• Title/Summary/Keyword: QC criteria

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Evaluation of Methodology for the Measurement of VOCs in the Air by Adsorbent Sampling and Thermal Desorption with GC Analysis (흡착포집 및 열탈착/GC 분석에 의한 공기 중 휘발성 유기화합물의 측정방법론 평가)

  • 백성옥;황승만;박상곤;전선주;김병주;허귀석
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.2
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    • pp.121-138
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    • 1999
  • This study was carried out to evaluate the performance of a sampling and analytical methodology for the measurement of selected volatile organic compounds (VOCs) in the ambient air. VOCs were determined by the adsorbent tube sampling and automatic thermal desorption coupled with GC/FID and GC/MSD analysis. Target analytes were aromatic VOCs, including BTEX, 1,3,5-and 1,2,4,-trimethylbenzenes(TMBs), and naphthalene. The methodology was investigatedwith a wide range of performance criteria such as repeatability, linearity, lower detection limits, collection efficiency, thermal conditioning, breakthrough volume and calibration methods using internal and external standards. standards. Stability of samples collected on adsorbent tubes during storage was also investigated. In addition, the sampling and analytical method developed during this study was applied to real samples duplicately collected in various indoor and outdoor environments. Precisions for the duplicate samples and distributed volume samples appeared to be well comparable with the performance criteria recommended by USEPA TO-17. The audit accuracy was estimated by inter-lab comparison of both duplicate samples and standard materials between the two independent labs. The overall precision and accuracy of the method were estimated to be within 30% for major aromatic VOCs such as BTEX. This study demonstrated that the adsorbent sampling and thermal desorption method can be reliably applied for the measurement of BTEX in ppb levels frequently occurred in common indoor and ambient environments.

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Evaluation of Uncertainties in the Measurement of Ambient NO2 Level (대기 중 NO2 측정의 불확도 평가)

  • 이진홍;임종명;우진춘
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.5
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    • pp.355-362
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    • 2002
  • There has been relatively a few studies that focused on evaluation of uncertainty for standard methods by which criteria pollutants are analyzed in ambient air. Especially, uncertainty evaluation has not been made yet for sampling and analysis of airborne NO$_2$. Ambient NO$_2$ has been thought to be a major criteria pollutant worldwide because of the potential of ozone formation as well as of its own toxicity. In this study, we tried to assess uncertainties associated with the every step of sampling and of analytical procedure of Griess-Saltzman method. Quality assurance (QA) and quality control (QC) were also emphasized with the uncertainty characterization. The use of Griess-Saltzman method for ambient NO$_2$ analysis showed very uniform daily concentration distribution with the mean of 10.8 ppb and the standard deviation of 1.08ppb during the sampling period. However, seven daily samples collected at the same sampling time and place exhibited highly different concentration distribution. Therefore, we evaluated uncertainties associated with sampling and analysis through the precise application of ISO Guide. Estimates of expanded uncertainties for a total of 62 samples fell in a relatively broad range of 5.17% to 11.85%. On the other hand. the expanded uncertainties were smaller for the high concentration range of greater than 15ppb.

Experimental studies of validation and stability of Sweet Bee Venom using HPLC (Sweet BV의 조제물 농도분석 및 안정성 확인을 위한 시험적 연구)

  • Kang, Kye-Sung;Kwon, Ki-Rok
    • Journal of Pharmacopuncture
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    • v.12 no.4
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    • pp.33-50
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    • 2009
  • Objectives : This study was conducted to confirm validation and stability of concentration analysis method of pure melittin (Sweet Bee Venom-Sweet BV) extracted from the bee venom by utilizing protein isolation method of gel filtration. Methods : All experiments were conducted at Biotoxtech, a non-clinical studies authorized institution, under the regulations of Good Laboratory Practice (GLP). Standard solutions of melittin (SIGMA, USA) and test substances were dispensed and were analyzed with HPLC for Sweet BV to secure the validation of analysis. Results : 1. Measurement of system suitability of Sweet BV satisfied criterion of below 3%. 2. Confirming Linearity of Sweet BV in 10-200${\mu}g/m\ell$ solution yielded correlation coefficient (r) of 0.995 and accuracy of 85-115% which satisfy criterion. 3. Measurement of Specificity of Sweet BV didn't yield any substance affecting the peak of test substances, but detected at 21.22min verified as the test substance. 4. Confirming Intra-day of Sweet BV, accuracy and precision of 0.1, 100${\mu}g/m\ell$ were 105.70, 95.81 and 0.66, 0.73, respectively, satisfying both criteria of accuracy (85-115%) and precision (within 10%). 5. To measure Stability in autosampler, all samples used in Intra-day reproducibility sat in the autosampler for five hours and were re-analyzed. Both variability and precision satisfied the criteria. 6. Homogeneity of Sweet BV (0.1, 100${\mu}g/m\ell$) at upper, middle, and lower layers all satisfied the accuracy and precision criteria. 7. Stability of Sweet BV (0.1, 100${\mu}g/m\ell$) at room temperature for four hours and refrigerated for 7 days all satisfied the criterion. 8. For the measurement of Quality control, QC samples measured on the first and eighth day all satisfied accuracy and precision criteria. Conclusion : Above experiment data satisfies validation and stability of concentration analysis method of Sweet BV.

Development of Criteria for Predicting Delamination in Cabinet Walls of Household Refrigerators (냉장고 캐비닛 벽면에서 발생하는 박리현상 예측을 위한 평가 기준 개발에 관한 연구)

  • Park, Jin Seong;Kim, Sung Ik;Lee, Gun Yup;Cho, Jong Rae
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.21 no.4
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    • pp.1-13
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    • 2022
  • Household refrigerator cabinets must undergo cyclic testing at -20 ℃ and 65 ℃ for quality control (QC) after their production is complete. These cabinets were assembled from different materials, including acrylonitrile butadiene styrene (ABS), polyurethane (PU) foam, and steel plates. However, different thermal expansion values could be observed owing to differences in the mechanical properties of the materials. In this study, a technique to predict delamination on a refrigerator wall caused by thermal deformation was developed. The mechanical properties of ABS and PU foams were tested, theload factors causing delamination were analyzed, delamination was observed using a high-speed camera, and comparison and verification in terms of stress and strain were performed using a finite element model (FEM). The results indicated that the delamination phenomenon of a refrigerator wall can be defined in two cases. A method for predicting and evaluating delamination was established and applied in an actual refrigerator. To determine the effect of temperature changes on the refrigerator, strain measurements were performed at the weak point and the stress was calculated. The results showed that the proposed FEM prediction technique can be used as a basis for virtual testing to replace future QC testing, thus saving time and cost.

A Study on Quality Control which is Expressed in Advertisement of Residential Beds (침대 광고에 표현된 품질관리 요소에 대한 연구)

  • Rim, Kwang Soon;Kim, Jong Kuk;Choi, Joon Oh
    • Journal of the Korea Furniture Society
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    • v.25 no.3
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    • pp.213-224
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    • 2014
  • Advertising provides consumers with information about products, purchasing effect and criteria. Advertising of the domestic bed companies started in the 1990's and each company focused on publicizing its brand. As the times change, however, they begin to express the quality-property which consumers demanded in the advertising. This research examined the advertising trends in the domestic and foreign bed companies. Also, it presents how the quality control (QC) is reflected on the advertising of the domestic and foreign bed companies. As a result of the analysis on bed-advertising of them, the things mostly represented as a determinant of product quality are performance, shape/quality, recognition and reliability. On the side of consumers, however, service, durability and stability are mirrored in the advertising and help choose the products as the determinants.

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Evaluation of Analytical Techniques for Some Gaseous Criteria Pollutants through a Field Measurement Campaign in Seoul, Korea (현장측정에 기초한 대기오염물질의 측정방식에 대한 비교연구-주요 기준성 오염물질을 중심으로)

  • 김세웅;김기현;김진석;이강웅;김경렬;문동민;김필수;손동헌
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.4
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    • pp.403-415
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    • 1999
  • To properly assess air pollution levels, application of quality assurance and quality control(QA/QC) is believed to be an essential step. In order to cope with such scientific principle, a field study was designed with an aim of comparing: 1) the methods of calibration for airborne pollutants and 2) the protocols developed for their measurements. Measurements were made at Han Yang University, Seoul during 29 May through 1 June 1998 under the management of the Division of Measurements and Analysis(DMA) of Korean Society for Atmospheric Environment(KOSAE). In this work, we report our results of intercomparative measurements on several gaseous criteria pollutants that were investigated mainly by the two institutes-Seoul National University(SNU) and the Korean Research Institute for Standards and Science(KRISS). Although measurements of major gaseous pollutants had been made routinely by many scientific institutes and organizations in Korea, most scientists involved in those studieswere obliged to do their experiments on the basis of their own procedural steps spaning from the preparation of gaseous standards to the methodological selections for the calibration. Hence, this campaign offered a unique opportunity to examine many important aspects on the measurements of these important gaseous pollutants. In the course of our study, we investigated the compatibility of data sets obtained by the two institutes in concert with reference data sets collected concurrently from a government-managed monitoring station. On the basis of our study, we conclude that different data sets made by different participants during this campaign agree well within the reasonable range of uncertainties.low, which indicated that during this period the potential acidity of precipitation was high but the neutralizing capacity was low. For Spring, pAi was very low but pH was slightly high. This was likely due to the large amount of $CaCO_3$ in the soil particles transported over a long range from the Chinese continent that were incorporated into the precipitation, and then neutralized the acidifying species with its high concentraton.

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Analysis of Effective Improvement Depth for Establishing Quality Control Criteria of Rapid Impact Compaction for Public Fill Compaction (Public Fill 다짐 시 급속충격다짐공법의 품질관리기준 수립을 위한 유효개량심도 분석)

  • Kim, Kyu-Sun;Park, Jaeyoung;Kim, Hayoung
    • Journal of the Korean Geotechnical Society
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    • v.39 no.10
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    • pp.5-18
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    • 2023
  • The construction timeline for earthworks can be significantly reduced by substituting the conventional layer-by-layer compaction using a vibratory roller with single-layer compaction through the rapid impact compaction (RIC) method. Dynamic load compaction is well-suited for coarse-grained soils like sand. However, as the supply of sand, the primary reclamation material, becomes scarcer, the utilization of soil with fines is on the rise. To implement the dynamic load compaction, such as RIC, with reclaimed materials containing fines, it's imperative to determine the effective improvement depth. In this study, we assess the impact of the RIC method on the effective improvement depth for clean sand and public fill with fines, comparing field test results before and after RIC application. Our focus is on the cone resistance (qc) as it pertains to compaction quality control criteria. In conclusion, it becomes evident that standardizing the cone resistance is vital for the quality control of various reclaimed soils with fines. We have evaluated the compaction quality control criteria corresponding to a relative density (Dr) of 70% for clean sand as Qtn,cs = 110. As a result of this analysis, we propose new quality control criteria for qc, taking into account the fines content of reclaimed soils, which can be applied to RIC quality control.

Comparison of Measurement Methods for Volatile Organic Compounds in Ambient Air Using Adsorbent Tubes and Canisters (흡착관과 캐니스터를 이용한 대기 중 휘발성유기화합물 측정방법의 비교 평가)

  • Baek, Sung-Ok;Seo, Young-Kyo;Heo, Gwi-Seok;Jeon, Chan-Gon;Lee, Min-do;Han, Jin-Seok
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.3
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    • pp.305-319
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    • 2016
  • This study was carried out to evaluate the performance of two sampling methods, i.e., adsorbent tubes and canisters, for the measurement of ambient volatile organic compounds (VOCs). A total of 24 target VOCs were selected from a list of 48 priority hazardous air pollutants (HAPs) in Korea. The two sampling methods were investigated with a wide range of performance criteria such as repeatability, linearity, and lower detection limits. In addition, mean relative errors (MRE) and mean duplicate precisions (MDP) were estimated by inter-lab comparison studies for duplicate field samples. Precisions for the two methods appeared to be well comparable with the performance criteria recommended by USEPA TO-15 and TO-17 for canister and adsorbent methods, respectively. Correlations and variations between the VOCs concentrations determined by the two methods were generally good in most cases. However, MREs and MDPs for individual VOCs appeared to be widely ranged, depending on each VOC. This implies that the two methods have its own advantages and disadvantages in determining a variety of VOCs in ambient air, and neither of which has absolute superiority. Finally, 9 of 24 VOCs were found to be difficult to determine by either methods due to their unstability in a canister, and lack of appropriate standard materials. Thus, it is suggested that development of measurement methods for such unstable VOCs is an urgent task from a viewpoint of HAPs management.

Optimizing dispatching strategy based on multicriteria heuristics for AGVs in automated container terminal (자동화 컨테이너 터미널의 복수 규칙 기반 AGV 배차 전략 최적화)

  • Kim, Jeong-Min;Choe, Ri;Park, Tae-Jin;Ryu, Kwang-Ryul
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2011.06a
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    • pp.218-219
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    • 2011
  • This paper focuses on dispatching strategy for AGVs(Automated Guided Vehicle). The goal of AGV dispatching problem is allocating jobs to AGVs to minimizing QC delay and AGV total travel distance. Due to the highly dynamic nature of container terminal environment, the effect of dispatching is hard to predict thus it leads to frequent modification of dispatching results. Given this situation, single rule-based approach is widely used due to its simplicity and small computational cost. However, single rule-based approach has a limitation that cannot guarantee a satisfactory performance for the various performance measures. In this paper, dispatching strategy based on multicriteria heuristics is proposed. Proposed strategy consists of multiple decision criteria. A muti-objective evolutionary algorithm is applied to optimize weights of those criteria. The result of simulation experiment shows that the proposed approach outperforms single rule-based dispatching approaches.

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Repeatability and Appropriate Predicted Value of Portable Spirometry on Korean Adults (휴대용 폐기능 검사기의 재현성과 기대치에 관한 연구)

  • Choi, Jun-Yong;Jung, Hee-Jae;Lee, Kun-Young;Jeong, Seung-Yeon;Hwang, Joon-Ho;Rhee, Hyung-Koo;Jung, Sung-Ki
    • The Journal of Internal Korean Medicine
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    • v.26 no.3
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    • pp.587-595
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    • 2005
  • Objectives : The object of this study was to evaluate repeatability of portable spirometry and to determine an appropriate equation for predicted value. Materials and Methods : The subjects were 76 men and 45 women recruited from among Kyunghee University oriental medical students. Portable spirometry was performed via the procedure recommended in ATS guidelines. Repeatability of spirometry was checked against ATS repeatability standards and NHLEP QC grade. Percentage of predicted value of non-smokers was calculated through a Caucasian population-based regression equation(by Morris et al.) and Korean population based regression equation(by Kim et al.). These were compared. Result : 91.7% of subjects matched repeatability standards of ATS and 95% of subjects got interpretable NHLEP QC grades of A, B, and C. Mean percentage of predicted value by Morris et al. were as follows: Mean of FVC% was 90.86, FEV1% was 96.66, FEV1/FVC% was 107.48. Mean percentage of predicted value by Kim et al. were as follows. Mean FVC% was 92.38, FEV1% was 89.77, FEV1/FVC% was 96.95. Conclusions : Results of this study show that more than 90% of subjects meet repeatability criteria. This supports a role for the portable spirometer as a primary oriental medical office tool. Further, results are a verify that they Korean population-based predicted value equation is a more appropriate standard than the Caucasian population-based one, but a still more accurate standard is needed for the Korean adult population.

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