• Bulletin of the Korean Chemical Society
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• 제34권9호
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• pp.2731-2736
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• 2013

We report a new tetrameric supramolecular Cu(II) complex ($Cu_4L_4$ = tetrakis(N,N'-bis(salicylidene)-2,2'-ethylenedianiline)Copper(II)) with a Schiff-base ligand ($H_2L$ = N,N'-bis (salicylaldimine)-1,2-ethylenediamine) containing two N,O-bidentate chelate groups. Though the copper sites of $Cu_4L_4$ are non-coupled, the complex exhibits a unsually high catecholase-like activity ($k_{cat}=935h^{-1}$) when the $Cu_4L_4$ solution is treated with 3,5-di-tert-butylcatechol (3,5-DTBC) at basic condition in the presence of air. Combined information obtained from UV-VIS and EPR measurements could lead the suggestion of the reaction pathway in which the substrate may bind to Cu(II) ions by anti-anti didentate bridging mode.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2009년도 추계학술발표대회
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• pp.33.2-33.2
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• 2009

Block copolymer lithography has attracted great attention for emerging nanolithography since nanoscaleperiodic patterns can be easily obtained through self-assembly process without conventional top-down patterning process. Since the morphologies of self-assembled block copolymer patterns are strongly dependent on surface energy of a substrate, suitable surface modification is required. Until now, the surface modification has been studied by using random copolymer or self-assembled mono layers (SAMs). However, the research on surface modifications has been limited within several substrates such as Si-based materials. In present study, we investigated the formation of block copolymer on Au substrate by $O_2$ plasma treatment with the SAM of 3-(p-methoxy-phenyl)propyltrichloro-silane [MPTS, $CH_3OPh(CH_2)_3SiCl_3$]. After $O_2$ plasma treatment, the chemical bonding states of the surface were analyzed by X-ray photoelectron spectroscopy (XPS). The static contact angle measurement was performed to study the effects of $O_2$ plasma treatment on the formation of MPTS monolayer. The block copolymer nanotemplates formed on Au surface were analyzed by scanning electron microscopy. The results showed that the ordering of self-assembled block copolymer pattern and the formation of cylindrical nano hole arrays were enhanced dramatically by oxygen plasma treatment. Thus, the oxidation of gold surface by $O_2$ plasma treatment enables the MPTS to form the monolayer assembly leading to surface neutralization of gold substrates.

• 소성∙가공
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• 제22권5호
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• pp.275-279
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• 2013

The tube hydroforming process has received much attention in the automotive industry because of its advantages compared to conventional manufacturing technologies. A wide range of products such as sub-frames, camshafts, radiator frames, axles and crankshafts are made by hydroforming process. The hydroformed parts often need to be structurally joined to other components during assembly. Therefore, these automotive parts need to be manufactured with a localized attachment flange. In this study, FE forming analyses of a part with a rectangular flanged shape was performed with Dynaform 5.5. Using the optimized conditions determined numerically, hydroforming experiments were performed. Then, the characterization of defects was analyzed. Finally, the accuracy of the optimized internal pressure condition as well as that of the initial ram position were evaluated. The results demonstrated that flanged parts can be successfully produced using the tube hydroforming process.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2005년도 추계종합학술대회
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• pp.885-888
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• 2005

In this study, we designed an ARM9 compatible RISC microprocessor using VHDL. The microprocessor was designed to support Harvard architecture with separate instruction cache and data cache. The state machine was optimized for multi-cycle instructions. In addition, a data forwarding mechanism was adopted to reduce the stall cycles due to data hazards. Assembly programs were up-loaded into a ROM block for system-level simulation. Proper operation of the designed microprocessor was confirmed by investigating the contents of the internal registers as well as the RAM block. Futhermore, the simulation results clearly indicated that the operation speed of the processor designed in this study is enhanced by reducing the execution cycles required for multiplication related instructions.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2001년도 춘계학술대회 논문집
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• pp.221-224
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• 2001

The dynamic characteristics of a hydraulic press for micro-stamping are investigated by Finite Element Analysis. This machine requires high precision in producing milli-structure of electric products such as TFT-LCD back-up light reflector. First, the modal analysis of the parts and the assembly of the hydraulic press is performed. Then, the sensitivity analysis is carried out. The results show that the bearing stiffness and the base mounting stiffness affect the specific mode shapes.

• 천문학회보
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• 제42권2호
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• pp.74.1-74.1
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• 2017

The two-halo conformity is that if a central galaxy in a dark matter halo is quenched in star formation, the central galaxies in other neighboring halos (within ~ 4 Mpc) even with no causal contact seem conformed to be quenched. The galactic similarity ranging far beyond the virial radius of each dark matter halo cannot be explained by known environmental effects (ram pressure, tidal interaction, etc.). Here, using a cosmological hydrodynamic simulation, we put forward new physical origins for the phenomenon; the back-splash galaxies scenario and the halo assembly bias scenario. We discuss the relative importance of the two explanations on a quantitative basis.

• 한국음향학회지
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• 제24권1호
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• pp.52-57
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• 2005

AMR-WB 음성부호화기는 50~7000 Hz의 확장된 대역폭을 갖는 음성신호를 압축/복원하는 광대역 음성부호화기로써 6.60 kbit/s에서 23.85 kbit/s까지 9개의 전송 비트율을 가지고 있다. 본 논문에서는 2개의 MAC (Multimply and-Accumulate) 유닛을 가진 Tl의 16bit 고정소수점 DSP인 TMS320C5509 DSP를 이용한 AMR-WB 음성부호화기의 실시간 구현에 관하여 논한다. 실시간 구현은 intrinsic을 이용한 C수준의 구현 및 어셈블리 코딩에 의한 구현을 수행하여 그 결과를 비교하였다. 어셈블리 코딩에 의하여 실시간 구현된 AMR-WB 음성부호화기는 23.85 kbit/s 모드에서 42.9 Mclock의 계산량을 가지며, 사용된 프로그램 메모리는 15.1 kword이고, 데이터 ROM 메모리는 9.2 kword이고 데이터 RAM 메모리는 13.9 kword이다.

• Journal of Ecology and Environment
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• 제40권1호
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• pp.55-65
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• 2016

Background: In this article, it was analyzed how snow melting affects the assembly of lichen and moss communities in a small area of the coastal region of Barton Peninsula, which is in maritime Antarctic. In the small area, even though there is a huge gap of difference of the environment between the snow-filled area and snow-melt one, the latter did not have distinctive environmental gradients. Results: Depending on the snow melting time, coverage and species diversity of lichens and mosses tend to increase remarkably. For species with significant changes depending on the snow-covered period, there are Andreaea regularis, crustose lichens, Placopsis contortuplicata, Usnea aurantiaco-atra, and snow algae. In this area, the process of vegetation assembly process has shown the directional development in the order of snow algae${\rightarrow}$crustose, lichen sub-formation${\rightarrow}$fruticose lichen, moss cushion sub-formation (Andreaea sociation)${\rightarrow}$fruticose lichen, and moss cushion sub-formation (Usnea sociation), according to the order of snow melting. These directional development stages are shown in gradual change in small area with the snow melting phenomena. However, in the snow-free area, where water is sufficiently supplied, it is expected that moss carpet sub-formation (Sanionia sociation) will be developed. Vegetation development in the small area with the snow melting phenomena, depending on differences of resistance on snow kill and moisture settled by species in according to the time of snow melting, tolerance model to form community is followed. Conclusions: The research results explain the development of vegetation in the Antarctic tundra and its spatial distribution according to the period for growth of lichens and mosses in the summer time by differences of snow melting in the small area. In the future, if research for the community development process in a large scale will be done, it will be helpful to figure out temporal and spatial dynamic of vegetation in the Antarctic tundra where snow and glaciers melt rapidly due to climatic warming.

• 대한전자공학회논문지SP
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• 제38권3호
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• pp.304-315
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• 2001

본 논문에서는 3GPP와 ETSI에서 IMT-2000의 음성부호화 방식 표준안으로 채택한 AMR 음성부호화 알고리즘을 분석하고 C 컴파일러와 어셈블리 언어를 이용한 최적화 과정을 거친 후, 고정 소수점 DSP 칩인 TMS320C6201을 이용하여 실시간 구현하였다. 구현된 codec의 프로그램 메모리는 약 31.06 kWords, 데이터 RAM 메모리는 약 9.75 kWords, 그리고 데이터 ROM 메모리는 약 19.89 kWords 정도를 가지며, 한 프레임(20 ms)을 처리하는데 약 4.38 ms가 소요되어 TMS320C6201 DSP 칩의 전체 가용한 clock의 21.94％만 사용하여도 충분히 실시간으로 동작 가능함을 확인하였다. 또한, DSP 보드상에서 구현한 결과가 ETSI에서 공개한 ANSI C 소스 프로그램의 수행 결과와 일치함을 검증하였고, 구현된 AMR 음성부호화기를 sound I/O 모듈과 결합하여 실험한 결과, 어떠한 음질의 왜곡이나 지연 없이 실시간으로 충분히 동작함을 확인하였다. 마지막으로, Host I/O와 LAN 케이블을 이용하여 AMR 음성부호화 알고리즘을 통한 쌍방간 실시간 통신을 full-duplex 모드로 확인하였다.

• 상하수도학회지
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• 제25권5호
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• pp.691-697
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• 2011

In this study, by using the Water footprint technique, the water consumption by washing machines, which holds higher ranks in using water than any other electric appliances, was analyzed during their life cycle. The life cycle is defined as raw materials production step, manufacturing step, and using step. In raw materials production step, Input materials were researched by using LCI DB(Life Cycle Inventory Database) and the water consumption was calculated with consideration of approximately 65% Input materials which were based weight. In manufacturing step, the water consumption was calculated by the amount of energy used in assembly factories and components subcontractors and emission factor of energy. In using step, referring to guidelines on carbon footprint labeling, the life cycle is applied as 5 years for a washing machine and 218 cycles for annual bounds of usage. The water and power consumption for operating was calculated by referring to posted materials on the manufacture's websites. The water consumption by nation unit was calculated with the result of water consumption by a unit of washing machine. As a result, it shows that water consumption per life cycle s 110,105 kg/unit. The water consumption of each step is 90,495 kg/unit for using, 18,603 kg for raw materials production and 1,006 kg/unit for manufacturing, which apparently shows that the using step consume the most water resource. The water consumption by nation unit is 371,269,584tons in total based on 2006, 83,385,649 tons in both steps of raw material production and manufacturing, and 287,883,935 tons in using step.