• Title/Summary/Keyword: R-TOC

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Performance of the Nanjido Composting Facility (난지도 퇴비화시범시설에서의 퇴비화과정 검토)

  • Namkoong, Wan;Kim, Joung-Dae;Park, Joon-Seok
    • Journal of the Korea Organic Resources Recycling Association
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    • v.5 no.2
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    • pp.7-16
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    • 1997
  • The food waste composting facility of 10 ton/d capacity at Nanjido has been operated successfully since July, 1996. This study was performed to investigate the characteristics of food waste quality, and variation of physicochemical characteristics of feed materials during composting. Food waste with 79% moisture content was used as a substrate. Wood chip was used as a bulking agent. Monitoring results based on VS, TOC, C/N ratio and gas composition indicated that the facility was operated normally under aerobic conditions. Conductivity values during food waste composting were increased. A highly positive correlation (r=1.00) existed between VS and TOC.

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The Distribution Characteristics of Organic Matters in the Contaminated Tributaries of Han River Region (한강권역 우심지류 하천의 유기물 분포 특성)

  • Kim, Ho-Sub;Park, Yun-Hee;Kim, Yong-Sam;Kim, Sang-Yong
    • Journal of Korean Society on Water Environment
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    • v.34 no.5
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    • pp.494-502
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    • 2018
  • The purpose of this study was to understand distribution characteristics of organic matters through concentration of $BOD_5$, $COD_{Mn}$ and TOC in 31 streams in Han River region, and to establish the relationship among organic matter concentration, and discharge load and flow rate. Concentration of $BOD_5$ and TOC in 22 streams were above IV grade except 9, and the average 80.9 % of total organic matter (by TOC) accounted for dissolved organic type. Correlation among organic matter parameters were higher ($r^2$ > 0.78) and the relationship between TOC and $COD_{Mn}$ concentration was higher than $BOD_5$. Ratio of biodegradable organic matter/total organic matter in the 31 streams was estimated at 41.4 % with $BOD_5$ oxidation rate, and 78.0 % with $BOD_5/COD_{Mn}$ concentration ratio. Ratio of $NBOD/BOD_5$ concentration in four sites with $BOD_5/COD_{Mn}$ concentration ratio exceeding 1 ranged from 54.5 % ~ 79.3 %. Among 979 flow rate data measured at 31 streams, 87 % of measured data was below 0.1 cms and increased water pollution under low flow conditions. Correlation between $BOD_5$ concentration and $BOD_5$ discharge load in the watershed was low, and it was revealed that several streams have more $BOD_5$ delivery load than $BOD_5$ discharge load. Results suggest that many biodegradable forms of organic matter are being introduced into the stream from pollutant sources in the watershed.

TiO2 Photocatalytic Reaction on Glass Fiber for Total Organic Carbon Analysis (총유기탄소 분석을 위한 유리섬유를 이용한 이산화티타늄 광촉매 반응)

  • Park, Buem Keun;Lee, Young-Jin;Shin, Jeong Hee;Paik, Jong-Hoo
    • Journal of Sensor Science and Technology
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    • v.31 no.2
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    • pp.102-106
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    • 2022
  • Currently, the demand for real-time monitoring of water quality has increased dramatically. Total organic carbon (TOC) analysis is a suitable method for real-time analysis compared with conventional biochemical oxygen demand (BOD) and chemical oxygen demand (COD) methods in terms of analysis time. However, this method is expensive because of the complicated internal processes involved. The photocatalytic titanium dioxide (TiO2)-based TOC method is simpler as it omits more than three preprocessing steps. This is because it reacts only with organic carbon (OC) without extra processes. We optimized the rate between the TiO2 photocatalyst and binder solution and the TiO2 concentration. The efficiency was investigated under 365 nm UV exposure onto a TiO2 coated substrate. The optimized conditions were sufficient to apply a real-time monitoring system for water quality with a short reaction time (within 10 min). We expect that it can be applied in a wide range of water quality monitoring industries.

A Study on Grade Classification for Improvement of Water Quality and Water Quality Characteristics in the Han River Watershed Tributaries (한강 수계 지류 하천의 수질 특성 및 수질 개선을 위한 등급화 방안 연구)

  • Cho, Yong-Chul;Park, Minji;Shin, Kyungyong;Choi, Hyeon-Mi;Kim, Sanghun;Yu, Soonju
    • Journal of Environmental Impact Assessment
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    • v.28 no.3
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    • pp.215-230
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    • 2019
  • The objective of this research is to evaluate the water quality characteristics using the statistical analysis of major tributaries in the Han River and to provide water quality improvement plan by selecting tributaries that should be preferentially managed by river grade classification method. The major 15 tributaries in Han River watershed were monitored for discharge and water quality during January-December 2017. As a result of the correlation analysis, the river discharge has been not correlation with other water quality constituents (p>0.05) but COD and TOC were significantly correlated (r=0.957, p<0.01). The main cause of water quality fluctuation was organic pollutants and nutrients in the principal component analysis (PCA) method. The BOD, COD, TOC, TN, and TP were found to be significantly different (p<0.05) by seasonal in result of one-way ANOVA analysis. Result of river grade classification by quantitative indicators the tributaries requiring improvement of water quality were Gulpocheon, Anyangcheon, Wangsukcheon, and Tancheon which affected by wastewater treatment plant.In this research, we determined tributaries that need to improve the water quality of Han River watershed and it can be used as an important data for efficient water quality management.

The Study of Statistical Optimization of 1,4-dioxane Treatment Using E-beam Process (전자빔 공정을 이용한 1,4-Dioxane 처리의 통계적 최적화 연구)

  • Hwang, Haeyoung;Chang, Soonwoong
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.4
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    • pp.25-31
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    • 2011
  • In this study, the experimental design methodology was applied to optimize 1,4-dioxane treatment in E-beam process. Main factor was mathematically described as a function of parameters 1,4-dioxane removal efficiencies(%), TOC removal efficiencies(%) modeled by the use of the central composite design(CCD) method among the response surface methodology(RSM). Concentration of 1,4-dioxane is designated as "$x_1$" and Irradiation intensity is designated as "$x_2$". The regression equation in coded unit between the 1,4-dioxane concentration and removal efficiencies(%) was $y=71.00-10.85x_1+20.67x_2+{1.53x_1}^2-{7.92x_2}^2-1.23x_1x_2$. The regression equation in coded unit between the 1,4-dioxane concentration and TOC removal efficiencies(%) was $y=44.48-13.25x_1+9.54x_2+{5.43x_1}^2-{1.35x_2}^2+4.45x_1x_2$. The model predictions agreed well with the experimentally observed results $R^2$(Adj) over 90%. Toxicity test using algae Pseudokirchneriella Subcapitata showed that the inhibition was reduced according to increasing an E-beam irradiation.

Water Quality Similarity Evaluation in Geum River Using Water Quality Monitoring Network Data (물환경측정망 자료를 활용한 금강수계 수질 유사도 평가)

  • Kim, Jeehyun;Chae, Minhee;Yoon, Johee;Seok, Kwangseol
    • Journal of Environmental Impact Assessment
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    • v.30 no.2
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    • pp.75-88
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    • 2021
  • Six locations in the automated monitoring network at the Geum River Basin were selected forthis study. The water quality characteristics at two of the locations in the water quality monitoring network that were identical, or nearby, were examined, and their correlations were evaluated through statistical analysis. The results of the water quality analysis were converted to the water quality index and expressed in grades for comparison. For the data necessary for the study, public data from four years, from 2016-2019 were used and the evaluation parameters were water temperature, pH, EC, DO, TOC, TN, and TP. Results of the analysis showed that the water quality concentrations measured in the automated monitoring network and the water quality monitoring network differed in some measured values, but they tended to register variation in a specified ratio in most of the locations in the network. The analysis of the correlations of the parameters between the two monitoring networks found that water temperature, EC, and DO showed high correlations between the two monitoring networks. The TOC, TN, and TP showed high correlations, with a 0.7 or higher (correlation coefficient r), with the exception of some of the monitoring networks, although their correlations were lower than those of the basic parameters. The water quality index analysis showed that the water quality index values of the automated monitoring network and the water quality monitoring network were similar. The water quality index decreased and the pollution degree increased in the downstream direction, in both networks.

A Study on Artificial Radionuclides(134Cs, 137Cs and 239+240Pu) Distribution in the Sediment from Lake Euiam (의암호 퇴적물 내 인공방사성동위원소 (134Cs, 137Cs, 239+240Pu) 분포특성 연구)

  • Kim, Seung Hwan;Lee, Sang-Han;Oh, Jung Suk;Choi, Jong Ki;Kang, Tae Gu
    • Journal of Radiation Protection and Research
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    • v.40 no.4
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    • pp.223-230
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    • 2015
  • The objective of this study is to identify the radionuclide distribution in public water by carrying out the analysis of artificial radionuclides($^{134}Cs$, $^{137}Cs$, $^{239+240}Pu$), natural radionuclide($^{210}Pb$) and TOC in the lake Euiam sediment in Chuncheon, South Korea. The $^{134}Cs$ concentration in all lake sediments showed below MDA values, and the $^{137}Cs$ concentration in lake sediment were ranged from MDA to $8.79Bq{\cdot}kg^{-1}-dry$. The $^{137}Cs$ concentrations in surface sediment were reported to be 2.4 to $4.2Bq{\cdot}kg^{-1}-dry$. The lowest concentration of $^{137}Cs$ was reported at St. 4 and the highest concentration was reported at St. 3, respectively. The $^{239+240}Pu$ concentration in lake sediment were ranged from 0.049 to $0.47Bq{\cdot}kg^{-1}-dry$. The lowest concentration was reported at St. 2 and the highest concentration was reported at St. 3. The correlation(r) between the $^{239+240}Pu$ concentration and $^{137}Cs$ concentration in lake sediment presented higher values (0.54 to 0.97) and this suggests the behavior and origin of $^{137}Cs$ is identical to the $^{239+240}Pu$ in the sediment. The $^{134}Cs$ concentration below MDA value and the $^{239+240}Pu/^{137}Cs$ ratio(mean value of 0.041) indicated that the artificial radionuclides in the sediment were originated from global fallout by the atmospheric testing of nuclear weapons conducted by former USSR and U.S.A, but not from the Fukushima Daiichi NPP accident. The sedimentation rate derived from $^{210}Pb$ age-dating method at St. 2 is calculated to be $0.31{\pm}0.06cm{\cdot}y^{-1}$. This value is similar to the value ($0.41{\pm}0.05cm{\cdot}y^{-1}$) estimated from the $^{137}Cs$ maximum peak produced from early 1960's. The content of TOC in lake Euiam sediments varied from 0.20 to 13.01%. While the highest correlation between TOC and $^{137}Cs$ concentration in the sediment were found at St. 1, the others presented the low correlation.

Runoff Characteristics of Refractory Organic Matters from Kyongan River Watershed during Rainfall Event and Dry Season (경안천 유역의 강우 시, 비 강우 시 난분해성 유기물질 유출 특성)

  • Kim, Taewon;Gil, Kyungik
    • Journal of Korean Society on Water Environment
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    • v.27 no.4
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    • pp.397-404
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    • 2011
  • This research investigates the runoff characteristics of refractory organic matters from Kyongan river watershed. Samples were taken 27 times during dry season, 4 times during rain events and analyzed into flow rate, Dissolved Organic Carbon (DOC), Particulate Organic Carbon (POC), Refractory Dissolved Organic Carbon (R-DOC), Refractory Particulate Organic Carbon (R-POC). R-DOC during dry season was the lowest in winter and showed a rising tendency in spring and R-POC changes less than R-DOC. The mass loading of Refractory Total Organic Carbon (R-TOC) in summer takes approximately 80% of 1 year mass loading. During rainy season, EMC of R-DOC was similar to R-DOC in dry season. But maximum EMC of R-POC was 12 times higher than that of R-POC in dry season. Results of the survey show that enhanced management of R-DOC in dry season and R-POC in rainy season is needed.

The Study on Increase the Decomposition of Organics and Organic Removal Rates by using Sulfate in Sanitary Landfills (황산염을 이용한 매립지 유기물분해 촉진과 분해속도에 관한 연구)

  • Kim, Jeong Gwon;Yun, Tae Gyeong;Kim, Ga Ya
    • Journal of Environmental Science International
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    • v.13 no.1
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    • pp.69-77
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    • 2004
  • In this study, sulfate reduction reaction was used to increase the decomposition of organics, which is the most critical factor for the stabilization of a landfill site. Composite of sewage sludge, papers, and incineration ashes was used in the column. The experimental results indicated that out of 10 reactors, the reactors 3, 4, 8. and 9 showed higher organics (i.e., TOC) removal rate than that in the absence of sulfate. The organics removal rates (K) in R3 and R9 were 8.65e$\^$-4/d and 3.82e$\^$-4//d, respectively. The times to reach 10% of initial concentrations in R3 and R9 was 7.3 and 16.5 years, respectively, showing faster organics decomposition rates in these reactors.

Inactivation of Microorganisms in Sewage Using a Pilot Plasma Reactor (Pilot 플라즈마 반응기를 이용한 하수 중 미생물의 불활성화)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Health Sciences
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    • v.39 no.3
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    • pp.289-299
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    • 2013
  • Objectives: For the field application of the dielectric barrier discharge plasma reactor, scale-up of the plasma reactor is needed. This study investigated the possibility of inactivation of microorganisms in sewage using pilot multi-plasma reactor. We also considered the possibility of degradation of total organic carbon (TOC) and nonbiodegradable matter ($UV_{254}$) in sewage. Methods: The pilot plasma reactor consists of plasma reactor with three plasma modules (discharge electrode and quartz dielectric tube), liquid-gas mixer, high voltage transformers, gas supply equipment and a liquid circulation system. In order to determine the operating conditions of the pilot plasma reactor, we performed experiments on the operation parameters such as gas and liquid flow rate and electric discharge voltage. Results: The experimental results showed that optimum operation conditions for the pilot plasma reactor in batch experiments were 1 L/min air flow rate), 4 L/min liquid circulation rate, and 13 kV electric discharge voltage, respectively. The main operation factor of the pilot plasma process was the high voltage. In continuous operation of the air plasma process, residual microorganisms, $UV_{254}$ absorbance and TOC removal rate at optimal condition of 13 kV were $10^{2.24}$ CFU/mL, 56.5% and 8.6%, respectively, while in oxygen plasma process at 10 kV, residual microorganisms, $UV_{254}$ absorbance and TOC removal rate at optimal conditions were $10^{1.0}$ CFU/mL, 73.3% and 24.4%, respectively. Electric power was increased exponentially with the increase in high voltage ($R^2$ = 0.9964). Electric power = $0.0492{\times}\exp^{(0.6027{\times}lectric\;discharge\;voltage)}$ Conclusions: Inactivation of microorganisms in sewage effluent using the pilot plasma process was done. The performance of oxygen plasma process was superior to air plasma process. The power consumption of oxygen plasma process was less than that of air plasma process. However, it was considered that the final evaluation of air and oxygen plasma must be evaluated by considering low power consumption, high process performance, operating costs and facility expenses of an oxygen generator.