• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.8 no.1
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• pp.151-165
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• 1996

Relation between condensate retention and heat transfer performance is studied for condensation of CFC-11 on horizontal integral-fin tubes. Eight tubes with trapezoidally shaped integral fin density from 738fpm to 1654fpm and 10, 30 grooves are tested. The liquid retention angles are measured by the height gauge, and each tube is tested under static(non-condensing) condition (CFC-11, water) and under dynamic(condensing) condition (CFC-11). The analytical model predicts the amount of liquid retention on a horizontal integral-fin tubes within＋10 percent over most of the data. Average retention angle increases as both surface tension-to-density ratio($\sigma/\rho$) and fin density(fpm) increase, The tube having a fin density of 1299~1654fpm has the best heat transfer performance. The amount of surface flooding must keep below of 40 percent for best heat transfer performance at condensation. The tube having low number of fin density must be used for fluids having high values of $\sigma/\rho$(water, (TEX)$NH_3$, ect.) and the tube having high number of fin density must be used for the fluid having low values of $\sigma/\rho$(R-11, R-22, etc.)

• Bulletin of the Korean Chemical Society
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• v.32 no.10
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• pp.3587-3591
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• 2011

The reactions of O,O-diethyl Z-S-aryl phosphorothioates with X-benzylamines are kinetically investigated in dimethyl sulfoxide at $85.0^{\circ}C$. The Hammett (log $k_2$ vs ${\sigma}x$) and Br$\ddot{o}$nsted [log $k_2$ vs $pK_a$(X)] plots are biphasic concave downwards for substituent X variations in the nucleophiles with a break point at X = H. The signs of the cross-interaction constants (${\rho}xz$) are positive for both the strongly and weakly basic nucleophiles. Considerably great magnitude of ${\rho}xz$ (= 6.56) value is observed with the weakly basic nucleophiles, while ${\rho}xz$ = 0.91 with the strongly basic nucleophiles. Proposed reaction mechanism is a stepwise process with a rate-limiting leaving group expulsion from the intermediate involving a backside nucleophilic attack with the strongly basic nucleophiles and a frontside attack with the weakly basic nucleophiles. The kinetic results are compared with those of the benzylaminolysis of O,O-diphenyl Z-S-aryl phosphorothioates.

• Journal of the Korean Institute of Telematics and Electronics B
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• v.32B no.11
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• pp.1473-1480
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• 1995

When the LMS algorithm is employed in the transversal filter structure, the computational complexity can be kept reasonably low. However, if the impulse response to be estimated is very long or signals involved are highly correlated like a speech the convergence speed becomes slow. The lattice filter is an excellent alternative to improve convergence speed since the lattice structure inherently has the orthogonal property among the backward prediction errors, but at the expense of the excessive computational load. If the input signal to be used can be sufficiently well modeled as a .RHO.-th order autoregressive(AR) process, the reflection coefficients after the .RHO.- th stage will be close to zero. Then, instead of employing the full lattice structure, the joint lattice filter structure can be implemented in conjunction with the transversal filter structure after the .RHO.-th stage. We propose, in this paper, this new lattice/transversal joint structure, and we will call it the reduced lattice filter. Using the reduced lattice filter, we are now able to achieve the performance as good as that of the lattice filter, while maintaining the complexity as low as that of the transversal filter. The proposed filter is particularly useful for an acoustic echo canceller due to the highly correlatedness nature of speeches and the long and frequently changing echo paths.

• Journal of the Korean Chemical Society
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• v.33 no.1
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• pp.120-126
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• 1989

The Kinetics of hydrolysis of styrylphenylsulfone derivatives in 50% methanol-water at 25$^{\circ}$C and ionic strength of 0.10 was investigated by UV spectrophotometry in the pH range of 0.0-14.0. The rate equations, which can be applied over a wide pH range, were obtained. The Hammett rho constants for the hydrolysis are 1.85 at pH 7.0 and 1.54 at pH 13.0, respectively. On the basis of the evidence, it is proposed that the general base-catalysis occurs in the hydrolysis of styrylphenylsulfone derivatives; above pH 11.0, Michael type nucleophilic addition take place, while below pH 9.0, the reaction is initiated by addition of water and from pH 9.0 to pH 11.0 these two reactions occur com-petitively.

• KSBB Journal
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• v.18 no.1
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• pp.74-77
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• 2003

A simple, reproducible, and rapid gas chromatographic method for putrefactive metabolite determination in feces was developed. The method involves the direct injection of fecal supernatants into the gas chromatograph, without pretreatment. The mass spectra of these metabolites were obtained using an HP 5971 mass selective detector operated in electron impact (EI) ionization mode. This method produced sharp peaks and allowed the simultaneous determination of fecal putrefactive metabolites.

• Korean Chemical Engineering Research
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• v.56 no.2
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• pp.252-260
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• 2018

Energy, a critical input, is to be efficiently managed via waste heat recovery and energy reuse for the economic viability of a process industry. In particular, cement manufacture demands a huge quantum of energy, for the necessary reactions. Huge amounts of hot effluent gases are generated. Energy recovery from these waste gases is an area that is of contemporary research interest. Now, about 75% of total heat recovery takes place in the riser of the suspension pre-heater system. This article deals with the hydrodynamic and heat transfer aspects of riser typically used in the cement industry. An experimental apparatus was designed and fabricated with provision for the measurement of gas pressure and solid temperatures at different heights of the riser. The system studied was air - chalcopyrite taken in different particle sizes. Acceleration length ($L_A$) determined at different parametric levels was fitted to an empirical correlation: $L_A/d_t=4.91902(d_p/d_t)^{0.10058}(w_s/w_g)^{-0.11691}(u_g{\mu}_g/d_t^2g{\rho}_g)^{0.28574}({\rho}_p/{\rho}_g)^{0.42484}$. An empirical model was developed for Nusselt number as a function of Reynolds and Prandtl numbers using regression analysis: $Nu=0.40969(Re_p)^{0.99953}(Pr)^{0.03569}$.

• Biomolecules & Therapeutics
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• v.22 no.6
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• pp.540-546
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• 2014

The high mortality rates associated with cancer reflect the metastatic spread of tumor cells from the site of their origin. Metastasis, in fact, is the cause of 90% of cancer deaths. Therefore, considerable effort is being made to inhibit metastasis. In the present study, we screened ketotifen for anti-migratory and anti-invasive activities against MDA-MB-231 breast cancer and HT-1080 fibrosarcoma cancer cells. Cancer cell migration and invasion were measured using multi-well chambers. Additionally, western blots were used to examine the effects of ketotifen on the expressions of CDC42, Rho, Rac, and matrix metalloproteinase 9 (MMP-9). The results showed that ketotifen dose-dependently suppressed the migration and invasion of MDA-MB-231 and HT-1080 cells. Ketotifen also suppressed the expressions of CDC42, Rac, and Rho, which, significantly, are involved in MDA-MB-231 and HT-1080 cancer cell migration. Moreover, ketotifen suppressed the expression and activity of MMP-9, which is involved in degradation of the extracellular matrix leading to invasion. The overall data suggested that ketotifen suppresses the migration and invasion of MDA-MB-231 and HT-1080 cancer cells via inhibition of CDC42, Rac, Rho, and MMP-9 expression.

• Journal of Distribution Science
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• v.20 no.10
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• pp.11-17
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• 2022

Purpose: This research aims to find the link between public service Distribution and individual job performance in the provincial municipality. Research design, data, and methodology: This is a quantitative approach study with a non-experimental and correlational design. The sample consisted of 140 employees appointed and hired by the provincial municipality of Huaraz. For data collection, Two questionnaires with an ordinal Likert-type scale and the Rho Spearman correlation coefficient were used to assess the link between the research variables., For Analysis: two questionnaires with an ordinal Likert-type scale and the Rho Spearman correlation coefficient were used to determine the connection between the research variables. Results: It was determined that both variables have a high degree of correlation (0.725), indicating a direct and significant relationship between the Distribution of public service and skill performance in the provincial municipality (0.614). Conclusion: Finally, this allows us to conclude that the institutional context is essential; that is, there is a significant correlation between the PSM and contextual performance in the provincial municipality of Huaraz, which has a Rho Spearman value of 0.723.

• Korean Journal of Medicinal Crop Science
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• v.2 no.3
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• pp.234-240
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• 1994

The essential oils of Thymus quinquecostatus Celakov. and T. magnus Nakai, respectively, were isolated by using a modified Likens-Nickerson type steam distillation and extraction apparatus and analyzed by gas chromatography and gas chromatography-mass spectrometry. The oil content of T. quinquecostatus was 1.94%, and that of T. magnus was 1.91% in mixed leaves and stems and 0.68% in flowers. Among 38 components identified in either mixed leaves and stems or flowers the major components in essential oil isolated from T. quinquecostatus were thymol(39.8%), ${\gamma}-terpinene(10.0%)$ ${\rho}cymene(9.2%)$ and camphor(5.9%) while those from mixed leaves and stems of T. magnus were thymoI(54.7%), ${\gamma}-terpinene(15.8%)$, ${\rho}cymene(6.7%)$ and carvacroI(3.2%). The contents of ${\alpha}-pinene$, camphene, camphor, bornyl acetate and ${\alpha}-terpinene+borneol$ were higher in T. quinquecostatus than in T. maglnus but ${\gamma}-terpinene$ and thymol were higher in T. magnus than in T. quinquecostatus. Comparing leaves and stems with flowers in T. magnus, peak area percentage(%) of ${\gamma}-terpinene$, ${\alpha}-terpinene$ were higher in mixed leaves and stems than in flowers, whereas ${\rho}cymene$ was predominantly higher in flowers than in leaves and stems.

• Korean Journal of Weed Science
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• v.30 no.4
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• pp.396-404
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• 2010

Phenolic compounds, which are products of secondary metabolism, have been demonstrated to be widespread growth substances in plants. The objectives of this study were to identify the phenolic compounds in common ragweed (Ambrosia artemisiifolia var. elatior) by HPLC and to evaluate their effects on germination and seedling growth of three weed species. Under controlled conditions in Petri dishes at $25^{\circ}C$, $10^{-3}$ and $10^{-4}$ M solutions of phenolic compounds were evaluated in seed germination tests. Four phenolic compounds (caffeic acid, O-coumaric acid, ${\rho}$-coumaric acid and ferulic acid) in common ragweed plant were identified and their concentration was increased from the stage before flowering through full flowering stage. Treatment of O- and ${\rho}$-coumaric acids delayed the seed germination of Digitalia ciliaris, while the treatment of caffeic acid delayed the seed germination of Echinochloa crus-galli. In time to 50% germination ($T_{50}$), phenolic compounds at $10^{-4}$ M promoted in Cyperus microiria and E. crus-galli but the level of $10^{-3}$ M delayed the $T_{50}$ of those weeds. The O-coumaric acid inhibited seed germination and seedling growth of the tested weeds and especially it perfectly inhibited the root growth of E. crus-galli.