• International Journal of Highway Engineering
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• v.9 no.4
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• pp.45-54
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• 2007

This study was carried out for developing artificial short-term aging(SA) and long-term aging(LA) methods of asphalt mixtures in which the aging level is properly matched with those of RTFO and PAV aged binders, respectively. The specimens were made of the short-term aged loose asphalt mixture which was kept in a convection oven at $154^{\circ}C$ for 2 hours and were aged at $110^{\circ}C$ for 24, 48, 72 and 96 hours for SA. Large molecular size(LMS) were measured using GPC after SA and LA to evaluate aging extents of each mixture with aging time. It is shown that the LMS was increased with aging time increment and that from the LMS(%) change ratio, it was possible to suggest an appropriate artificial aging time which is corresponding level of aging with RTFO and PAV. It was found that SA was somewhat strong and LA for 48 hours at $110^{\circ}C$ would be appropriate if sort-term aging is properly controlled.

• International Journal of Highway Engineering
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• v.6 no.2 s.20
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• pp.15-24
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• 2004

Oxidation causes increment of the quantity of large molecular size or LMS in asphalt and is a major reason for hardening of asphalt binder. An extended service life of pavement on a road is expected by reducing oxidation of binder. Oxidation of binder occurs during hot mixing with aggregates before placement on road and then during in-service after the asphalt pavement is constructed. Quantitative increase of LMS as result of aging after RTFO and PAV was analyzed based on the data from high-pressure gel-permeation chromatography (HP-GPC). Polymer modified asphalt (PMA) after RTFO procedure showed 20-30% increment in LMS and then after PAV procedure more than twice, although the percentage of increment was different according to asphalt brand and grade. The PMAs containing LDPE or SBS, which showed a great mechanical property improvement in previous studies, were selected for characterizing PMA aging In this study. Considerably reduced increment of LMS was observed from the PMA containing LDPE after RTFO and PAV procedures. The GPC result showing the binder with less LMS increment means that the asphalt while being mixed with LDPE was aged less during the aging treatment. The dispersed particle of LDPE in asphalt cement seems to disturb oxidative aging reaction and evaporation.

• International Journal of Highway Engineering
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• v.13 no.2
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• pp.1-8
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• 2011

The objective of this paper is to evaluate the performance of low $CO_2$ asphalt binder properties using LEADCAP$^{(R)}$(Low Energy and Carbon Asphalt Pavement) additive as function of various aging methods such as RTFO(Rolling thin film oven), Ultraviolet(UV) lay. In order to simulate the short-term aging of asphalt binder that occurs during the hot-mixing asphalt process, the Rolling Thin Film Oven(RTFO) was used. Asphalt binder using LEADCAP$^{(R)}$ is prepared by addition of a photoinitiator activated by ultraviolet lay. The mechanical and rheological properties of the asphalt binder were estimated using UTM(Universal Testing Machine) and DSR(Dynamic Shear Rheometer). The test results showed that the asphalt binder using LEADCAP$^{(R)}$ additive was improved the rutting resistance at testing temperature ($70^{\circ}C$) and increased tensile strength at low temperature. Also, Thermal analysis shows that the Melting Point(Tm) of asphalt binder using LEADCAP$^{(R)}$ additive was constant although the asphalt binder was aged by Ultraviolet.

• New & Renewable Energy
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• v.7 no.4
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• pp.18-29
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• 2011

Biofuls are considered as an option to reduce greenhouse gases emission, increase energy supply diversity and security of supply, as well as an opportunity for job creation and rural development. First of all, biofuls technologies have been promoted as a means for reducing the carbon intensity of the transport sector. Hence, in the last decade biofuels production has been driven by governmental policies. The key instruments widely adopted to foster production and increase consumption have been mandatory blending targets, tax exemptions and sibsidies. As one of the most powerful instruments, biofuel mandates require fuel producers to produce a pre-defined amount (or share) of biofuels and blend them with petroleum fuel. National biofuels mandates are in place 35 countries and partially in place in 6 countries. In this study, we reviewed status of global biofuels policies to reduce greenhouse gases in the European Union, United States and other countires worldwide. Especially, we discussed representative biofuels mandates policies same as Renewable Fuel Standard (RFS, US), Renewable Transport Fules Obligation (RTFO, UK) in transport sector.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.150.1-150.1
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• 2011

The global rise of greenhouse gas(GHG) emissions and its potentially devastating consequences require a comprehensive regulatory framework for reducing emissions, including those from the transport sector. alternative fuels and technologies have been promoted as a means for reducing the carbon intensity of the transport sector. Renewable fuel policies were historically motivated by energy security concerns, and to promoted agricultural industries. In the last decade, biofuels have also been discussed as low or net-zero carbon soures of energy for transportation. Hence, the development of biofuels has been supported by a range of policy instruments, including volumetric targets or blending mandates, tax incentives or penalties, preferential government purchasing, government funded research, development in world-wide. As one of the most powerfuel instruments, renewable fuel mandates require fuel producers to produce a pre-defined amount(or share) of biofuels and blend them with petroleum fuel. In this study, we reviewed Renewable Fuel Standard(RFS, USA), Renewable Transport Fules Obligation (RTFO, UK) as a renewable fuel mandate policy to reduce GHG. This includes not only mandate system for blending of biofuels in transport fuels, but also sustainability to use biofuels in this system.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.4
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• pp.82-88
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• 2012

The usage of recycling agent is the most effective way of enhancing the performance of recycled asphalt pavement. Generally, many countries accepted these recycling agents retarding the various types of cracks resulted in binder aging. Contrary to such general tendency, recycling agents are used as very small amount in domestic recycling plant. The main reason of this is relatively high price of recycling agent. Even though agent price is high, agent can be a effective and economical way of alternative in asphalt recycling. In this study, penetration and softning point test performed by using RTFO(Rolling Thin Film Oven) aged binder. And, PG(Performance Grade) at high temperature, fatigue and MSCR(Multi Stress Creep and Recovery) tests exercised. The oil type agent is worked well to retrieving target penetration number. In PG test, $G^*/sin{\delta}$ of agents identically showed high value and polymer type agent is good at recovery value.

• International Journal of Highway Engineering
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• v.16 no.5
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• pp.9-18
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• 2014

PURPOSES : The objective of this study is to evaluate the applicability of the pitch, which is produced during SDA petroleum upgrading process, as a pavement paving material. In order for the purpose, the physical and chemical properties of the pitch are analyzed, and then the various plasticizers are applied in the pitch. METHODS : Two types of pitch are selected from oil refinery companies, which are owned the SDA petroleum upgrading process. Also, two types of asphalt binders, PG 64-22 and PG 58-22, are employed to compare with the pitch because these two types of asphalt binders are currently used as paving materials. For the chemical property of the pitch, the composition of SARA (Saturate, Aromatic, Resin, Asphaltene), the elementary composition, and the functional group are analyzed. For the physical property of the pitch, the basic material property tests, such as penetration test, softening point test, flash point test, ductility test, and rotational viscometer test, are performed. Also, the DSR (Dynamic Shear Rheometer) test and the BBR (Bending Beam Rheometer) test are conducted using asphalt binder specimens obtained by both short term aging (Rolling Thin Film Oven, RTFO) and long term aging (Pressure Aging Vessel, PAV) processes. The rheological property of each pitch type is evaluated as a function of temperatures and loading cycles. PG 64-22 asphalt binder is used as a control material. RESULTS AND CONCLUSIONS : The Pitch may not be suitable for the pavement paving material without modifications, but the pitch can be used as alternatives of modified addictive or asphalt. If low molecular component, such as saturate and aromatic components, are added in the pitch based on the development of various plasticizers, it has a strong possibility for the pitch to be used as a alternative. However, in order to verify the performance property of the pitch, further research is needed.

• International Journal of Highway Engineering
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• v.17 no.6
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• pp.55-63
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• 2015

PURPOSES : The objective of this study is to investigate the properties of recycled asphalt binders with five different rejuvenators, in order to evaluate the applicability of the recycled asphalt binders compared with the original asphalt binder. METHODS : In order to simulate recycled asphalt binders, fresh asphalt binders are aged by various Superpave aging procedures, such as the rolling thin-film oven (RTFO) and the pressure aging vessel (PAV). Then, selected rejuvenators are added to the aged asphalt binders in the amount of 5%, 10%, and 15%. The asphalt binder properties are evaluated by the dynamic shear rheometer (DSR), the rotational viscometer (RV), and the bending beam rheometer (BBR). In this study, AP-5 (penetration grade 60-80, PG 64-16) asphalt binder is used. A total of five types of rejuvenators are employed. RESULTS AND CONCLUSIONS : When considering aged asphalt without a new asphalt binder, it seems that the percentage of rejuvenator used in Korea is a bit too low, and that it fails to possess the characteristics of the original binder. From the current practice of evaluating the properties of recycled binder based on penetration ratio only, the amount of rejuvenator required is similar for the long-term-aged binder, but is excessive for the longest-term aged binder, causing deterioration of workability and stiffness of the recycled binder.

• International Journal of Highway Engineering
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• v.1 no.2
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• pp.121-133
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• 1999

This study was based on the evaluation of 9 asphalts that were produced in five major Korean refineries. The study was concentrated to identify the problems of the current asphalt specification (KS M 2201) and to determine the ranges of visco-elastic asphalt behavior. As a conventional asphalt property. asphalt penetration, ring and ball(R&B) softening point, asphalt viscosity, and flash point of asphalt were measured. Also Dynamic Shear Rheometer (DSR) were used to evaluate visco-elastic properties of asphalts in the $-20^{\circ}C$ through $30^{\circ}C$ temperature range. These properties before and after the short-term (RTFO) and long-term (PAV) aging were compared and analyzed to achieve the research objectives. The conclusion from this study can be summarized by the followings. The low temperature rheological behavior of all the straight asphalt from five major Korean refineries is similar regardless of asphalt grade. In the mean while, the rheological behavior at high and intermediate temperature of Korean straight asphalt varies depending on asphalt grade.