• Title/Summary/Keyword: Rare

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Study on Reaction Behavior of Mg-FeB Phase for Rare Earth Elements Recovery from End-of-life Magnet

  • Sangmin Park;Dae-Kyeom Kim;Rongyu Liu;Jaeyun Jeong;Taek-Soo Kim;Myungsuk Song
    • Journal of Powder Materials
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    • v.30 no.2
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    • pp.101-106
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    • 2023
  • Liquid metal extraction (LME), a pyrometallurgical recycling method, is popular owing to its negligible environmental impact. LME mainly targets rare-earth permanent magnets having several rare-earth elements. Mg is used as a solvent metal for LME because of its selective and eminent reactivity with rare-earth elements in magnets. Several studies concerning the formation of Dy-Fe intermetallic compounds and their effects on LME using Mg exist. However, methods for reducing these compounds are unavailable. Fe reacts more strongly with B than with Dy; B addition can be a reducing method for Dy-Fe intermetallic compounds owing to the formation of Fe2B, which takes Fe from Dy-Fe intermetallic compounds. The FeB alloy is an adequate additive for the decomposition of Fe2B. To accomplish the former process, Mg must convey B to a permanent magnet during the decomposition of the FeB alloy. Here, the effect of Mg on the transfer of B from FeB to permanent magnet is observed through microstructural and phase analyses. Through microstructural and phase analysis, it is confirmed that FeB is converted to Fe2B upon B transfer, owing to Mg. Finally, the transfer effect of Mg is confirmed, and the possibility of reducing Dy-Fe intermetallic compounds during LME is suggested.

Industrial Feature of Rare Metals in Electronic Components (전자부품산업에서의 희소금속의 산업적 특징)

  • Kim, Taek-Soo;Lee, Min-Ha;Kim, Bum-Sung;Choi, Han-Shin;Kim, Yong-Hwan;Lee, Hyo-Soo
    • Journal of the Microelectronics and Packaging Society
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    • v.18 no.2
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    • pp.1-9
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    • 2011
  • Rare metals, called as vitamins of industry, are defined as the elements which are very few in the earth and are difficult to extract from ores. The requirements for total amounts of rare metals have increased as the global economics grows and the function of electronic components varies considerably. The rare metals have been maldistributed to America, CIS(Commonwealth of Independent States), China, Australia, Canada as about 80% of total natural resources, which also lead to unequal materials flow or distribution. Therefore, it was needed to investigate the feature of rare metals in terms of industry as well as technology. We could identify the industrial issues associated with the supply of critical rare elements in electronic components.

A Study on Demand Forecasting Model of Domestic Rare Metal Using VECM model (VECM모형을 이용한 국내 희유금속의 수요예측모형)

  • Kim, Hong-Min;Chung, Byung-Hee
    • Journal of Korean Society for Quality Management
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    • v.36 no.4
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    • pp.93-101
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    • 2008
  • The rare metals, used for semiconductors, PDP-LCS and other specialized metal areas necessarily, has been playing a key role for the Korean economic development. Rare metals are influenced by exogenous variables, such as production quantity, price and supplied areas. Nowadays the supply base of rare metals is threatened by the sudden increase in price. For the stable supply of rare metals, a rational demand outlook is needed. In this study, focusing on the domestic demand for chromium, the uncertainty and probability materializing from demand and price is analyzed, further, a demand forecast model, which takes into account various exogenous variables, is suggested, differing from the previously static model. Also, through the OOS(out-of-sampling) method, comparing to the preexistence ARIMA model, ARMAX model, multiple regression analysis model and ECM(Error Correction Mode) model, we will verify the superiority of suggested model in this study.

A Study on the Recovery of Rare Earth Minerals from Ja-Eun Iron Ore. (자은철광석으로부터 희토류광물 회수에 관한 연구)

  • Jeon, Ho-Seok;Kim, Joon-soo;Moon, Young-bae;Lee, Jae-Jang
    • Journal of Industrial Technology
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    • v.21 no.A
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    • pp.257-261
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    • 2001
  • The separation of rare earths minerals is very difficult because of their similar chemical properties. The rare earth minerals are used as the mixed rare earth minerals or the misch metal without separation to each element. However, the high purity rare earths are recently produced commercially to each element so they there are used as the materials for high tech. Based on the characterization results for the raw minerals, we have developed a combined process containing gravity seperation, magnetic seperation and flotation. The result obtained from this study is monazite concentration of TREO grade 69.11% and Recovery 56.02%.

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Production of Rare Monosaccharides Using Microorganisms and Their Enzymes

  • Izumori, Ken;Bhuiyan, Shakhawat Hossain
    • Food Industry And Nutrition
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    • v.2 no.1
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    • pp.16-21
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    • 1997
  • Microbial of enzymatical methods are suitable for production of rare monosaccharides. Using oxidation and reduction ability of Microorganisms, various rare ketoses and polyols can be produced, for example D-tagatose from galagtitol by Enterobacter agglomerans strain 221e. L-tagatose from galactitol by Klebsiella pheumonias strain 40b, L-psicose from allitol by Gluconobacter frateurii IFO 3254, D-talitol from d-tagatose by Aureobasidium pullulans strain 113B, allitol from D-psicose by Enterobacter agglomerans strain 221e and so on. We can produce various rare aldoses and ketoses using aldose isomerases, for example L-galactose from L-tagatose by D-arabnose isomerase, and L-ribose from L-ribulose by L-isomerase, and so on. D-Tagatose 3-epimerase of Pseudomonas sp. ST-24 is very useful for preparationof various rare ketoses, for example D-psicose from D-fructose, D-sorbose from D-tagatose, L-fructose, from L-psicose and so on. Using polyol dehydrogenases, aldose isomerases and D-tagatose 3-epimerase, we can design the suitable for production of a certain rare monosaccharide from a suitable substrate.

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Recovery of Rare Earth Metal from Used Automotive Three-Way Catalyst (자동차용 폐 삼원촉매로부터의 희귀금속 회수공정 기술 동향)

  • Hong, Yeon Ki
    • Journal of Institute of Convergence Technology
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    • v.1 no.1
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    • pp.13-17
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    • 2011
  • The car industry is one of the technological applications which more rare earth metals employes as three-way catalysts. Therefore, the recovery of rare earth metals from the used automotive three-way catalysts could be important source to obtain these metals. This work presents the analysis of market and demand for rare earth metal in automotive three-way catalyst and introduces the dry and the wet processes for the recovery of rare earth metals from used three-way catalyst. Finally, the alternative methods to conventional wet processes was simply suggested based on the economic and ecological point of view.

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Development of the Environmental Impact Assessment Techniques for the Grading of Rareness in Plant (식물의 희소성 평가를 위한 환경영향평가기법 개발)

  • Lee, You Mi
    • Journal of Environmental Impact Assessment
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    • v.6 no.2
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    • pp.153-164
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    • 1997
  • This study was conducted to develop the new Environmental Impact Assessment techniques for the grading of rareness in plant. 17 EISs which were submitted in 1996 were analyzed to know the problems in existent EIA techniques for the conservation of rare plants. Category of rare plant was reevaluated and evaluation technique for the grading of rareness in plant was developed. The results obtained from this study were as follows: 1. The evaluation technique of rareness in plant was not reflected in the current preparation provision for EIS. And t his fact also appeared in most of the EIS which were reexamined in this study. 2. The category of rare species which have been considered as the subject of protection in EIA have to be enlarged to more than legally protected species designated by MOE. 3. The taxonomic characteristics and status of species, characteristics of population, geographical characters, extent of threat and its possibility by man resulted from the habitat loss were investigated. Each item was endowed scores from 1 to 5 and all the scores were summed, and then this value was used to evaluate the order of conservation. 4. Conservation measures for the rare plants have to be applied according to the levels of rareness grade, and they are absolute conservation, in situ conservation, transplanting and ex situ conservation, post observation and none by the levels from A to E. 5. Considering the phenology of rare plants, investigation for the rare plants have to be made a1 least three times. 6. Size of the MVP(Minimum Viable Population), pollination ecology also have to be considered for the conservation of rare plants. And in the case of adopting ex situ conservation measure, the site and methods for the conservation of rare plants have to be proposed in detail.

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A Study on the Preparation of Rare Earth Oxide Powder for Rare Earth Precipitates Recovered from Spent Ni-MH Batteries (폐니켈수소전지로부터 회수된 희토류 침전물의 희토류 산화물 분말 제조에 대한 연구)

  • Kim, Dae-Weon;Ahn, Nak-Kyoon;Shim, Hyun-Woo;Park, Kyung-Soo;Choi, Hee-Lack
    • Journal of Powder Materials
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    • v.25 no.3
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    • pp.213-219
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    • 2018
  • We report a method for preparing rare earth oxides ($Re_xO_y$) from the recycling process for spent Ni-metal hydride (Ni-MH) batteries. This process first involves a leaching of spent Ni-MH powders with sulfuric acid at $90^{\circ}C$, resulting in rare earth precipitates (i.e., $NaRE(SO_4)_2{\cdot}H_2O$, RE = La, Ce, Nd), which are converted into rare earth oxides via two different approaches: i) simple heat treatment in air, and ii) metathesis reaction with NaOH at $70^{\circ}C$. Not only the morphological features but also the crystallographic structures of all products are systematically investigated using field-emission scanning electron microscopy (FESEM) and X-ray diffraction (XRD); their thermal behaviors are also analyzed. In particular, XRD results show that some of the rare earth precipitates are converted into oxide form (such as $La_2O_3$, $Ce_2O_3$, and $Nd_2O_3$) with heat treatment at $1200^{\circ}C$; however, secondary peaks are also observed. On the other hand, rare earth oxides, RExOy can be successfully obtained after metathesis of rare earth precipitates, followed by heat treatment at $1000^{\circ}C$ in air, along with a change of crystallographic structures, i.e., $NaRE(SO_4)_2{\cdot}H_2O{\rightarrow}RE(OH)_3{\rightarrow}RE_xO_y$.

Analysis of Plantar Foot Pressure During Golf Swing Motion of Pro & Amateur Golfer (프로와 아마추어 골퍼의 골프스윙 동작시 족저압력 비교 분석)

  • Lee, Joong-Sook;Lee, Dong-Ki
    • Korean Journal of Applied Biomechanics
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    • v.15 no.2
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    • pp.41-55
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    • 2005
  • In this study, weight carrying pattern analysis and comparison method of four foot region were suggested. We used three types of club(driver, iron7, pitching wedge). This analysis method can compare between top class golfer and beginner. And the comparison data can be used to correct the swing pose of trainee. If motion analysis system, which can measure the swing speed and instantaneous acceleration at the point of hitting a ball, is combined with this plantar foot force analysis method, new design development of golf shoes to increase comfort and ball flight distance will be available. 1. Regional change of force acting, in address, is evenly distributed on both feet. In back swing top, 76% on right foot, 75% on left foot as impact, and 86% on left foot as finish. As regional force acting, in address, pros get high marks on rare and inside of right foot and rare and outside for amateurs. In back swing top, it is higher as fore and inside of left foot, pros as rare part of right foot and amateurs as forefoot. In impact, it is higher for pros and amateurs in outside and rare part of left foot and fore and inside of right foot. In finish, for both pros and amateurs, it is higher for outside and rare parts of left foot. 2. For each club, forces are evenly distributed on both feet in address. In back swing top, the shorter a club is, the higher impact on right foot and the higher finish distribution on left foot. For all the clubs used, in each region, pros get higher on rare and inside of right foot and as amateurs on rare and outside of left foot in address. In back swing top, for all clubs, pros get higher on rare and outside of right foot as fore and outside for amateurs. In impact acting, for all clubs, rare and outside of left foot get higher. In finish, force concentrates on rarefoot. 3. On both feet force, right foot forces of amateurs is higher than those of pros in back swing top. In impact and finish, pros get higher on left foot.

Separation and Recovery of Rare Earth Elements from Phosphor Sludge of Waste Fluorescent Lamp by Pneumatic Classification and Sulfuric Acidic Leaching

  • Takahashi, Touru;Takano, Aketomi;Saitoh, Takayuki;Nagano, Nobuhiro;Hirai, Shinji;Shimakage, Kazuyoshi
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.421-426
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    • 2001
  • The pneumatic classification and acidic leaching behaviors of phosphor sludge have been examined to establish the recycling system of rare earth components contained in waste fluorescent lamp. At first, separation characteristic of rare earth components and calcium phosphate in phosphor sludge was investigated by pneumatic classification. After pneumatic classification of phosphor sludge, rare earth components were leached in various acidic solutions and sodium hydroxide solution. For recovery of soluble component in leaching solution, rare earth components were separated as hydroxide and oxalate precipitations. The experimental results obtained are summarized as follows: (1) In classification process, rare earth components in phosphor sludge were concentrated to 29.3% from 13.3%, and its yield was 32.9%. (2) In leaching process, sulfuric acid solution was more effective one as a leaching solvent of rare earth component than other solutions. Y and Eu components in phosphor sludge were dissolved in sulfuric acid solution of 1.5 k㏖/㎥, and other rare earth components were rarely dissolved in leaching solution. Leaching degrees of Y and Eu were respectively 92% and 98% in the following optimum leaching conditions; sulfuric acid concentration is 1.5 k㏖/㎥ , leaching temperature 343 K, leaching time 3.6 ks and pulp concentration 30 kg/㎥. (3) Y and Eu components of phosphor sludge contained in waste fluorescent lamp were, effectively recovered by three processes of pneumatic classification, sulfuric acid leaching and oxalate precipitation methods. Their recovery was finally about 65 %, and its purity was 98.2%.

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