• Title/Summary/Keyword: Range of variation

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Effect of Thermal Imidization and Curing on Fluorescence Behavior of a Phenylethynyl-Terminated Poly(amic acid)

  • Cho, Donghwan;Yang, Gyeongmo;Drzal, Lawrence T.
    • Macromolecular Research
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    • v.11 no.5
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    • pp.297-302
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    • 2003
  • The imidization and cure reaction of a thermosetting phenylethynyl-terminated amic acid (LaRC PETI-5) in film form have been monitored as a function of temperature by means of a steady-state fluorescence technique using a front-face illumination method. The variation of the fluorescence emission spectra of LaRC PETI-5 can be divided into four temperature regions; Region I: below 15$0^{\circ}C$, Region II: 150-25$0^{\circ}C$, Region III: 250-35$0^{\circ}C$, and Region IV: above 35$0^{\circ}C$. The fluorescence spectra in Region I are largely influenced by residual N-methyl-2pyrrolidinone in the polymer and also slightly by partial imidization of the polymer. There is a combined effect of imidization and solvent removal on the fluorescence behavior in Region II. The spectra in Regions III and IV are due significantly to the cure reaction of LaRC PETI-5 and to a post-cure effect of the polyimide, respectively. This spectroscopic evidence indicating the transformation of the amic acid imide oligomer into the corresponding polyimide via imidization and cure, agrees well with thermal analysis results obtained previously. The intermediate stage of cure in the range of 250-30$0^{\circ}C$ predominantly influences the change of the fluorescence intensity. The later stage above 30$0^{\circ}C$ significantly influences the position of the spectrum. This fluorescence study also supports the mechanism proposed in earlier work that the crosslinking reaction takes place at the reaction sites in the conjugated polyene and the phenylethynyl end group in the polyimide chain.

Analysis of Behavior Characteristics of Instantaneous Input of Pollutant in River (하천에 순간 유입된 오염물질의 거동 특성 분석)

  • Yoon, Sei-Eui;Ko, Jae-Hyung;Kim, Soo-Youl
    • Journal of Korea Water Resources Association
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    • v.36 no.4
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    • pp.575-586
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    • 2003
  • In case of continuous input of a pollutant, dispersion characteristics do not change much with changing dispersion coefficient, but that of an instantaneous input is very sensitive to the changes of dispersion coefficient. The characteristics of behavior of instantaneous input of a pollutant at the downstream of Han river were analyzed in this paper Field measurement of hydraulic and water quality factors at the downstream of Han river were conducted at low flow condition. The hydraulic factors were used to estimate the longitudinal dispersion coefficient, and the reasonable empirical equations for longitudinal dispersion coefficient at the downstream of Han river were suggested. The measured concentrations of BOD were closely matched with the calculated ones from RMA-4 model. In case of instantaneous input, range of dispersion, transport pathway and the traveltimes of the first and maximum concentration with variation of the longitudinal dispersion coefficients and water levels of downstream boundary were evaluated in this paper.

Thermal Stability of Glass Powder and Rubber-Filled Phenolic Resins and Dynamic Mechanical Properties of Glass Braid/Phenolic Composites (유리분말 및 고무 충진 페놀수지의 열안정성 및 Glass Braid/페놀수지 복합재료의 동역학적 열특성)

  • Yoon, Sung Bong;Cho, Donghwan;Lee, Geon-Woong
    • Journal of Adhesion and Interface
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    • v.8 no.4
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    • pp.14-22
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    • 2007
  • In the present study, the effect of milled glass powder and liquid-type nitrile rubber (NBR) on the thermal stability of phenolic resin and the dynamic mechanical properties of glass braid/phenolic composites has been investigated by means of thermogravimetric analysis and dynamical mechanical analysis. It was found that both milled glass power and NBR filled in the waterborne phenolic resin significantly influenced the thermal stability of phenolic resins and the storage modulus and tan delta of the composites. The presence of glass powder increased the thermal stability of the phenolic resin, whereas the presence of NBR resulted in the weight loss in the specific temperature range. The thermal stability of the phenolic resins without and with the fillers was dependent not only on the cure temperature but also on the cure time. The variation of the storage modulus and tan ${\delta}$ of strip-type glass braid/phenolic composites was also influenced with the introduction of glass powder and NBR to the phenolic matrix as well as by the cure conditions given.

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Chromosome numbers and polyploidy events in Korean non-commelinids monocots: A contribution to plant systematics

  • JANG, Tae-Soo;WEISS-SCHNEEWEISS, Hanna
    • Korean Journal of Plant Taxonomy
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    • v.48 no.4
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    • pp.260-277
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    • 2018
  • The evolution of chromosome numbers and the karyotype structure is a prominent feature of plant genomes contributing to or at least accompanying plant diversification and eventually leading to speciation. Polyploidy, the multiplication of whole chromosome sets, is widespread and ploidy-level variation is frequent at all taxonomic levels, including species and populations, in angiosperms. Analyses of chromosome numbers and ploidy levels of 252 taxa of Korean non-commelinid monocots indicated that diploids (ca. 44%) and tetraploids (ca. 14%) prevail, with fewer triploids (ca. 6%), pentaploids (ca. 2%), and hexaploids (ca. 4%) being found. The range of genome sizes of the analyzed taxa (0.3-44.5 pg/1C) falls well within that reported in the Plant DNA C-values database (0.061-152.33 pg/1C). Analyses of karyotype features in angiosperm often involve, in addition to chromosome numbers and genome sizes, mapping of selected repetitive DNAs in chromosomes. All of these data when interpreted in a phylogenetic context allow for the addressing of evolutionary questions concerning the large-scale evolution of the genomes as well as the evolution of individual repeat types, especially ribosomal DNAs (5S and 35S rDNAs), and other tandem and dispersed repeats that can be identified in any plant genome at a relatively low cost using next-generation sequencing technologies. The present work investigates chromosome numbers (n or 2n), base chromosome numbers (x), ploidy levels, rDNA loci numbers, and genome size data to gain insight into the incidence, evolution and significance of polyploidy in Korean monocots.

Study of Humidity Sensing Properties Related to Metal Content of Aerosol Deposited Ceramic/Metal Composite Films (에어로졸 증착한 세라믹/금속 복합막의 금속 함량에 따른 습도 감지 특성 연구)

  • Kim, Ik-Soo;Koo, Sang-Mo;Park, Chulhwan;Shin, Weon Ho;Lee, Dong-Won;Oh, Jong-Min
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.34 no.5
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    • pp.314-320
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    • 2021
  • Controlling ambient humid condition through high performance humidity sensors has become important for various fields, including industrial process, food storage, and the preservation of historic remains. Although aerosol deposited humidity sensors using ceramic BaTiO3 (BT) material have been widely studied because of their longtime stability, there remain critical disadvantages, such as low sensitivity, low linearity, and slow response/recovery time in case of the sensors fabricated at room temperature. To achieve superior humidity sensing properties even at room temperature condition, BT-Cu composite films utilizing aerosol deposition (AD) process have been proposed based on the percolation theory. The BT-Cu composite films showed gradually improved sensing properties until the Cu concentration reached 15 wt% in the composite film. However, the excessive Cu (above 30 wt%) containing BT-Cu composite films showed a rapid decrease of the sensing properties. The results of observed surface morphology of the AD fabricated composite films, to figure out the metal filler effect, showed correlation between surface topography as well as size and the amount of open pores according to the metal filler content. Overall, it is very important not only dielectric constant of the humidity sensing films but also microstructures, because they affect either the variation range of capacitance by ambient humidity or adsorption/desorption of ambient humidity onto/from the humidity sensing films.

Groundwater Investigation in Northwestern Part of Saudi Arabia (Saudi Arabia 북서부의 지하수조사)

  • 한정상;정수웅
    • Water for future
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    • v.8 no.2
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    • pp.30-40
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    • 1975
  • Hydrogeological survey and geophysical prospecting have been carried out in Saudi Arabia for the purpose of finding groundwater in the soil and rock at the request of General trading company in Jeddah, Saudi Arabia. The surveyed area is located on $38^{\circ}-39^{\circ}$ 30' in longitude and $26^{\circ}-26^{\circ}$ 30' in latitude. The topography of this area is dominated by northwest southeast mountain range composed mostly of precambrian rocks and basalt of tertiary period. Geology is mainly composed of greenstone, granite, andesite, diorite rhyolite of pre-cambrian era and sandstone of cambrian period which are underlained by basalt and andesite of tertiary period and alluvium of quaternary unconformably. The instruments used in this investigation are TR-18B2 radioactivity unit which isjapanese patented and A.C. Terrameter, a resistivity meter manufactured by ABEM of Stockholm, Sweden. Radioactivity method has been conducted along the Alula-Khaybar road, totally 164Km by the car-borne. As a result of the above survey 16 places have been selected and these anomalies show 1.2N-1.6N compared to background of each area in intensity with width of 10-50m. Resistivity vertical profiling which made use of Schlumberger configuration method has been made over selected areas by radioactivity method to provide hydrogeological information for a water resources survey. The result of resistivity shows that good aquifers are located in the western part of surveyed area where sedimentary rock is distributed. The strata showing 10-50, ${\Omega}-m$ in resistivity are thought to be waterbearing layer. The variations in aquifer resistivity found, are thought to be due to verying clay content, which could be related to aquifer yield. It has proved impossible to detect small salinity variation in the buried aquifer by geophysics. As a result of resistivity prospecting 10 places are recommended to be drilled at the anomalies as shown attached map. yields from the proposed holes have been estimated approximately from $20m^3$ to $200m^3$ per day. Prior to drilling for groundwater, test boring using ${\c}4"$ should be drilled in order to obtain more reliable hydrogeological information for the construction of perfect wells.ells.

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Fabrication and Electrical Properties of Anodic Aluminum Oxide Membrane with Various Anodizing Temperatures for Biosensor (바이오센서로 응용을 위한 양극산화알루미늄의 양극산화 온도에 따른 제작 및 전기적 특성)

  • Yeo, Jin-Ho;Lee, Sung-Gap;Kim, Yong-Jun;Lee, Young-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.6
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    • pp.394-398
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    • 2014
  • We fabricated the electrolyte-dielectric-metal (EDM) sensor on the base of AAO (anodic aluminum oxide) template with variation of the anodizing temperature. When a surface is immersed or created in an aqueous solution, a discontinuity is formed at the interface where such physicochemical variables as electrical potential and electrolyte concentration change significantly from the aqueous phase to another phase. Because of the different chemical potentials between the two phases, charge separation often occurs at the interfacial region [1]. This interfacial region, togeter with the charged surface, is usually known as the electrical double layer (EDL) [2]. The structural and electrochemical properties of AAO sensor were investigated for applications in capacitive pH sensors. To change the thickness of the AAO template, the anodizing temperature was varied from $5^{\circ}C$ to $20^{\circ}C$, the thickness of the AAO template invreased from 300 nm to 477 nm. The pH sensitivity of sensors with the anodizing temperature of $20^{\circ}C$ showed the highest value of 56.4 mV/pH in the pH range of 3 to 11. The EDM sensor with the anodizing temperature of $20^{\circ}C$ exhibited the best long-term stability of 0.037 mV/h.

Vertical Analysis of Wind Speed over South Korea for the Flight Safety of HALE UAV (장기체공무인기의 운항안전을 위한 남한지역 고도별 풍속 분석)

  • Cho, Young-Jun;Ha, Jong-Chul;Choi, Reno K.Y.;Kim, Ki-Hoon;Lim, Eunha;Kim, Su-Bok;Yun, Jong-Hwan
    • Journal of the Korea Institute of Military Science and Technology
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    • v.19 no.4
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    • pp.551-558
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    • 2016
  • We analyzed wind speed over South Korea for HALE UAV(High Altitude Long Endurance Unmaned Aerial Vehicle) flight safety. Annual variation of wind speed at 200 hPa showed that winter season was stronger than summer. According to latitude, wind speeds in January and August were found to be $52{\sim}74m\;s^{-1}$ and $15{\sim}26m\;s^{-1}$, respectively. Wind speed was stronger(weaker) at lower latitudes than higher latitudes in winter(summer). Frequency(%) of wind speed less than threshold value($18m\;s^{-1}$) for the operation date was investigated. The days showing the frequency greater than 60 % in all altitudes of surface ~ 50 hPa showed the range of 1 ~ 33 days at 7 stations. Operation date was the longest period at Gosan. The appropriate date of HALE UAV operation at Gosan and Osan is considered as the middle of July ~ middle of August and end of July ~ early August, respectively. These results can be used to determine the operation date of HALE UAV.

Evaluation of Dynamic Delivery Quality Assurance Process for Internal Target Volume Based RapidArc

  • Song, Ju-Young
    • Progress in Medical Physics
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    • v.28 no.4
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    • pp.181-189
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    • 2017
  • The conventional delivery quality assurance (DQA) process for RapidArc (Varian Medical Systems, Palo Alto, USA), has the limitation that it measures and analyzes the dose in a phantom material and cannot analyze the dosimetric changes under the motional organ condition. In this study, a DQA method was designed to overcome the limitations of the conventional DQA process for internal target volume (ITV) based RapidArc. The dynamic DQA measurement device was designed with a moving phantom that can simulate variable target motions. The dose distribution in the real volume of the target and organ-at-risk (OAR)s were reconstructed using 3DVH with the ArcCHECK (SunNuclear, Melbourne, USA) measurement data under the dynamic condition. A total of 10 ITV-based RapidArc plans for liver-cancer patients were analyzed with the designed dynamic DQA process. The average pass rate of gamma evaluation was $81.55{\pm}9.48%$ when the DQA dose was measured in the respiratory moving condition of the patient. Appropriate method was applied to correct the effect of moving phantom structures in the dose calculation, and DVH data of the real volume of target and OARs were created with the recalculated dose by the 3DVH program. We confirmed the valid dose coverage of a real target volume in the ITV-based RapidArc. The variable difference of the DVH of the OARs showed that dose variation can occur differently according to the location, shape, size and motion range of the target. The DQA process devised in this study can effectively evaluate the DVH of the real volume of the target and OARs in a respiratory moving condition in addition to the simple verification of the accuracy of the treatment machine. This can be helpful to predict the prognosis of treatment by the accurate dose analysis in the real target and OARs.

A Petrological Study on the Southwestern Contact Zone of the Boeun Granodiorite, Ogcheon Zone (보은화강섬록암(報恩花崗閃綠岩) 서남부(西南部) 접촉대(接觸帶)에 관(關)한 암석학적(岩石學的) 연구(硏究))

  • Lee, Dai Sung;Park, Jong Sim
    • Economic and Environmental Geology
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    • v.14 no.2
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    • pp.55-76
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    • 1981
  • Southwestern contact zone of the Boeun granodiorite occurs near the thrust fault between the Ogcheon Group and Majeonri Limestone Formation. Ogcheon Group, metasediments composed of the Munjuri Formation, Changri Formation, and unconformably overlying Hwanggangri Formation, belongs to greenschist facies of regional metamorphism accompanied with deformation of two fold axes, $N10^{\circ}E$ and $N45-65^{\circ}E$ directions. Basic metamorphic rocks occurring in the Changri and Limestone Formations are the meta-basalts and meta-diabases of tholeiitic basalt series. The meta-basalts intruded in the Changri Formation as sills, whereas the meta-diabases in the Changri and Limestone Formations as stocks in appearance. They are considered to have emplaced before the formation of two fold axes and related with the thrust fault, based on the geologic setting of the area. The metamorphic facies are identified to be greenschist facies to epidote-amphibolite facies for the meta-basalt, and epidote-amphibolite facies for the meta-diabases. It is interpreted that such a variety of facies was related from the combination of earlier deuteric alteration and later regional metamorphism. The metasediments in southwestern contact zont of the Boeun granodiorite which is a product of later syntectonic intrusion of middle Jurassic in age, show pyroxene-hornfels facies near the contact and amphibole-horenfels facies away from the contact to the mineral zoning in the contact metamorphic aureole of the Limestone Formation, based on the paragenetic analysis of mineral assemblages. The Limestone in the area appears to be considerably $SiO_2-CaO-MgO-CO_2-H_2O$ can be adopted to evaluate equilibrium conditions of the mineral assemblages in each mineral zone. It is revealed that a temperature gradient was existed accross the contact aureole ranging from the higher igneous side to lower sedimentary side, whereas no clear trend of $XCO_2$ variation appears but high mole fraction. The tremolite diopside-quartz-calcite assemblages occurs in common through the most mineral zones of contact aureole that is in good agreement with the equivalent reaction curve which extends over a wide range of $T-XCO_2$ conditions.

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