• 자원환경지질
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• 제49권2호
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• pp.89-95
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• 2016

산화 환원 환경에 민감하게 분별되는 몰리브덴(Mo) 안정동위원소는 지구화학적 과정을 유추할 수 있는 지시자로 사용될 수 있다. 최근 분석기기의 발달로 Mo 동위원소를 활용한 지질물질 연구가 많이 보고되고 있지만, 국내에서는 Mo 동위원소에 관한 연구가 없었다. 이번 연구에서는 컬럼관(BioRad PolyPrep(R) column, 10 ml)과 음이온 교환수지(BioRad Resin AG(R) 1-X8, 200-400 mesh)를 이용한 두 번에 걸친 컬럼 작업을 통해 Mo을 분리 및 회수하였다. 이 분리법을 이용하여 고체(BHVO-2, SDO-1, PACS-2) 및 액체(IAPSO) 표준시료의 Mo 동위원소 분석을 다검출기 유도결합 플라즈마 질량분석기(Multi-collector Inductively Coupled Plasma Mass Spectrometer; MC-ICP-MS)로 측정한 결과, 측정된 표준물질의 Mo 동위원소 분석값은 참값과 오차 범위 내에서 잘 일치하였다.

• 한국재료학회지
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• 제22권8호
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• pp.385-389
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• 2012

Significant improvements in the switching voltage distribution are required for the development of unipolar resistive memory devices using $MnO_x$ thin films. The $V_{set}$ of the as-grown $MnO_x$ film ranged from 1 to 6.2 V, whereas the $V_{set}$ of the oxygen-annealed film ranged from 2.3 to 3 V. An excess of oxygen in an $MnO_x$ film leads to an increase in $Mn^{4+}$ content at the $MnO_x$ film surface with a subsequent change in the $Mn^{4+}/Mn^{3+}$ ratio at the surface. This was attributed to the change in $Mn^{4+}/Mn^{3+}$ ratios at the $MnO_x$ surface and to grain growth. Oxygen annealing is a possible solution for improving the switching voltage distribution of $MnO_x$ thin films. In addition, crystalline $MnO_x$ can help stabilize the $V_{set}$ and $V_{reset}$ distribution in memory switching in a Ti/$MnO_x$/Pt structure. The improved uniformity was attributed not only to the change of the crystallinity but also to the redox reaction at the interface between Ti and $MnO_x$.

• 한국농공학회지
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• 제15권1호
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• pp.2853-2877
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• 1973

Models of cross-sections and channels were made in order to measure seepage losses. Cross-sections were made of sand, sandy clay loam and loam, their thicknesses being 30cm and 40cm, respectively. Flow depths kept in the cross-sections were 4cm, 6cm, 8cm and 10cm. Straight and curved channel models were provided so as to measure seepage losses, when constant water depths maintained at the heads of the channels were 7.3cm and 5.7cm, respectively. The results obtained in this experiment are presented as follows: 1) A cumulative seepage loss per unit length at a point in the channel varies in accordance with time and flow depth. The general equation of cumulative seepage loss may be as follows(Ref. to Table V.25): $$q_{cum}=\int_{o}^aq(a)dt+\int_a^bq(b)dt+\int_b^tq(c)dt$$ 2) In case that the variation of water depth through the channel is slight, the total seepage loss may be computed by applying the following general equation: $$\={q}_{cum}{\cdot}x=\int_o^tq_{cum}\frac{{\partial}x}{{\partial}t}dt$$ 3) Because seepage loss varies considerably according to water depth in case that the variation of flow depth through the channel is great, seepage loss should be computed by taking account of the change of flow depth. 4) The relation between time and traveling distance of water flow may be presented as the following general equation(Ref. to Table V.29): $$x=pt^r$$ 5) The ratios of the seepage losses of the straight channel to the curved channel are 1:1.03 for a flow depth of 7.3cm and 1:1.068 for that of 5.7cm. 6) The ratios of the seepage losses occurring through the bottom to those through the inclined plane in the channel cross-section are 1:2.24 for a water depth of 8cm and 1:2.47 for a depth of 10cm in case that soil-layer is 30cm in thickness. Similarly, those ratios are 1:2.62 and 1:2.93 in case of a soil-layer thickness of 40cm(Ref. to Table V.5).

• Asian-Australasian Journal of Animal Sciences
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• 제14권10호
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• pp.1374-1382
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• 2001

Fifteen Inner Mongolian wethers with permanent ruminal and duodenal cannulas were used to study the effects of dietary rumen-undegradable protein (RUP) to rumen-degradable protein (RDP) ratios or protein sources on fiber digestion in the gastrointestinal tract and ruminal fluid characteristics. Fiber digestion and ruminal fermentation were not affected (p>0.05) by dietary RUP to RDP ratios (from 1.54 to 0.72). Soybean meal supplementation improved ruminal digestion. Fish meal supplementation increased (p<0.05) the ruminal degradability of fiber. The different RUP to RDP ratios (from 1.54 to 0.72) did not influence (p>0.05) ruminal fluid pH, but there were differences (p<0.05) in ruminal fluid $NH_3-N$ concentration because of urea replacement. Soybean meal as a dietary protein source decreased (p<0.05) ruminal fluid pH and increased (p<0.05 or p<0.01) $NH_3-N$, acetate, propionate and butyrate concentrations in the rumen. Fish meal as a dietary protein source decreased (p<0.05 or p<0.01) ruminal $NH_3-N$ and acetate concentrations and increased (p<0.05) ruminal propionate concentration. It can be concluded that dietary protein sources have more significant effect on fiber digestion and ruminal fermentation than different dietary RUP to RDP ratios, when the dietary crude protein requirements of growing sheep are satisfied.

• Journal of Yeungnam Medical Science
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• 제11권1호
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• pp.160-166
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• 1994

1990년 1월부터 1993년 12월까지 영남대학교 의과대학 부속병원에서 출생한 적정체중아(appropriate for gestational age infants) 207명을 대상으로 중앙 상완위 및 두위를 측정하여 관찰한 결과 재태 연령의 증가에 따라 중앙 상완위(y=0.3181x-2.2069, r=0.81 p<0.001)와 중앙 상완위 대두위 비(y=0.0049x+0.1128, r=0.62, p<0.001)는 직선적인 증가를 보였으며 이를 기초로 작성된 재태 연령에 대한 표준 곡선은 향후 신생아의 발육 상태를 평가하는 참고치로서 활용될 수 있을 것으로 생각된다.

• 한국응용곤충학회지
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• 제23권1호
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• pp.28-36
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• 1984

무우의 바이러스 이병율과 매개진딧물 비래밀도간의 상관관계를 조사하고자 전주지방에 무(Raphanus sativus L. var. Chungsu gungjung)를 파종하고 1982년 4월부터 11월 사이에 실시하였다. 진딧물 비래밀도는 황색수반으로 채집하고, 바이러스 이병율은 병징을 육안으로 조사하였다. 전주지방의 진딧물 비래밀도는 5월 하순과 10월 중순에 최성기를 나타냈으며 매개진딧물의 비래분포도 같은 경향이었다. 무우의 바이러스병 매개진딧물은 복숭아혹진딧물 (Myzus perticae), 무우테두리 진딧물(Lipaphis erysimi), 목화진딘들(Aphis gossypii), 양배추가루진딧물(Brevicoryne brassicae)이 채집되었고, 전체진딧물 대 매개진딧물의 비율은 $62.82\%(39.260/62.499)$이었다. 매개진딧물중 복숭아혹진딧물이 $82.53\%(32.401/39.260)$로서 우점종으로 나타났다. 춘계의 바이러스 이병율은 급상승하며 높은데 비하여 추계의 바이러스 이병율은 완만하면서 낮았다. 매개진딧물의 밀도상승과 바이러스 이병율간의 상관관계는 춘계는 $r=0.7414^*(\hat{Y}=8.1444+0.0551X)$, 추계는 $r=0.9117^{**}(\hat{Y}=10.2590+0.463X)$로서 고도의 유의성이 인정되었다. 또 매개진딧물의 비래와 바이러스 병징발현간에는 약 15일의 기간이 소요되는 것으로 나타났다. 바이러스병의 이병주 보존구가 이병주 제거구보다 발병율이 높게 나타났다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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• pp.232-233
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• 2007

We manufactured Liquid Crystal Polymer (LCP) and (1-x)CaTiO3-xLaAlO3 (CT-LA) ceramic composites and investigated dielectric properties to use as embedded capacitor in printed circuit boards and replace LTCC substrate. The dielectric properties of these composites are varied with volume fraction of CT-LA and ratios of CT/LA. Dielectric constants are in the range of 3~15. In addition, we could get low TCC and High Q value that could not achieve in other ceramic-polymer composites. Especially, in composite with x=0.01 and 30 vol% CT-LA, the dieletric constant and Q-value are 10 and 200, respectively. And more TCC is $-28{\sim}300ppm/^{\circ}C$ in the temperature range of $-55{\sim}125^{\circ}C$. We think that this composites can be used high-Q substrate material like LTCC and embedded temperature compensation capacitor in printed circuit boards.

• 대한화학회지
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• 제30권5호
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• pp.441-448
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• 1986

몰리브덴산암모늄 수용액에서 적절한 살리실알데히드의 메탄올 혼합용액으로부터 디옥소비스(치환-살리실알데히다토) 몰리브덴늄(VI), $MoO_2(X-sal)_2(X=H,\;5-CH_3)$착물을 합성하고, 이들 각각의 화합물과 다양한 일차아민의 반응에 의하여 디옥소비스(치환-살리실알디미나토) 몰리브덴늄(VI)착물, $MoO_2(X-sal-N-R)_2,\;(R=C_6H_5,\;p-F-C_6H_4,\;m-Cl-C_6H_4,\;p-I-C_6H_4$ 및 $p-C_2H_5-C_6H_4)$을 합성하였다. 이들 착물은 모두 $900{\sim}940cm^{-1}$ 부근에서 ${\upsilon}_{Mo}=0$에 기인한 두 개의 강한 흡수띠가 관찰되었고, 핵자기공명스펙트럼에서 N=CH양성자에 대한 한 개의 시그날이 8.9ppm부근에서 나타났다. 이는 이들 착물이 $cis-MoO_2$기를 가진 6배위팔면체 착물임을 나타낸다. 질량분석의 결과로부터, $MoO_2$ : ligand의 결합비가 1:2임을 확인하였고, $MoO_2(5-CH_3-sal-N-R)_2$착물에 대한 분해과정을 조사하였다. 전자흡수스펙트럼에서 $N{\to}Mo$와 $O{\to}Mo$에 해당하는 전하이동전이는 $29,000cm^{-1}$과 $32,000cm^[-1}$부근에서 각각 일어났다. 한편, 디메틸포름아미드에서 측정한 이들 착물에 대한 몰전도도로부터 이들 착물이 비이온성 물질임을 확인하였다.

• Transactions on Electrical and Electronic Materials
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• 제1권1호
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• pp.22-25
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• 2000

Polycrystalline SBTN layered ferroelectric thin film with various Nb mole ratios were prepared by sol-gel method Pt/ $SiO_2$/Si (100) substrates. The films were annealed at different temperature and characterized in terms of phase and microstructure. The films were crystallized with a high (105) diffraction intensity and had rodike structure, SBTN films fired at 800$^{circ}C$ revealed standard hysteresis loops with no fatigue for up to 10$^{10}$ cycles. At an applied voltage of 5V the dielectric constant($varepsilon$) , dissipation factor (tan $delta$), remanent polarization(ZPr) and coercive field(Ec) of typical S $r_{0.8}$B $i_{2.3}$(T $a_{1-x}$ N $b_{x}$) $O_{9+}$$alpha$/ thin film(x=0.1) prepared on Pt/ $SiO_2$/Si (100) were about 277.7, 0.042, 3.74$mu$C/$textrm{cm}^2$, and 24.8kv/cm respectively.ly.y. respectively.ly.y.y..

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 추계학술대회 논문집
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• pp.294-296
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• 1999

Solid solution ceramics having various ratios between xPb( $Y_{1}$2/T $a_{1}$2/) $O_3$ and Pb(Z $r_{0.52}$ $Ti_{0.48}$) $O_3$were synthesized by a conventional solid state reaction for well sintered specimens, dielectric and piezoelectric prperties were studied as a function of composition. The dielectric constant of PYT-PZT ceramics of 4 mol% PYT was 1,424 at room temperature. The maximum value of electromechanical couping facotr $k_{p}$ of 51% $k_{t}$ of 30% were obtained at the composition of 4 mol% PYT, howerver mechanical quality factor( $Q_{m}$) had a minimum value of 69 at 4 mol% PYT. Also the maximum value of piezoelectric constant of $D_{33}$(310[pC/N]) and $d_{31}$(-131[pC/N]) were obtained at the composition of 4 mol% PYT content.ntent.t.t.t.