• Korean Journal of Environmental Agriculture
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• v.35 no.1
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• pp.24-31
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• 2016

BACKGROUND: Heavy metal adsorption not only depends on rapid cooling slag(RCS) characteristics but also on the nature of the metals involved and on their competitive behavior for RCS adsorption sites. The goal of this study was to investigate the competitive absorption characteristics of Cu, Cd and Zn in single- and multi-metal forms by RCS.METHODS AND RESULTS: Both single- and multi-metal adsorption experiments were conducted to determine the adsorption characteristics of RCS for the heavy metals. Adsorption behaviors of the heavy metals by RCS were evaluated using both the Freundlich and Langmuir adsorption isotherm equations. The maximum adsorption capacities of metals by RCS were in the order of Cu(16.6 mg/g) > Cd(8.1 mg/g) > Zn(6.2 mg/g) in the single-metal adsorption isotherm and Cu(14.5 mg/g) >> Zn(1.3 mg/g) > Cd(0.6 mg/g) in the multi-metal adsorption isotherm. Based on data obtained from Freundlich and Langmuir adsorption models and three-dimensional simulation, multi-metal adsorption behaviors differed from single- metal adsorption due to competition. Cadmium and Zn were easily exchanged and substituted by Cu during multi-metal adsorption.CONCLUSION: Results from adsorption experiments indicate that competitive adsorption among metals increases the mobility of these metals.

• Journal of the Korea Concrete Institute
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• v.25 no.2
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• pp.209-215
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• 2013

This study is aimed to identify the method to use the CaO-$Al_2O_3$ system of rapidly cooled steel making slag (RCSS) as the environment-friendly inorganic accelerating agent by analyzing its physical and chemical properties. The fraction of rapidly cooled steel making slag is distinguished from its fibrous, and the contents of CaO and $Fe_2O_3$ are inversely proportional across different fractions. In addition, as the content of CaO decreased and the content of $Fe_2O_3$ increased, the loss ignition tended to become negative (-) and the density increased. The pore distribution by mercury intrusion porosimetry is very low as compared to the slowly cooled steel-making slag, which indicates that the internal defect and the microspore rate are remarkably lowered by the rapid cooling. To analyze the major minerals the rapidly cooled steel-making slag, XRD, f-CaO quantification and SEM-EDAX analysis have been performed. The results shows that f-CaO does not exist, and the components are mainly consisted of $C_{12}A_7$ and reactive ${\beta}-C_2S$.

• Journal of Advanced Marine Engineering and Technology
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• v.25 no.5
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• pp.1122-1129
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• 2001

Underwater wet arc welding process was experimentally investigated by using the six types of flux coated electrodes of 3.2 mm diameter and the KR-RA steel plate of 11 mm thickness as base metal. Two types of electrodes were domestic covered arc welding electrode(CR13, CR14) and another two types of wet welding electrodes(UWCS, TN20)were imported goods, and the other two type (UWX1, UWX2) were individually designed flux coated electrodes for experimental welding purpose. Main experimental results are summerized as follows: 1. It is ascertained that individually designed flux coated electrode(UWX1) could be used in practice with KR-RA steel plate for underwater wet arc bead welds. 2. Welding arc can be generated easily and considerably kept in stable using TN20 and UWX1 electrodes. 3. The micro Vickers hardness value and the portion of martensite in the HAZ were increased in all the electrodes by rapid cooling rate, but it is relatively maintain stable for UWCS, TN20 and UWX1 electrodes.

• Journal of the Korea Institute of Building Construction
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• v.16 no.2
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• pp.97-105
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• 2016

Recently, application case of the ultra rapid hardening concrete-polymer composite(URHCPC) are increasing to repair for the deterioration of pavement. But it is a major disadvantage that the main material is expensive and has environmental load. For these reasons, the development of the economic, eco-friendly materials is needed. Calcium Aluminate Composite (CAC), produced by rapid cooling of atomizing method with molten ladle furnace slag, is a material capable of improving the economic feasibility and reducing the environmental load of URHCPC. In this paper, the properties of CAC and gypsum mixed CAC (GC) as alternative materials of RSC according to the types of polymer dispersion were studied. The results were as follows; compressive strength, tensile strength, flexural strength, bonding strength and modulus of elasticity of the composites using CAC or GC showed higher values than those of plain proportion in 3 hour. In later age, they were at the same level as the general proportions. URHCPC using BPD as polymer dispersion had superior strength properties generally. But modulus of elasticity was the same level as the case of using a SBR latex. According to these results, CAC or GC can partially substituted for RSC to product the URHCPC. When URHCPC uses the BPD as the polymer dispersion, it can be improved performance.