• Journal of Korean Society for Atmospheric Environment
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• v.15 no.5
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• pp.575-586
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• 1999

The size-resolved number concentrations of aerosols ranging from 0.3 to 25 $mu extrm{m}$ were observed in Seoul and Anmyondo in the west coast of Korea during an Yellow Sand phenomenon in April 1998. Number size distributions of aerosols observed in both places are characterized by decrease in small particles of diameter less than 1${\mu}{\textrm}{m}$ and increase in large size between 1.35 and 10${\mu}{\textrm}{m}$ in heavy dust period. For particles in this size range, there was a good correlation between number concentrations observed in both places during the Yellow Sand episode. On the other hand, the number of small particles less than 0.82${\mu}{\textrm}{m}$ decreased, but the correlation between these particles in both places was enhanced during more intense dust period. The number of coarse particle larger than 10 ${\mu}{\textrm}{m}$ showed a distince diurnal variation without a significant change in amplitude, which was more visible in Seoul. It suggests that these coarse particles were more affected by local sources. Form these results, it was range of 1~10${\mu}{\textrm}{m}$ originated possibly from the dust source regions and the source signature depended on the degree of dust intensity.

• Proceedings of the Korea Electromagnetic Engineering Society Conference
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• 2003.11a
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• pp.203-207
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• 2003

Due to the inherent nature of the low flying UAV, obstacle detection is a fundamental requirement in the flight path to avoid the collision from obstacles as well as manned aircraft. In this paper, a preliminary sensor requirements of an obstacle detection system for UAV in low-altitude flight are analyzed, and the automated obstacle detection sensor system is proposed assessing both passive and active sensors such as EO camera, IR, Laser radar, microwave and millimeter radar. In addition, TCAS (Traffic Alert and Collision Avoidance System) are reviewed for the collision avoidance of the manned aircraft system. It is suggested that small-sized radar sensor is the best candidate for the smart UAV because an active radar can provide the real-time informations on range and range rate in the all-weather environment. However, an important constraints on small UAV should be resolved in terms of accommodation of the mass, volume, and power allocated in the payload of the UAV system design requirements.

• Korean Journal of Materials Research
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• v.23 no.7
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• pp.373-378
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• 2013

In order to clarify the effect of C/Ti atom ratios(${\chi}$) on the deformation behavior of $TiC_{\chi}$ at high temperature, single crystals having a wide range of ${\chi}$, from 0.56 to 0.96, were deformed by compression test in a temperature range of 1183~2273 K and in a strain rate range of $1.9{\times}10^{-4}{\sim}5.9{\times}10^{-3}s^{-1}$. Before testing, $TiC_{\chi}$ single crystals were grown by the FZ method in a He atmosphere of 0.3MPa. The concentrations of combined carbon were determined by chemical analysis and the lattice parameters by the X-ray powder diffraction technique. It was found that the high temperature deformation behavior observed is the ${\chi}$-less dependent type, including the work softening phenomenon, the critical resolved shear stress, the transition temperature where the deformation mechanism changes, the stress exponent of strain rate and activation energy for deformation. The shape of stress-strain curves of $TiC_{0.96}$, $TiC_{0.85}$ and $TiC_{0.56}$ is seen to be less dependent on ${\chi}$, the work hardening rate after the softening is slightly higher in $TiC_{0.96}$ than in $TiC_{0.85}$ and $TiC_{0.56}$. As ${\chi}$ decreases the work softening becomes less evident and the transition temperature where the work softening disappears, shifts to a lower temperature. The ${\tau}_c$ decreases monotonously with decreasing ${\chi}$ in a range of ${\chi}$ from 0.86 to 0.96. The transition temperature where the deformation mechanism changes shifts to a lower temperature as ${\chi}$ decreases. The activation energy for deformation in the low temperature region also decreased monotonously as ${\chi}$ decreased. The deformation in this temperature region is thought to be governed by the Peierls mechanism.

• Journal of the Korean Chemical Society
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• v.33 no.2
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• pp.156-163
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• 1989

The $ν_a+amide II$ combination band of thiopropionamide has been recorded for investigation of Hydrogen bonding between thiopropionamide (TPA) and N,N-dimethylalkylamide (DMF, DMA and DMP) in carbon tetrachloride over the range of $5^{\circ}$ to $55^{\circ}$. The combination band of monomeric TPA and hydrogen-bonded TPA can be resolved by Lorentzian-Gaussian product function into monomeric TPA and hydrogen-bonded TPA with amides. The association constants ($K_1$) for the hydrogen-bonded TPA were calculated by the concentrations of the monomeric TPA and the hydrogen-bonded TPA obtained from the computer resolved absorption bands. Thermodynamic parameters for the Hydrogen bonding have been evaluated by the analysis of the temperature dependent spectra. The ${\Delta}$$H^{\circ}$ of hydrogen-bonded TPA with DMF, DMA and DMP have been found to be-12.5, -13.5 and -14.1 kJ/mol, respectively. The corresponding ${\Delta}$$S^{\circ}$for the above system were -15.2, -17.9 and -22.3 J/mol${\cdot}$deg, respectively.

• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.191.2-191.2
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• 2015

Details of carrier dynamics in self-assembled quantum dots (QDs) with a particular attention to nonradiative processes are not only interesting for fundamental physics, but it is also relevant to performance of optoelectronic devices and the exploitation of nanocrystals in practical applications. In general, the possible processes in such systems can be considered as radiative relaxation, carrier transfer between dots of different dimensions, Auger nonradiactive scattering, thermal escape from the dot, and trapping in surface and/or defects states. Authors of recent studies have proposed a mechanism for the carrier dynamics of time-resolved photoluminescence CdTe (a type II-VI QDs) systems. This mechanism involves the activation of phonons mediated by electron-phonon interactions. Confinement of both electrons and holes is strongly dependent on the thermal escape process, which can include multi-longitudinal optical phonon absorption resulting from carriers trapped in QD surface defects. Furthermore, the discrete quantized energies in the QD density of states (1S, 2S, 1P, etc.) arise mainly from ${\delta}$-functions in the QDs, which are related to different orbitals. Multiple discrete transitions between well separated energy states may play a critical role in carrier dynamics at low temperature when the thermal escape processes is not available. The decay time in QD structures slightly increases with temperature due to the redistribution of the QDs into discrete levels. Among II-VI QDs, wide-gap CdZnTe QD structures characterized by large excitonic binding energies are of great interest because of their potential use in optoelectronic devices that operate in the green spectral range. Furthermore, CdZnTe layers have emerged as excellent candidates for possible fabrication of ferroelectric non-volatile flash memory. In this study, we investigated the optical properties of CdZnTe/ZnTe QDs on Si substrate grown using molecular beam epitaxy. Time-resolved and temperature-dependent PL measurements were carried out in order to investigate the temperature-dependent carrier dynamics and the activation energy of CdZnTe/ZnTe QDs on Si substrate.

• Journal of Korean Vacuum Science & Technology
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• v.4 no.1
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• pp.23-26
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• 2000

We have fabricated by metal organic chemical vapor deposition (MOCVD) In$\_$0.13/Ga$\_$0.87/N/GaN multiple quantum well (MQW) with thickness as thin as 10 A and barriers also of th same width on (0001) sapphire substrate. We have investigated this thin MQW by steady-state and time-resolved photoluminescence(PL) in picosecond time scale in a wide temperature range from 10 to 290 K. In the PL at 10 K, we observed a broad peak at 3.134 eV which was attributed to the quantum well emission of InGaN. The full width at half maximum (FWHM) of this peak was 129 meV at 10 K and its broadening at low temperatures was considered to be due to compositional fluctuations and interfacial disorder in the alloy. The narrow width of the quantum well was mainly responsible for the broadening of the emission linewidth. We also observed an intense and sharp peak at 3.471 eV of GaN barrier. From the temperature dependent PL measurements, the activation energy of the InGaN quantum well emision peak was estimated to be 69 meV. The lifetime of the quantum well emission was found to be 720 ps at 10 K, which was explained in terms of the exciton localization arising from potential fluctuations.

• Journal of the Korean Chemical Society
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• v.30 no.6
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• pp.510-515
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• 1986

Spectra for the $v_3$+ Amide II combination band of thioacetamide(TA) were obtained in carbon tetrachloride solutions and in very dilute solutions of TA-N,N-dimethlylacetamide (DMA) in carbon tetrachloride in the range of 5~55$^{\circ}$C. The combination band in the three component system can be resolved into components due to monomeric TA, 1 : 1 TA-DMA complex and 1 : 2 TA-DMA complex. In the dilute solutions the experimental spectrum was resolved by using the computer into its two Lorentzian-Gaussian product components which have been identified with the monomeric TA and the 1 : 1 complex. The equilibrium constants and thermodynamic parameters of 1 : 1 complex were determined by analysis of concentration and temperature dependent spectra. The ${\Delta}H^{\circ}$ and ${\Delta}S^{\circ}$ for the 1 : 1 complex were -14.4 KJ mol$^{-1}$ and -15.6 J mol$^{-1}deg^{-1}$, respectively.

• Particle and aerosol research
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• v.9 no.1
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• pp.7-21
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• 2013

Twelve-hour size-resolved atmospheric aerosols were measured to determine size distributions of water-soluble organic carbon(WSOC) during daytime and nighttime, and to investigate sources and formation pathways of WSOC in individual particle size classes. Mass, WSOC, ${NO_3}^-$, $K^+$, and $Cl^-$ at day and night showed mostly bimodal size distributions, peaking at the size range of $0.32-0.55{\mu}m$(condensation mode) and $3.1-6.2{\mu}m$(coarse mode), respectively, with a predominant condensation mode and a minor coarse mode. While ${NH_4}^+$ and ${SO_4}^{2-}$ showed unimodal size distributions which peaked between 0.32 and $0.55{\mu}m$. WSOC was enriched into nuclei mode particles(< $0.1{\mu}m$) based on the WSOC-to-mass and WSOC-to-water soluble species ratios. The sources and formation mechanisms of WSOC were inferred in reference to the size distribution characteristics of inorganic species(${SO_4}^{2-}$, ${NO_3}^-$, $K^+$, $Ca^{2+}$, $Na^+$, and $Cl^-$) and carbon monoxide. Nuclei mode WSOC was likely associated with primary combustion sources during daytime and nighttime. Among significant sources contributing to the condensation mode WSOC were homogeneous gas-phase oxidation of VOCs, primary combustion emissions, and fresh(or slightly aged) biomass burning aerosols. The droplet mode WSOC could be attributed to aqueous oxidation of VOCs in clouds, cloud-processed biomass burning aerosols, and small contributions from primary combustion sources. From the correlations between WSOC and soil-related particles, and between WSOC and sea-salt particles, it is suggested that the coarse mode WSOC during daytime is likely to condense on the soil-related particles($K^+$ and $Ca^{2+}$), while the WSOC in the coarse fraction during nighttime is likely associated with the sea-salt particles($Na^+$).

• Analytical Science and Technology
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• v.36 no.4
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• pp.180-190
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• 2023

The presence of process related impurities in any drug or the drug product was associated with its safety, stability and efficacy. The overall literature survey proved that there is no method published on the assessment of process related impurities in brigatinib. In this study, a simple, reliable and stable HPLC qualitative method was reported for quantification of process related impurities with easy and quick extraction procedure. The impurities along with standard brigatinib was resolved on Lichrospher^® C18 (250 mm × 4.6 mm; 5 ㎛ particle size) column in room temperature using methanol, acetonitrile, pH 4.5 phosphate buffer in 55:25:20 (v/v) at 1.0 mL/min as mobile phase and UV detection at 261 nm. The method produces well resolved peaks at retention time of 4.60 min, 12.28 min, 3.37 min, 7.34 min and 8.39 min respectively for brigatinib, impurity A, B, C and D. The method produces a very sensitive detection limit of 0.0065 ㎍/mL, 0.0068 ㎍/mL, 0.0053 ㎍/mL and 0.0058 ㎍/mL for impurity A, B, C and D respectively with calibration curve linear in the concentration range of 22.5-135 ㎍/mL for brigatinib and 0.0225-0.135 ㎍/mL for impurities. The method produces all the validation parameters under the acceptable level and doesn't produces any considerable changes in peak area response while minor changes in the developed method conditions. The method can effectively resolve the unknown stress degradation products along with known impurities with less % degradation. The method can efficiently resolve and quantify the impurities in formulation and hence can suitable for the routine quality analysis of brigatinib in raw material and formulation.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.117-117
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• 2012

Si:Ge alloy semiconductor nanocrystals (NCs) offer challenging opportunities for integrated optoelectronics/optoplasmonics, since they potentially allow unprecedentedly strong light-matter interaction in the wavelength range of the optical communication. In this talk, we discuss the recent research efforts of my laboratory to develop optoelectronic components based on individual group IV NCs. We present experimental demonstration of the individual NC optoelectronic devices, including broadband Si:Ge nanowire (NW) photodetectors, intra NW p-n diodes, Ge NC electrooptical modulators and near-field plasmonic NW detectors, where the unique size effects at the nanometer scales commonly manifest themselves. In particular, we demonstrated a scanning photocurrent imaging technique to investigate dynamics of photocarriers in individual Si:Ge NWs, which provides spatially and spectrally resolved local information without ensemble average. Our observations represent inherent size-effects of internal gain in semiconductor NCs, thereby provide a new insight into nano optoplasmonics.