• Journal of the Korean Chemical Society
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• v.34 no.5
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• pp.404-412
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• 1990

The time resolved electron spin resonance spectroscopy are used to two measurement methods of chemically induced dynamic electron polarization (CIDEP) and absorption ESR. The spectra of the semiquinone radical anion were successively detected in the laser flash photolysis of anthraquinone in the mixtures of 2-propanol and triethylamine. The semiquinone radical anion was fairly stable and its cw ESR could be observed. The rate constant (T1$^{-1}$) of the spin-depolarization of polarized semiquinone radical anion was 2.6 ${\times}\;1-^5$ sec$^{-1}$ and the decay of the radical anion was the first order with the rate constant (K$_1}$) of 300.0 sec$^{-1}$. The intensity of CIDEP spectra increased with the increasing the microwave power, but the Torrey wiggles appeared following with decay curves.

• Journal of Ginseng Research
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• v.13 no.1
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• pp.92-97
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• 1989

This study investigated the effects of high light intensity (100 KLw) and high temperature (45 ℃, dark) on enzyme (glucose-6-phosphate dehydrogenase, acid phosphatase, catalase, peroxidase, and proteinase) activities and characteristics of Panax ginseng C.A. Meyer leaves. Enzyme activity and protein content decreased rapidly under treatment with high light intensity In P ginseng the thermal stabilities of catalase and peroxidase were high (above 70%), and the coagulation rates of soluble proteins were low (below 17%). Therefore, the decrease in enzyme activity and protein content was not caused by increase in leaf temperature due to the high light intensity, but by increase in proteolytic activities. The photochemical formation rate of superoxide radical (O-2) was higher in the P ginseng leaf extracts than in Solanum nigmm, and was accelerated by addition of crude saponin to the buffer extracts.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.31 no.6 s.261
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• pp.539-546
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• 2007

An experimental study was performed to investigate the characteristics of chemiluminescence in a radiant burner, varying the excess air ratio from 0.91 to 1.67 at firing rate 80.5 to 134.2 kW/m2 on $OH^*,\;CH^*,\;{C_2}^*$ in LNG-Air premixed flames. The signals from electronically excited states of $OH^*,\;CH^*,\;{C_2}^*$ were detected using a Intensified Couple Charged Detector (ICCD) camera. The measurements of exhausted emission were made to investigate the correlation between chemiluminescence and emissions. The chemiluminescence intensity was increased with increase of firing rate like characteristics of $NO_x$ emission. $NO_x$ also increased with increase of firing rate and excess air ratio. It is found that offset of firing rate is more dominant excess air ratio $NO_x$ emission. The maximum chemiluminescence intensity occurs near the stoichiometric excess air ratio or lean conditions in case of high firing rate and the maximum intensity occurs rather than rich conditions in case of relatively low firing rate. Amount of $NO_x$ emission is maximum at near stoichiometric excess air ratio, which is chemiluminescence intensity is maximum.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.1979-1983
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• 2008

The effects of carbon dioxide addition to oxygen have been investigated with swirl-stabilized premixed methane flame in a laboratory-scale pre-mixed combustor. The methane fuel and oxydant mixture gas ($CO_2$ and $O_2$) were mixed in a pre-mixer and introduced to the combustor through different degrees of swirl vanes. The flame characteristics were examined for different amount of carbon dioxide addition to the methane fuel and different swirl strengths. The effects of carbon dioxide addition and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using chemiluminescence techniques to provide information about flow field. The results show that the flame area increases at upstream of reaction zone because of increase in recirculation flow for increase in swirl intensity. The flame area is also increased at the downstream zone by recirculation flow because of increase in swirl intensity which results in higher centrifugal force. The OH and CH radical intensity of reaction zone decrease with carbon dioxide addition because the carbon dioxide plays a role of dilution gas in the reaction zone.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.20 no.2
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• pp.659-669
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• 1996

To clarify the effects of equivalence ratio, initial pressure and temperature on the flame propagation and radicals characteristics, a series of the experimental study were conducted in a quiescent methane-air premixture using a constant volume chamber. The development of the flame was visualized following the start of ignition using high speed schlieren photo and radical images by intensified CCD camera. Combustion pressure and ion current were recorded simultaneously according to the experimental conditions which were equivalence ratio with 0.7 to 1.2, initial pressure with 0.08 MPa to 0.40 MPa and initial premixture temperature with 3l3.2K to 403.2K. The results showed that the flame speed by ion current and mass fraction burned by combustion pressure characterized the effects of flame propagation very well. And increased combustion duration due to lean combustion condition that was below equivalence ratio, 0.8 caused cycle variation and decreasing the power of engine.

• Journal of ILASS-Korea
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• v.8 no.2
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• pp.38-45
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• 2003

This study was carried on the combustion characteristics of a pure light oil and emulsified fuels at high-pressure injection in a spray combustion installation, The volume fractions of water in an emulsion were varied up to 30% and the injection pressures were 7.5, 100, 200, and $300kg_f/cm^2$. The concentrations of NOx and the average temperatures of flame were measured. And Images of OH radical using ICCD camera and instantaneous schlieren photography of flames were photographed. It was found that the temperature distribution of axial distance in the emulsified fuels was increased in the upstream and decreased in the down stream. The temperature distribution of radial distance was high at the peripheral regions of the spray in the upstream and at the central regions of spray in the downstream, The intensity of OH radical was denser at the water content 10% than at the pure light oil over the injection pressure $200kg_f/cm^2$.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.5
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• pp.602-614
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• 1997

In order to evaluate the effects of equivalence ratio, initial pressure and temperature on the laminar flame propagation process, and combustion radicals characteristics, experimental approaches are carried out in methane-air premixture using a constant volume chamber. Local and average radical intensities were measured to determine the time and spatial correlations between each radicals; C $H^{*}$(431 nm), $C_{2}$$^{*}$ (517 nm) and O $H^{*}$(309 nm) . The results are showed that two kinds of equation were proposed for the cases of continuous flame and intermittent flame type to evaluate actual equivalence ratio using relative intensities with each radicals. Both equations were agreed with actual equivalence ratio within 10% errors range. And schlieren photo and CCD image were compared with flame sizes at equivalence ratio 1.0.o 1.0.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.3
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• pp.281-288
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• 2004

Combustion using oxygen enriched air is an energy saving technology that can increase thermal efficiency by improving the burning rate and by increasing the flame temperature. Flame figures, OH radical intensities, temperature distributions and emissions concentration were examined according to oxygen enriched concentration(OEC) in a turbulent diffusion flat flame. As long as the oxygen enriched concentration was increased, the length and volume of the flat flame was decreased while OH radical intensity was raised and the flame temperature was increased. However, RMS of the fluctuating temperature was decreased, and more homogeneous temperature field was formed. Thermal NO also was increased with increase of oxygen enriched concentration, but CO was decreased due to the increase of chemical reaction rate.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.46 no.5
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• pp.411-415
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• 2001

Fifty-four Korean native and 28 foreign rice varieties harvested in 1998 and 1999 were examined for antioxidative activity that is measured to a chemiluminescence and superoxide radical intensity, by the flow injection chemiluminescence (FI-CL) system and an electron spin resonance (ESR) spectrophotometer, respectively. In the chemiluminescence measurement by FI-CL, radical scavenger activity did not differ significantly among rice varieties between origin types of rice varieties, and between storage periods. GinSun and Hongchoengdo, colored rice exhibited high electron scavenging effect by ESR. Therefore, these results indicate that the pigments of rice varieties may play important antioxidative roles and that it may be possible to breed rice varieties with higher antioxidative potentials.

• Journal of Ginseng Research
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• v.15 no.2
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• pp.139-143
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• 1991

This study investigated the relations between the photosynthetic rate and the activities of antioxidatile enzymes, glutathione reductase, ascorbate free radical reductase, ascorbate peroxidase, glutathione peroxidase, and ascorbate oxidase, in the leaves of Panax ginseng. Under the normal cultivation condition, Panax in showed lower g1utathione reductase and ascorbate free radical reductase activities the Glycine max. But P ginseng showed higher 91utathione Peroxidase, ascorbate Peroxidase, and ascorbate oxidase activities than C. Panax. Therefore, P. ginseng showed weak activities of reductases for the reduction of the oxidized antioxidants. Under the light intensity of 25 KLux, the reductases showed a decrease of over 75% after 24 hours. But the peroyoxidases decreased about 40%. These results showed that the decrease of reductases acitivities was consistent with the decrease of photosynthetic rate. Therefore, we consider that the regulation of antioxidative enzymes or the application of exogenous antioxidants will be effective means for the protection of photodamage in p. ginseng.