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Numerical Study on Ignition Delay Time of CH4 as CO/H2 Addition in MILD Combustion (MILD 연소 환경에서 CO/H2 첨가에 따른 CH4의 점화 지연 시간의 해석적 연구)

  • Kim, Donghee;Huh, Kang Y.;Lee, Youngjae
    • Journal of the Korean Institute of Gas
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    • v.25 no.2
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    • pp.1-12
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    • 2021
  • MILD(Moderate or Intense Low-oxygen Dilution) combustion has attracted attention as the clean thermal energy technology due to the lower emissions of unburnt carbon and NOx. MILD combustion aims to enlarge the combustion reaction zone using the spontaneous ignition phenomenon of the reactants. In this study, the ignition delay time of CH4 according to the initial temperature of reactants and the addition of CO, H2 was investigated using a numerical approach. Ignition delay time became shorter as the increases of initial temperature and H2 addition. But, CO addition to the fuel increase the ignition delay time. In case of H2 addition to the fuel, the ignition delay time decreased because the higher fraction of HO2 promotes the decomposition of methyl radical(CH3) and produce OH radical. However, in case of CO addition to the fuel, ignition delay time inceased because a high proportion of HCO consumes H radical. There was no significant effect of HCO on the reduction of ignition delay time. Also, the increase rates of NO emissions by the addition of CO and H2 were approximately 7% and 1%, respectively. A high proportion of NCO affects the increase in NO production rate.

Estimation of the Input Wave Height of the Wave Generator for Regular Waves by Using Artificial Neural Networks and Gaussian Process Regression (인공신경망과 가우시안 과정 회귀에 의한 규칙파의 조파기 입력파고 추정)

  • Jung-Eun, Oh;Sang-Ho, Oh
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.34 no.6
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    • pp.315-324
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    • 2022
  • The experimental data obtained in a wave flume were analyzed using machine learning techniques to establish a model that predicts the input wave height of the wavemaker based on the waves that have experienced wave shoaling and to verify the performance of the established model. For this purpose, artificial neural network (NN), the most representative machine learning technique, and Gaussian process regression (GPR), one of the non-parametric regression analysis methods, were applied respectively. Then, the predictive performance of the two models was compared. The analysis was performed independently for the case of using all the data at once and for the case by classifying the data with a criterion related to the occurrence of wave breaking. When the data were not classified, the error between the input wave height at the wavemaker and the measured value was relatively large for both the NN and GPR models. On the other hand, if the data were divided into non-breaking and breaking conditions, the accuracy of predicting the input wave height was greatly improved. Among the two models, the overall performance of the GPR model was better than that of the NN model.

Assessment of ECMWF's seasonal weather forecasting skill and Its applicability across South Korean catchments (ECMWF 계절 기상 전망 기술의 정확성 및 국내 유역단위 적용성 평가)

  • Lee, Yong Shin;Kang, Shin Uk
    • Journal of Korea Water Resources Association
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    • v.56 no.9
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    • pp.529-541
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    • 2023
  • Due to the growing concern over forecasting extreme weather events such as droughts caused by climate change, there has been a rising interest in seasonal meteorological forecasts that offer ensemble predictions for the upcoming seven months. Nonetheless, limited research has been conducted in South Korea, particularly in assessing their effectiveness at the catchment-scale. In this study, we assessed the accuracy of ECMWF's seasonal forecasts (including precipitation, temperature, and evapotranspiration) for the period of 2011 to 2020. We focused on 12 multi-purpose reservoir catchments and compared the forecasts to climatology data. Continuous Ranked Probability Skill Score method is adopted to assess the forecast skill, and the linear scaling method was applied to evaluate its impact. The results showed that while the seasonal meteorological forecasts have similar skill to climatology for one month ahead, the skill decreased significantly as the forecast lead time increased. Compared to the climatology, better results were obtained in the Wet season than the Dry season. In particular, during the Wet seasons of the dry years (2015, 2017), the seasonal meteorological forecasts showed the highest skill for all lead times.

Plant Grouping by Light and Watering of Cacti and Succulents Planting in a Pot and Its Current Situation (선인장 및 다육식물 혼합식재 실태 및 광과 수분요구에 따른 식물의 분류)

  • Song, C.Y;Lee, S.D.;Lim, S.H.;Kim, S.J.;Lee, J.S.
    • Journal of Practical Agriculture & Fisheries Research
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    • v.8 no.1
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    • pp.30-42
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    • 2006
  • This experiment was conducted to investigate current situation and plant grouping by light and watering of mingled several cacti and succulents in a pot. The main 11 cacti are consist of Myrtillocactus geometrizans (Mart.) Cons., Gymnocalycium mihanovichii var. friedrichii Werd., Marginatocereus marginatus(DC.) Backbg., Eriocactus leninghausii (Hge. Jr.) Backbg, Notocactus scopa (Spreng.) Berg., Lobivia nealeana Backbg., Mammillaria elongata var. intertexta (DC.) SD., Pseudoespostoa (Vp1.) Backbg., Mammillaria albilanata Backbg., Mammillaria klissingiana Bod. and Espostoa lanata (HBK.) Br. & R. The main 10 succulents are Kalanchoe thyrsifolia Harv., Portulacaria afra var. foliis-variegatis Jacobs., Crassula perforata Thunbg., Echeveria pulvinata Rose, Aeonium arboreum cv. atropurpureum., Echeveria lauii Moran & J. Meyran, Pachypodium lamerei Drake, Sedum rubrotinctum cv. Aurora Boom., Aloe mitriformis Mill., and Euphorbia coerulescens Haw. The cacti were native to Mexico, Brazil, Peru, Paraguay, Ecuador, etc. The sucullents were native to Mexico, Africa, Gran Canaria, Madagascar, etc. Most of all the cacti and sucullents in the experiment are growing well under full sun or light shade, however Portulacaria afra var. foliis-variegatis Jacobs, and Sedum rubrotinctum cv. Aurora Boom. did not influenced by light. And all the plants require a little or moderate watering. Thus, planting by similar required water and light, when growing in a pot of several cacti and succulents, might be decreased the rate of death causing by their different plant physiology.

Experimental assessment of thermal radiation effects on containment atmospheres with varying steam content

  • R. Kapulla;S. Paranjape;U. Doll;E. Kirkby;D. Paladino
    • Nuclear Engineering and Technology
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    • v.54 no.11
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    • pp.4348-4358
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    • 2022
  • The thermal-hydraulics phenomena in a containment during an accident will necessarily include radiative heat transfer (i) within the gas mixture due to the high radiative absorption and emission of steam and (ii) between the gas mixture and the surrounding structures. The analysis of some previous PANDA experiments (PSI, Switzerland) demonstrated the importance of the proper modelling of radiation for the benefit of numerical simulations. These results together with dedicated scoping calculations conducted for the present experiments indicated that the radiative heat transfer is considerable, even for a very low amount of steam (≈2%). The H2P2 series conducted in the large-scale PANDA facility at the Paul-Scherrer-Institut (PSI) in the framework of the OECD/NEA HYMERES-2 project is intended to enhance the understanding of thermal radiation phenomena and to provide a benchmark for corresponding numerical simulations. Thus, the test matrix was tailored around the two opposite extremes: either gas compositions with small steam content such that radiative heat transfer phenomena can be neglected. Or gas mixtures containing larger amounts of steam, so that radiative heat transfer is expected to play a dominant role. The H2P2 series consists of 5 experiments designed to isolate the radiation phenomena from convective and diffusive effects as much as possible. One vessel with a diameter of 4 m and a height of 8 m was preconditioned with different mixtures of air / steam at room and elevated temperatures. This was followed by the build-up of a stable helium stratification at constant pressure in the upper part of the vessel. After that, helium was injected from the top into the vessel which leads to an increase of the vessel pressure and a corresponding elevation-dependent and transient rise of the gas temperature. It is shown that even the addition of small amounts of steam in the initial gas atmosphere considerably impacts the radiative heat transport throughout all phases of the experiments and markedly influences i) the monitored gas peak temperature, ii) the temperature history during the compression and iii) the following relaxation phase after the compression was stopped. These PANDA experiments are the first of its kind conducted in a large scale thermal-hydraulic facility.

Estimation of Non-linear Strength and Stiffness for Silty Sands (실트질 모래지반의 비선형 강도 및 강성도 추정법)

  • Lee Kyung-Sook;Kim Hyun-Ju;Lee Jun-Hwan
    • Journal of the Korean Geotechnical Society
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    • v.22 no.1
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    • pp.35-44
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    • 2006
  • In general typically granular soils contain a certain amount of fines. It is also widely recognized that foundation soils under working loads show highly non-linear behavior from very early stages of loading. In the present study, a series of laboratory tests with sands of different silt contents are conducted and methods to assess strength and stiffiness characteristics are proposed. Modified hyperbolic stress-strain model is used to analyze non-linearity of silty sands in terms of non-linear Degradation parameters f and g as a function of silt contents and Relative density Dr. Stress-strain curves were obtained from a series of triaxial tests on sands containing different amounts of silt. Initial shear modulus, which is used to normalize Degradation modulus of silty sands, was determined from resonant column test results. From the laboratory test results, it was observed that, as the Relative density increases, values of f decrease and those of g increase. In addition, it was found that values of f and g increase and decrease respectively as a Skeleton void ratio $(e_{sk})$ increases.

Activation of Bovine Oocytes by Combined Treatment with Ionomycin and cdc2 Kinase Inhibitor

  • Yoo, J.G.;Cho, S.R.;Lee, S.L.;Ock, S.A.;Rho, G.J.;Son, D.S.;Lee, H.J.;Choe, S.Y.
    • Journal of Embryo Transfer
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    • v.16 no.3
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    • pp.223-231
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    • 2001
  • The success of nuclear transplantation with mammalian oocytes depends critically on the potential of oocytes activation, which mainly caused to prevent the re-accumulation of maturation promoting factor (MPF). This study was conducted to compare the effect of combined treatment of lonomycin with a Hl-histone kinase inhibitor (dimethylaminopurine, DMAP) or cdc2 kinase inhibitor (sodium pyrophosphate, SPP) on activation of bovine oocytes. In vitro matured bovine oocytes with the first polar body (PB) and dense cytoplasm were assigned to 3 experimental groups. For activation treatment, oocytcs were exposed to 5 $\mu$M lonomycin for 5 min (Group 1), and followed by 1.9 mM dimethylaminopurine (DMAP) for 3 h (Group 2) or followed by 2 mM sodium pyrophosphate (SPP) for 3 h (Group 3). The activation effects in the three treatments and the control group (untreated) were judged by the extrusion of the second PB and formation of a pronucleus (PN). Differences among groups were analysed using one-way ANOVA after arc-sine transformation of proportional data. All three treatments led to high activation rates (90% to 95%), with significant difference from the control. However, the extrusion of the second PB and the rate of PN formation differed remarkably among treatments. In Group I and 3, about 95% of the oocytes had extruded the second polar body, but one PN had formed in a higher proportion of oocytes in Group 3 than in Group 1 (90% vs. 5%). In experiment 2, the rates of cleavage and development into blastocysts in Group 1 were significantly lower than those of Group 2 and 3 (8.7% and 0% vs. 50.5% and 11.6%, and 44.6% and 7.2%, respectively, P<0.05). In experiment 3, ~80% of parthenotes in Group 1 were developed with haploid chromosomal sets. However, when ionomycin was followed immediately by DMAP (Group 2). only 20% of parthenotes were haploid. In Group 3, combined treatment with ionomycin and SPP, the appearance of abnormal chromosomal tracts was significantly (P〈0.05) reduced and the proportion of haploid parthenotes was increased to 85% (17/20) than in Group 2. These results demonstrate that SPP acted as a cdc2 kinase inhibitor and formed the haploidy in oocyte activation. Thus, the present study suggests that cdc2 kinase inhibitor, such as sodium pyrophosphate, may have an effective role in oocyte activation for the production of cloned embryos/animals by nuclear transplantation.

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The Analysis of the Differences of Evaluation Level of Service Encounter Quality, Emotional Responses, Customer Satisfaction and Service Loyalty by Types of Restaurants (레스토랑 유형에 따른 레스토랑 서비스 인카운터 품질 평가 수준, 감정적 반응, 고객 만족 및 서비스 충성도 차이 분석)

  • Yang, Il-Sun;Jo, Mi-Na
    • Journal of the Korean Society of Food Culture
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    • v.21 no.5
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    • pp.524-535
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    • 2006
  • The purpose of this study was to identify the differences of cognitive responses, emotional responses, customer satisfaction, and service loyalty about service encounter quality by types of restaurants and to analyse emotional responses, customer satisfaction, and service loyalty in accordance with level of service encounter quality. The questionnaire were collected from customers (N=812) who had used restaurants in Seoul, aiming at 15 or more-year-old customers from October 24, 2005 to November 6, 2005. The main results of this study were as follows: Statistically significant difference was showed in importance and performance of interaction quality, importance and performance of physical environment quality, performance of outcome quality depending on types of restaurants, while significant difference was not indicated in importance of outcome quality by types of restaurants. Positive emotional response was significantly high by types of restaurants in order of fine-dining restaurants, family restaurants, and fast-food restaurants, while negative emotional responses were significantly higher in fast-food restaurants than in the other two types. As far as Customer satisfaction are concerned, fine-dining restaurants showed higher customer satisfaction than the other two types. Attitudinal service loyalty was high in fine-dining restaurants, family restaurants and fast-food restaurants in order and behavioral loyalty was not significantly different with each type of restaurant. In accordance with level of service encounter quality, cluster analysis was conducted and the clusters were divided into 'high-valuation' and 'low-valuation'. 'High-valuation cluster' and 'low-valuation cluster' showed significant difference depending on types of restaurants that customers used(p<.001). The customers who used fine-dining restaurants and family restaurants valued the performance of service encounter highly. However, in fast-food restaurants, a lot of low-valuation customers existed. Therefore, fast-food restaurants have to improve performance of interaction quality, outcome quality and physical environment quality in service encounter. In addition, in 'high-valuation cluster' who valued service encounter quality highly showed higher scores in positive responses, customer satisfaction, service loyalty than in 'low-valuation cluster', and showed low negative responses.

A Study on the Comparison of Korea Good Manufacturing Practice (KGMP) Evaluation Criteria with Certification Criteria of Extramural Herbal Dispensaries (원외탕전실 평가인증기준과 KGMP 평가인증 기준과의 비교연구)

  • Hyeong-Gi Kim;Eui-Hyoung Hwang;Eun-Gyeong Lee;Byung-Mook Lim;Young-Jae Shin;Sun-Young Park;Byung-Cheul Shin
    • The Korea Journal of Herbology
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    • v.38 no.6
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    • pp.61-71
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    • 2023
  • Objectives : This study aimed to find out the future direction of accreditation system of Extramural herbal dispensaries (EHD) by comparing the current criteria of EHD and the existing Korea good manufacturing practice (GMP) regulations. Methods : Among the accreditation criteria of EHD, criteria of general herbal medicine was compared with the pharmaceutical GMP of Korea. The regulations of the accreditation of EHD and the regulations of KGMP were compared and organized with similar things based on the index of KGMP. All criteria from both were extracted for each element, classified into key-words and evaluated by dividing them into the same, similar one and no-matching. Results : Among the 189 criteria of KGMP, 77 criteria were consistent with the accreditation of EHD, and 15 criteria were similar. Based on the accreditation of EHD, 70.4% of the criteria were consistent or similar to KGMP. There were a total of 27 key-words only in the GMP criteria and not in the EHD one. Hence, a total of 25 key-words only in the EHD criteria and not in the GMP one. There were 12 similar key-words, and among them, there were 4 key-words in which accreditation of EHD was more specific than the KGMP. Conclusions : The criteria of general herbal medicine in EHD showed a similar or equivalent level of accreditation criteria compared to that of pharmaceutical GMP in Korea, and it ts believed that it should be considered at the current level to reflect the characteristics of herbal medicine.

Comparison Analysis on Characteristics and Components of Various Waste Plastic Pyrolysis Oils by Vacuum Distillation Method (감압증류를 통해 분획된 폐플라스틱 열분해유의 특성평가와 구성성분 비교분석 연구)

  • Hwayeon Jeon;Cheol Hwan Jeon;Sung Joon Park;Jae Woo Lee;Jae-kon Kim
    • Clean Technology
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    • v.29 no.4
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    • pp.262-271
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    • 2023
  • Globally, the amount of waste plastics has been occurring to environmental problems. As a result, it is necessary to research methods that utilize waste plastic pyrolysis oil (WPPO) produced by pyrolysis. One such method being studied is utilizing WPPO as a naphtha feedstock. In this study, five types of WPPO were analyzed to determine whether they can be used as raw materials for naphtha. Because of their wide boiling point range, the WPPOs were fractionated into light and heavy fractions through vacuum distillation, and the separation and purification techniques were analyzed using GC-VUV to determine the content of paraffin, olefin, and other compounds. All WPPOs showed high olefin content regardless of the source and fraction. Aromatic and paraffin content varied depending on the source, and oxygen and other compounds also varied significantly by source and fraction. In addition, the light fraction showed a carbon distribution similar to that of naphtha, whereas the heavy fraction showed a carbon distribution of C11 ~ C14. In conclusion, additional processes and raw material selection are required to utilize waste plastic pyrolysis oil as a raw material for naphtha.