• Title/Summary/Keyword: Raising temperature

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A Kinetic Study of 2-Phenethyl p-Bromobenzenesulfonate with Substituted Pyridines Under High Pressure (II) (2-Phenethyl p-Bromobenzenesulfonate 와 치환 피리딘과의 고압반응 (제 2 보))

  • Soo-Dong Yoh;Kyung-Hwan Park;Sung-Hong Kim;Jong-Hwan Park
    • Journal of the Korean Chemical Society
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    • v.32 no.1
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    • pp.48-52
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    • 1988
  • Kinetics of the reaction of 2-phenethyl p-bromobenzenesulfonate with substituted pyridines in acetonitrile were investigated by an electric conductivity method at 1-2000 bars and $45{\sim}55{\circ}C$. The rates of these reactions were increased with raising temperatures, pressures and by changing electron-donating substitutents in pyridine. When raising pressure the Hammett reaction parameter $I{\rho}I$ and Bronsted ${\beta}$ values were increased, and isokinetic temperature observed from isokinetic relations hip between ${\Delta}H^{\neq}$ and TEX>${\Delta}S^{\neq}$ was decreased. These results indicate that the $S_N2$ characters were increased with raising pressure.

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Study on Shortening Light-Off Time of Three Way Catalyst and Reduction of Harmful Emissions with Exhaust Synthetic Gas Injection(ESGI) Technology during Cold Start of SI Engines (가솔린 기관의 냉간시동 조건에서 합성가스 배기분사 기술에 의한 촉매의 활성화 온도 도달시간 단축 및 유해배출물 저감에 관한 연구)

  • Cho, Yong-Seok;Lee, Seang-Wock;Won, Sang-Yeon;Song, Chun-Sub;Park, Young-Joon
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.3
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    • pp.94-101
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    • 2008
  • Since regulations of exhaust emissions are continuously reinforced, studies to reduce harmful emissions during the cold start period of SI engines have been carried out very extensively worldwide. During the cold start period, raising the temperature of cold exhaust gas is a key strategy to minimize the light-off time of three way catalysts. In this study, a synthetic gas containing a large amount of hydrogen was injected into the exhaust manifold to raise the exhaust gas temperature and to reduce harmful emissions. The authors tried to evaluate changes in exhaust gas temperature and harmful emissions through controlling the engine operating parameters such as ignition timings and lambda values. Also the authors investigated both combustion stability and reduction of harmful emissions. Experimental results showed that combustion of the synthetic gas in the exhaust manifold is a very effective way for solving the problems of harmful emissions and light-off time. The results also showed that the strategy of retarded ignition timings and increased air/fuel ratios with ESGI is effective in raising exhaust gas temperature and reducing harmful emissions. Futhermore, the results showed that engine operating parameters ought to be controlled to lambda = 1.2 and ignition timing = $0{\sim}3^{\circ}$ conditions to reduce harmful emissions effectively under stable combustion conditions.

A Study on the Comparison of Explosive Lower Limit Concentration & Thermal Specific of Wheat Powder Dust & Salicylic Acid Dust (밀가루분진 및 살리실산분진의 폭발하한농도 및 열적특성 비교에 관한 연구)

  • Ko, Jae-Sun
    • Fire Science and Engineering
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    • v.26 no.4
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    • pp.1-9
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    • 2012
  • We have examined In order to compare each other from explosion and combustion characteristics about the dusts which collects from manufacturing process of wheat flour and cosmetics manufacturing process of functional Keratin removal soap at the small and medium enterprise style. We measured explosive pressure and explosive lower limit which follows in change of concentration change at the time of talc addition uses Hartman dust explosion apparatus, also measured weight loss and endothermic quantity uses DSC and TGA. The explosion test results show that increased explosive lower limit concentration and explosive pressure decreased by the increased ratio of the talc dust. And the DSC results show that heat flux and temperature decreased by the increased ratio of the talc dust. Also increased in raising temperature causes initial smoldering temperature to move towards low temperature section and the endothermic quantity increased on a large scale. Together the TGA results show that weight loss decreased by the increased ratio of the talc dust. From this research we have assured the successive dust explosion mechanism study will play a key role as a significant safety securing guideline against the dust explosion.

Effects of Raising Seeding by Cold Water, Low Night Temperature, and Using Abandoned Mine on Flower Bud Differentiation, Growth and Yield of Forcing Cultured Strawberry (Fragaria x ananassa Duch.) (냉수경, 야냉 및 폐광육묘가 촉성딸기의 화아분화와 생육 및 수량에 미치는 영향)

  • Kim, Woon-Seop;Yoon, Wha-Mo
    • The Journal of Natural Sciences
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    • v.8 no.1
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    • pp.71-80
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    • 1995
  • This experiment was conducted to investigate the effect of raising seedling methods of cold water, low night temperature, and abandoned mine on forcing culture of strawberry. The results were as follows ;1. $17^{\circ}C$ cold water alone and cold water plus 8-hour short day treatments significantly accelerated the flower bud differentiation of Nyoho cultivar to 11 and 15 days, respectively, comparing to common soil raising seedling.2. The date of flower bud differentiation of Nyoho cultivar as influenced by cold water treatment the 17th, the 13th and the 10th of September, respectively, when the seedlings were treated on the 10th of September and on the 25th and the 10th of August in 1991. In 1992, data showed that the flower bud differentiation dates were the 4th and the 2nd of September and the 29th of August when cold water treatment was done on the 10th of August and on the 25th and the 10th of July.3. The first harvest date when Nyoho cultivar was treated by cold water for 30days from Jul. 25 was Nov. 10, this implying that the harvesting day could advanced to 19 days comparing to that by the common soil raising seedling method. The resulting yield was recorded to 21.94 ton per hectare.4. Regardless of the starting date of the treatment, $13^{\circ}C$ low night temperature plus 8-plus short day treatments for 20 days required 17 days to differentiate the flower bud of Nyoho cultivar. Harvesting day could be advanced to 59 days comparing to that by the common raising seedling method when the seedling was treated on July 25, this resulting in increasing the total yield obtained by April 14 of following year to 8.25 ton per hectare.5. When the seedlings of both Nyoho and Hokowase cultivars were raised under the condition of abandoned mine, flowering and harvest date were earlier by the treatment for 20 days than that for 30 days or 40 days. The highest yiesd obtained was recorded in Nyoho cultivar or 1.88 ton per hectare.

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Effects of Thermal Properties and Water Retention Characteristics of Permeable Concrete Pavement on Surface Temperature (투.보수성 시멘트 콘크리트 포장의 열물성 및 수분보유특성이 표면온도에 미치는 영향)

  • Ryu Nam-Hyang;Yoo Byung-Rim
    • Journal of the Korean Institute of Landscape Architecture
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    • v.34 no.1 s.114
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    • pp.21-36
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    • 2006
  • This study was undertaken to analyze the effects of pavement thermal properties and water retention characteristics on the surface temperature of the gray permeable cement concrete pavement during the summer. Following is a summary of major results. 1) The hourly surface temperature of pavement could be well predicted with a heat transfer model program that incorporated the input data of major meteorological variables including solar radiation, atmospheric temperature, dew point, wind velocity, cloudiness and the evaporation rate of the pavements predicted by the time domain reflectometry (TDR) method. 2) When the albedo was changed to 0.5 from an arbitrary starting condition of 0.3, holding other variables constant, the peak surface temperature of the pavement dropped by 11.5%. When heat capacity was changed to $2.5\;kJm^{-3}K^{-1}\;from\;1.5\;kJm^{-3}K^{-1}$, surface temperature dropped by 8.0%. When daily evaporation was changed to 1 mm from 2 mm, temperature dropped by 5.7%. When heat conductivity was changed to $2.5\;Wm^{-1}K^{-1}\;from\;1.5\;Wm^{-1}K^{-1}$, the peak surface temperature of the pavement fell by 1.2%. The peak pavement surface temperature under the arbitrary basic condition was $24.46^{\circ}C$ (12 a.m.). 3) It accordingly became evident that the pavement surface temperature can be most effectively lowered by using materials with a high albedo, a high heat capacity or a high evaporation at the pavement surface. The glare situation, however, is intensified by raising of the albedo, moreover if reflected light is absorbed into surrounding physical masses, it is changed into heat. It accordingly became evident that raising the heat capacity and the evaporative capacity may be the moot acceptable measures to improve the thermal characteristics of the pavement. 4) The sensitivity of the surface temperature to major meteorological variables was as follows. When the daily average temperature changed to $0^{\circ}C\;from\;15^{\circ}C$, holding all other variables constant, the peak surface temperature of the pavement decreased by 56.1 %. When the global solar radiation changed to $200\;Wm^{-2}\;from\;600\;Wm^{-2}$, the temperature of the pavement decreased by 23.4%. When the wind velocity changed to $8\;ms^{-1}\;from\;4\;ms^{-1}$, the temperature decreased by 1.4%. When the cloudiness level changed to 1.0 from 0.5, the peak surface temperature decreased by 0.7%. The peak pavement surface temperature under the arbitrary basic conditions was $24.46^{\circ}C$ (12 a.m.)

The Implementation of Smart Raising Environment Management System based on Sensor Network and 3G Telecommunication (센서 네트워크와 3G 통신 기반 스마트 생장환경 관리시스템 개발)

  • Jeong, Kyong-Jin;Kim, Won-Jung
    • The Journal of the Korea institute of electronic communication sciences
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    • v.6 no.4
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    • pp.595-601
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    • 2011
  • This study proposed the system to automatically control the optimized raising environment for vegetation, raised in an equipment house, in which u-IT agricultural technology concept was applied. The system consists of environment sensors such as temperature, humidity, etc., biosensors such as EC, PH, etc., and requested automatic control devices, in which they were automatically controlled by the software system. The system is established in client systems, installed in each equipment house and the server system, collecting data from each client system as well. In addition, the system collects each farmer's data through the Internet and 3G network. In this phase, collected raising environment data comes to be analyzed in order to find out the optimized vegetation raising environment, finally, which is visualized and used for consulting each farmer.

The effect of deposition conditions on the adhesion strength of TiN multilayer by D. C. magnetron sputtering (D. C. 마그네트론 스퍼터링에 의한 증착조건이 TiN다층박막의 밀착력에 미치는 영향)

  • 김선규;유정광;이건환;권식철
    • Journal of the Korean institute of surface engineering
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    • v.29 no.4
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    • pp.261-267
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    • 1996
  • The characteristics and adhesion strength of TiN layer deposited by D. C. magnetron sputtering were investigated. Three types of TiN layers were deposited on STS304 stainless steel. Scratch tests were performed to determine the effect of deposition temperature, the thickness of coated TiN layer and the titanium inter-layer on the adhesion strength. TiN multilayer with titanium inter-layer showed the highest critical load in the deposition temperature range of $25^{\circ}C$ to $300^{\circ}C$. Adhesion strength of TiN multilayer with titanium inter-layer was raised from 15N to 20N by raising deposition temperature from $25^{\circ}C$ to $400^{\circ}C$. Adhesion strength was raised from 18N to 38N by increasing the thickness of outer layer of TiN multilayer from 2.1 $\mu\textrm{m}$ to 9.5 $\mu\textrm{m}$.

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Studies on the Ternary Blends of Liquid Crystalline Polymer and Polyesters

  • Kim, Seong-Hun;Kang, Seong-Wook
    • Fibers and Polymers
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    • v.1 no.2
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    • pp.83-91
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    • 2000
  • Thermotropic liquid crystalline polymer made up of poly(p-hydroxybenzoate) (PHB)-poly(ethylene terephthalate)(PET) 8/2 copolyester, poly(ethylene 2,6-naphthalate) (PEN) and PET were mechanically blended to pursue the liquid crystalline phase of ternary blends. Complex viscosities of blends decreased with increasing temperature and PHB content. DSC thermal analysis indicated that glass transition temperature (Tg) and melting temperature (Tm) of blends increased with increasing PHB content. Both tensile strength and initial modulus increased with raising PHB content and take-up speed of monofilaments. In the WAXS diagram, only PEN crystal reflection at 2Θ=$15.5^{\circ}C$ appeared but PET crystal reflection was not shown in all compositions. The degree of transesterification and randomness of blends increased with blending time but sequential length of both PEN and PET segment decreased.

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Syntheses and Photostability of Unsymmetrical Squarylium Dyes for Organic Photoconductors(OPC) (유기광전도재료 (OPC)용 비대칭 Squarylium계 색소의 합성과 광안전성)

  • 김성훈
    • Journal of the Korean Graphic Arts Communication Society
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    • v.12 no.1
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    • pp.133-143
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    • 1994
  • A new photochromic spiroxazine dye having a pyridinium s-triazine moiety has been prepared. It shows a reversible photochemical color change from colorless to reddish-purple in ethanol solution. In ethanol solution the half life time of the open form was 150sec, which was shortened by raising temperature. Silica-immobilized spiroxazine(6). Fine power of silica-immobilized spiroxazine was changed intensely blue from colorless by U.V. light or sunlight.

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