library history, one should never forget Kwang-Hae-Kun's significant and remarkable contribution to it.

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Calculation of the Activity Coefficients of Ions in Weak Electrolyte Solutions (묽은 전해질용액에서 이온의 활동도계수 계산)

  • Lee, Man-Seung;Son, Seong Ho
    • Resources Recycling
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    • v.27 no.5
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    • pp.9-13
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    • 2018
  • The equilibrium constant of a chemical reaction is related to the standard Gibbs free energy change. Since equilibrium constant is defined as the ratio of the activities of the chemical species, it is necessary to consider the non-ideal behavior of the solutes as ionic strength of the solution increases. In this paper, the derivation of Debye-$H{\ddot{u}}ckel$ limiting law and its modification by which the activity coefficient of an ion can be calculated was explained. Moreover, the method to obtain the activity coefficient of an ion from the experimentally determined mean activity coefficients of an electrolyte was explained.

A Case of Multi-organ Failure due to Acute Chromic Acid Poisoning (급성 크롬산 중독으로 인한 다발성 장기 부전 1례)

  • Jung, Hyun Min;Eun, Hee Min;Paik, Jin Hui;Kim, Ji Hye;Kim, Jun Sig;Han, Seung Baik
    • Journal of The Korean Society of Clinical Toxicology
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    • v.10 no.2
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    • pp.118-121
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    • 2012
  • Chromic acid is a strong metal acid and acute poisoning is very rare. However, chromic acid causes serious complications, such as skin injuries, as well as renal and hepatic failure. We report on a case of a 47-year-old male who accidentally had chromic acid spilled over his nose and face. For the first few days, he was treated with ascorbic acid and massive hydration. However, after three days, his condition began to worsen. He was treated with hemodialysis for anuria and acute renal failure, and antibiotics for pneumonia. On day 10 of hospitalization, he expired of multi-organ failure. We suggest firm control and close supervision of chromic acid in the work place, and, considering severe complications of chromic acid, we propose a nearly and aggressive treatment.

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Recovery of Platinum from Spent Petroleum Catalysts by Substrate Dissolution in Sulfuric Acid

  • Lee, Jae-Chun;Jinki Jeong;Kim, Wonbaek;Jang, Hee-Dong
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.472-477
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    • 2001
  • Spent catalysts containing platinum were generated in petroleum refinery and other chemical industries. The reclamation of precious metals from such wastes has long been attempted in view of their rare, expensive and indispensable nature. In this study, the recovery of platinum from petroleum catalysts was attempted by a method consisting mainly of dissolving alumina substrate with sulfuric acid thereby concentrating insoluble platinum. Also, platinum dissolved partially in sulfuric acid was recovered by a cementation method using aluminum metal as a reductive agent. The effect of temperature, time, concentration of sulfuric acid. and pulp density on the dissolution of substrate was investigated. When the substrate of platinum catalyst was ${\gamma}$-AI$_2$O$_3$ about 95% alumina was dissolved in 6.0M sulfuric acid at 10$0^{\circ}C$ for 2 hours. When the substrate was the mixture of ${\gamma}$-A1$_2$O$_3$and $\alpha$-A1$_2$O$_3$about 92% was dissolved after 4 hours. As a result, more than 99% of platinum could be recovered by this method and aluminum sulfate was obtained as byproduct.

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Weldability of SUS304 and Ti Dissimilar Welds with Various Welding Speed using Single Mode Fiber Laser (싱글모드 파이버 레이저를 이용한 SUS304와 Ti 이종재료의 용접속도에 따른 용접특성)

  • Lee, Su-Jin;Katayama, Seiji;Kim, Jong-Do
    • Journal of Welding and Joining
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    • v.31 no.5
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    • pp.64-70
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    • 2013
  • The joining of Ti and SUS304 dissimilar metals is one of the effective measures to save rare metal. But Ti and SUS304 have differences in materials properties, and Ti and Fe intermetallic compounds such as TiFe and $TiFe_2$ are easily formed in weld fusion zone between Ti and SUS304. Nevertheless, in this study, full penetration lap dissimilar welding of Ti and SUS304 using single-mode fiber laser with ultra-high welding speed was tried, and it was found out that ultra-high welding speed could control the generation of intermetallic compound. To recognize the formation of intermetallic phase in the weld fusion zone and the compound zone of interface weld area were observed and analyzed using energy dispersive X-ray spectroscopy (EDX). And it was confirmed that the ultra-high welding speed could reduce amount of intermetallic compounds, but the intermetallic compounds were existed in the weld fusion zone under the all conditions.

Fabrication of CNT Flexible Field Emitters and Their Field Emission Properties

  • Shin, Dong-Hoon;Song, Yenan;Sun, Yuning;Shin, Ji-Hong;Lee, Cheol-Jin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.384-384
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    • 2011
  • Carbon nanotubes (CNTs) have been studied as an ideal material for field emitters due to the high aspect ratio, excellent electrical property and good mechanical strength. There were many reports on CNT emitters fabricated on rigid substrates, but rare reports about CNT flexible field emitters. Recently, we considered that CNTs can be a good candidate for a flexible field emitter material because of their excellent Young's modulus and elasticity, which could not be achieved with metal tips or semiconducting nanowire tips. In this work, we demonstrated the CNT flexible field emitters fabricated by a simple method and studied the field emission properties of the CNT flexible field emitters under various bending conditions. The flexible field emitters showed stable and uniform emission characteristics. Especially, there is no remarkable change of the field emission properties at the CNT flexible field emitters according to the bending conditions. The CNT flexible field emitters also exhibited a good field emission performance like the low turn-on field and high emission current. Therefore, we suggest that the CNT flexible emitters can be used in many practical applications under different bending conditions.

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Magnetic characteristics of Pt/Co modualted films (Pt/Co 인공격자다층막의 자기특성에 관한 연구)

  • Kim, Chan-Wook;Onishi, Atushi
    • Korean Journal of Materials Research
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    • v.4 no.2
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    • pp.233-240
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    • 1994
  • We have investigated how the magneto-optical and recording properties of Pt/Co modulated films vary with sample preparation conditions : sputtering at various gas pressures, sputtering with Xe instead of Ar, and etching the buffer layers, etc. The magneto-optical characteristics of Pt/Co multilayers was comparable with those of currently prevailing rare-earth transition-metal alloys(Tb-Fe-Co amorphous films). On a disk of $12{\times}[Pt10.7\;{\AA}/Co2.8{\;}{\AA}]$ multilayer enhanced with 70nm silicon nitride, we have achieved a CNR of 36dB with a reading laser(${\lambda}\;=\;780nm$) power of 2.5-4.5mW for 720KHz carrier at 1.4m/s and the enhanced kerr rotation angle of $1.23^{\circ}$ at 780nm. It is suggested that Pt/Co modulated films clearly are very promising magneto-optical materials for a commercially use.

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Sintering behavior and characterization of Ln0.7Ca0.3MnO3 (Ln=Nd, Sm, La) (Ln0.7Ca0.3MnO3 (Ln=Nd, Sm, La)의 소결 거동 및 특성)

  • Chon, Gom-Bai;Koo, Bon-Heun;Lee, Chan-Gyu
    • Korean Journal of Materials Research
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    • v.16 no.1
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    • pp.44-49
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    • 2006
  • Effects of doping rare earth element on Ln site of $Ln_{0.7}Ca_{0.3}MnO_3$ (Ln=Nd, Sm and La) were examined from sintering behavior, structure and magnetic properties. Sintering reactions proceeded rapidly in order of $La_{0.7}Ca_{0.3}MnO_3>Nd_{0.7}Ca_{0.3}MnO_3>Sm_{0.7}Ca_{0.3}MnO_3$. This result can be explained by diffusivity of metal cation. Size of a-axis increased as following order of La$Nd_{0.7}Ca_{0.3}MnO_3$, 93K for $Sm_{0.7}Ca_{0.3}MnO_3$ and 225K for $La_{0.7}Ca_{0.3}MnO_3$ were obtained. This result coincides with change of Mn-O bond length causing by a-axis lattice constant.