• 제목/요약/키워드: Radical distribution

검색결과 203건 처리시간 0.024초

동축류 확산화염의 OH 라다칼 분포 및 매연 특성 (OH Radical Distribution and Sooting Characteristics in Co-Flow Diffusion Flames)

  • 이원남;송영훈;차민석
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 1997년도 제15회 KOSCO SYMPOSIUM 논문집
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    • pp.1-11
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    • 1997
  • The soot and OH radical distributions have been experimentally studied in ethylene and propane laminar diffusion flames. The integrated soot volume fraction was measured along the centerline of a flame using a laser light extinction method. Planar laser light scattering and PLIF techniques are employed for the soot and OH radical distribution measurements utilizing Nd:YAG laser and OPO, FDO system. The concentration of OH radical is rapidly decreased at the edge of sooting region, which implies the importance of OH radical species on the soot oxidation process. For ethylene flames, the addition of air in fuel moves the OH radical distribution towards the center line of a flame at the soot oxidation region, while the concentration of OH radical remains relatively high at the soot formation region. The interaction between soot particles and OH radicals becomes more active with fuel-air at the soot oxidation region. For propane flames, however, any indication of the increased interaction between soot particles and OH radicals with fuel-air was not noticed.

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난류확산화염의 화염구조와 연소특성에 관한 실험적 연구(2) (An Experimental Study on Flame Structure and Combustion Characteristics of Turbulent Diffusion Flame(II))

  • 최병륜;장인갑;최경민
    • 대한기계학회논문집B
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    • 제20권3호
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    • pp.1050-1060
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    • 1996
  • Recently, attention has been paid to the flame diagnostic by noncontact methods which dose not deform the flame shape. One of them is a method which is using the radical luminous intensity. Generally, this diagnostic method using radical luminous has been investigated its reliability by applying to laminar flame. This study, however, investigated each radical luminous signals through stocastical analysis like auto-correlation, cross-correlation, phase and coherence which were acquired from measuring radical luminous intensity of OH, CH, $O_{2}$, radicals in turbulent diffusion flame. To compare radical luminous intensity in flame with temperature, ion current and concentration , radious distribution of each properties was investigated and considered. In radical luminous intensity, correlation in the reaction zone of flame was higher than in correlation in combusted gas zone. And radious distribution of radical luminous intensity was corresponded with radious distribution of temperature, ion current and concentration. The result of the study confirms that a radical luminous flame diagnosis is possible in the turbulent diffusion flame.

OH PLIF를 이용한 부분 예혼합 화염의 화염구조에 관한 실험적 연구 (An Experimental Study on the Flame Structure of Partially Premixed Flame using OH PLIF)

  • 이승영;이종호;전충환;장영준
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집D
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    • pp.54-59
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    • 2001
  • OH radical concentration have been measured in a methane-air partially premixed flames using PLIF. Excitation lines were selected $Q_{1}(6)$ branch, (1,0) band. The system is consisted of Nd:YAG laser, dye laser and frequency doubler to make pump beam for OH radical. On the direct photographs, flame height increases as fuel flow rate and equivalence ratio increase. And on the PLIF images, OH radical is distributed from premixed flame front to nonpremixed flame front through the flame structure with all equivalence ratio. OH overall concentrations increase with equivalence ratio. At the stoichiometric equivalence ratio, the peak of OH radical concentration exists strongly near the inner cone. As equivalence ratio is changed to richer, OH radical distribution goes thinly and the peak is increased as longitudinal direction. As the flow goes to the downstream, OH radical concentration decreases and broadens, because OH radical reacts with another species after OH formation at the initial oxidization. This phenomenon resembles radial distribution. At the l00cc fuel flowrate, the radial peak of OH radical exists from x/R=l.0 to 1.5.

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Object Tracking with Radical Change of Color Distribution Using EM algorithm

  • 황인택;최광남
    • 한국정보과학회:학술대회논문집
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    • 한국정보과학회 2006년도 한국컴퓨터종합학술대회 논문집 Vol.33 No.1 (B)
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    • pp.388-390
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    • 2006
  • This paper presents an object tracking with radical change of color. Conventional Mean Shift do not provide appropriate result when major color distribution disappear. Our tracking approach is based on Mean Shift as basic tracking method. However we propose tracking algorithm that shows good results for an object of radical variation. The key idea is iterative update previous color information of an object that shows different color by using EM algorithm. As experiment results, we show that our proposed algorithm is an effective approach in tracking for a real object include an object having radical change of color.

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The Distribution of Cytoplasm and Nuclei within the Extra-radical Mycelia in Glomus intraradices, a Species of Arbuscular Mycorrhizal Fungi

  • Lee, Jai-Koo
    • Mycobiology
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    • 제39권2호
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    • pp.79-84
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    • 2011
  • Nuclear distribution within the extra-radical fungal structures and during spore production in the arbuscular mycorrhizae fungus Glomus intraradices was examined using an in vitro monoxenic culture system. A di-compartmental monoxenic culture system was modified using a nitrocellulose membrane and a coverglass slip for detailed observations. Nuclear distribution was observed using the fluorescent DNA binding probes SYBR Green I and DAPI. Both septate and non-septate mycelial regions were observed, but cytoplasmic contents were only found within non-septate mycelia. Nuclear fluorescent staining revealed that the non-septate hyphal region contained nuclei only with cytoplasm, and that nuclear distribution was limited by septa. Swollen hyphal bodies were often associated with septate and empty-looking hyphae. Cytoplasmic contents filled the swollen hyphal body from the non-septate hyphal region following removal of the septa. As a consequence, the swollen body developed into a new spore. These observations provide understanding about the distribution of AM fungal nuclei within extra-radical mycelia and during spore formation. The results suggest a mechanism by which the development of a cytoplasm-containing mycelium is controlled by the formation or removal of septa to efficiently maintain and proliferate essential contents. This mechanism may provide a survival strategy to the fungus.

Analysis of Fourier Transform Jet Emission Spectra of CN $(B^{2}{\Sigma}^+{\rightarrow}X^{2}{\Sigma}^+)$

  • Lee, Sang-Kuk
    • Bulletin of the Korean Chemical Society
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    • 제15권5호
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    • pp.349-353
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    • 1994
  • The CN radical was generated in a jet with an inert buffer gas, helium from high voltage dc discharge of the precursor $CH_3CN$. The Fourier transform emission spectra of the O-O band of the $(B^2{\Sigma}^+{\to}X^2{\Sigma}^+)$ transition of CN have been obtained with a Bruker IFS-120HR spectrometer. The spectra show an anomalous distribution of rotational intensity which cannot be explained by a simple Boltzmann distribution. The analysis of the transition frequencies provides molecular constants with high accuracy for both the ground and the excited electronic states of the CN radical.

로켓 플룸 내부 OH 라디칼 공간분포 계측을 위한 발광 분광 기법에 관한 연구 (Study on optical emission spectroscopic method for measuring OH radical distribution in rocket plume)

  • 한기욱;한재원
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2017년도 제48회 춘계학술대회논문집
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    • pp.1135-1139
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    • 2017
  • 화염 내 화학종의 공간적 분포는 화염의 구조 및 연소 특성을 이해하는데 중요한 지표가 되며, 그 계측을 위해 발광분광법 (Optical emission spectroscopy)은 간단하고 비침투적인 진단 방식으로 인해 널리 활용되고 있다. 본 연구에서는 측정 line-of-sight 방향의 공간 분해 계측 목적으로 개발된 발광분광기를 이용한 로켓 플룸 내 화학종 (OH radical) 분포 계측의 가능성을 제시하였다. 발광분광기의 측정 신호로부터 바닥 상태의 화학종 농도를 예측하기 위해 화염 내 열적 여기와 화학적 여기 기작을 고려하였으며, 열적으로 여기된 종에 대해서 열적 평형 상태를 가정하였다. 또한 발광분광기의 공간 분해 성능 및 공간에 따른 수광 특성을 보정하기 위한 방법론을 제시하였다.

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Prediction of Hydroxyl Substitution Site(s) of Phenol, Monochlorophenols and 4-Chloronitrobenzene by Atomic Charge Distribution Calculations

  • Lee, Byung-Dae;Lee, Min-Joo
    • Bulletin of the Korean Chemical Society
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    • 제30권4호
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    • pp.787-790
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    • 2009
  • The predictions of the radical reaction sites for phenol, 2-, 3- and 4-chlorophenols (CPs) and 4-chloronitrobenzene (CNB) were studied by atomic charge distribution calculations. The atomic charge distributions on each atom of these molecules were obtained using the CHelpG and MK (Merz-Kollman/Singh) methods with the optimized structural parameters determined by DFT calculation at the level of BLYP/6-311++G(d,p). By comparing the experimentally obtained hydroxyl addition site(s) and the calculated atomic charges on carbon atoms of phenol and CPs, we found that hydroxyl substitution by oxidation reaction mainly occurred to the carbon(s) with high atomic charges. With these results, we were easily able to predict the position(s) of the ·OH reaction site(s) of phenol, CPs and CNB through atomic charge distribution calculations.

Observation of Rotational Cooling of CN($B^2{\Sigma}^+$) Radical Generated in a Supersonic Expansion

  • Lee, Sang-Kuk;Choi, Iek-Soon;Kim, Un-Sik
    • Bulletin of the Korean Chemical Society
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    • 제15권5호
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    • pp.353-356
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    • 1994
  • The $CN(B^2{\Sigma}^+)$ radical was produced in a jet using an electric dc discharge of the precursor $CH_3CN$ with inert carrier gases. The rotationally resolved Fourier transform emission spectra of the 0-0 band of the $(B^2{\Sigma}^+{\to}X^2{\Sigma}^+)$ transition of CN have exhibited different distribution of the intensity for the carrier gases He and Ar, respectively. From the analysis of intensity distribution in the spectra, the mechanism for rotational cooling process of CN radical in a supersonic expansion has been suggested.

한국산 감자의 기관별, 품종별, 중량별, 분포별 및 조리 방법에 따른 총 페놀 함량과 DPPH 라디칼 소거능에 관한 연구 (The Total Phenolic Contents and DPPH Radical Scavenging Activities of Korean Potatoes according to Physical Characteristics and Cooking Methods)

  • 임효원;서봉순
    • 동아시아식생활학회지
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    • 제19권3호
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    • pp.375-383
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    • 2009
  • This study was conducted to measure the total polyphenol contents and DPPH radical scavenging activities of different potato plants parts, varieties, and grades, and by distribution and different cooking conditions. The results were as follows. For the plant parts, total phenolic content and DPPH radical scavenging activity were highest in the flowers followed by leaves and stems, respectively. Among 5 potato varieties, 'Jasim' had the highest DPPH radical scavenging activity and the activity of its pulp was lower than that of its cortex(peel). Regardless of potato grade, the cortexes(peel) of samples had two-fold higher DPPH radical scavenging activity than pulp, and the Grade SS potato had the highest phenolic content. It was also found that the bud ends and stem ends had comparably larger amounts of phenolic compounds in horizontally cut potatoes. Finally, the descending order for DPPH radical scavenging activity, according to different cooking conditions, was as follows: gas oven range-baking, frying, microwave-heating, sauteing, boiling in 1% saline solution, steaming, and boiling in 3% saline solution.

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