• Title/Summary/Keyword: Pyrophyllite

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Occurrence and Mineralogy of Sericite Deposit in the Hongjesa Granite from the Bonghwa Area in Kyungsangbuk-do, Korea (경북 봉화지역 홍제사 화강암 내에 배태하는 견운모광상의 산상 및 구성광물)

  • Oh, Ji-Ho;Hwang, Jin-Yeon;Koh, Sang-Mo;Kwack, Kyu-Won;Lee, Hyo-Min;Chi, Se-Jung
    • Journal of the Mineralogical Society of Korea
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    • v.21 no.1
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    • pp.67-83
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    • 2008
  • The sericite ore deposits formed in the Precambrian granitic rock at the Bonghwa area, Kyungsangbuk-do, South Korea. The geochemical and mineralogical characteristics of sericite occurred in Daehyun and Seonghwang mine were analyzed using petrographic microscope, XRD, EPMA, XRF and ICP. An alteration mechanism was also studied. Sericitization occurred within the granitic rock by hydrothermal alteration. From the careful study on the occurrence and mineral assemblage, four alteration zone were clearly identified. These zones reflect progressive hydrothermal alteration process. All sericites belong to $2M_1$ polytype and their mineralogical and geochemical properties are close to illite. The sericite ores show various colors, but the characteristics of major element compositions and crystal structures are not different. The trace element analysis, however, indicates that the difference in color attribute to the abundance of Cr and Ti: bluish green colored sericite are enriched in Cr and blackish green colored sericite enriched in Ti. The formation of sericite ore deposit in the granitic rocks are closely relate to fracture system such as fault and joint. It is considered that the sericite ore deposits in this area were formed by very simple hydrothermal alteration occurred along the fracture zones in granitic rocks with absence of other hydrothermally altered minerals such as kaolin and pyrophyllite.

Variations in Geochemical characteristics of the Acid Mine Drainages due to Mineral-Water Interactions in Donghae Mine Area in Taebaek, Korea (태백 동해광인일대의 물-광물의 반응에 의한 산성광산배수의 지구화학적 특성 변화)

  • 김정진;김수진
    • Economic and Environmental Geology
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    • v.35 no.1
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    • pp.55-66
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    • 2002
  • There are several abandoned coal mines around Donghae mine area in the Taebaek coal field. Two major creeks, Soro and Sanae, are contaminated with the colored precipitates formed from the coal mine drainages. Bed rocks of the study area consist of limestone, shale, and sandstone. Limestone consisted mainly of calcite and dolomite, and shale of quartz, pyropyllite and chlorite, and sandstone of quatz and illite. Coal coal spoil dumps composed mainly of pyrite and chlorite. The oxidative dissolution of sulfide minerals leads to acid mine drainage and adds the metal ions in the stream water. The ion concentrations of Fe, Ca, Mg, Al, Si, SO$_{4}$in the stream polluted by AMD are generally higher than those in the unpolluted stream water. High concentrations of Ca and Mg, Al and Si can be resulted from dissolution of carbonate minerals such as calcite, dolomite and aluminosilicates such as chlorite, pyrophyllite. Although the Fe, Al, Si, SO$_{4}$ contents are considerbly high in the acid water released from the mine adits, they become decreased downstream due to dilution of unpolluted water and precipitation of oxide/hydroxide and sulfate minerals on the bottom of stream.

Sedimentary type Non-Metallic Mineral Potential Analysis using GIS and Weight of Evidence Model in the Gangreung Area (지리정보시스템(GIS) 및 Weight of Evidence 기법을 이용한 강릉지역의 퇴적기원의 비금속 광상부존가능성 분석)

  • Lee Sa-Ro;Oh Hyun-Joo;Min Kyung-Duck
    • Spatial Information Research
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    • v.14 no.1 s.36
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    • pp.129-150
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    • 2006
  • Mineral potential mapping is an important procedure in mineral resource assessment. The purpose of this study is to analyze mineral potential using weight of evidence model and a Geographic Information System (GIS) environment to identify areas that have not been subjected to the same degree of exploration. For this, a variety of spatial geological data were compiled, evaluated and integrated to produce a map of potential mineral in the Gangreung area, Korea. for this, a spatial database considering mineral deposit, topographic, geologic, geophysical and geochemical data was constructed for the study area using a GIS. The used mineral deposits were non-metallic(Kaolin, Porcelainstone, Silicastone, Mica, Nephrite, Limestone and Pyrophyllite) deposits of sedimentary type. The factors relating to mineral deposits were the geological data such as lithology and fault structure, geochemical data, including the abundance of Al, As, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, Pb, Si, Sr, V, Zn, $Cl^-,\;F^-,\;{PO_4}^{3-},\;{NO_2}^-,\;{NO_3}^-,\;SO_{42-}$, Eh, PH and conductivity and geophysical data, including the Bouguer and magnetic anomalies. These factors were used with weight of evidence model to analyze mineral potential. Probability models using the weight of evidence were applied to extract the relationship between mineral deposits and related factors, and the ratio were calculated. Then the potential indices were calculated by summation of the likelihood ratio and mineral potential maps were constructed from Geographic Information System (GIS). The mineral potential maps were then verified by comparison with the known mineral deposit areas. The result showed the 85.66% in prediction accuracy.

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Material Characteristics and Provenance Presumption for Stone Artifacts of Bronze Age from the Hyocheon Site in Gwangju, Korea (광주 효천유적 출토 청동기시대 석기의 재질특성과 원산지 추정)

  • Park, Sung-Mi;Lee, Chan-Hee;Kim, Ji-Young;Jeong, Il
    • Journal of Conservation Science
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    • v.21
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    • pp.5-20
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    • 2007
  • The stone artifacts in Bronze age from the Hyocheon sites in the Gwangju, Korea were studied on the basis of material characteristics and provenance presumptions. The use and rock names of the artifacts are a stone shovel by andesite, the stone grinding pestle by pyrophyllite, the stone sickle by schist and four stone semifinished artifacts by slates. Andesitic stone shovel could be observed easily around the Hyocheon relic site. But, rocks of the stone grinding pestle, the stone sickle, the stone arrowhead and the stone semifinished artifacts could be confirmed typical occurrences of the all kinds of rocks around the Hwasun coal mine area above 10km from the site. These are made the coupled samples with each stone artifact to the same kinds of raw material rocks based on analysis of the lithology and geochemistry. As a result a geochemical evolution trends of both a stone artifact and the rock showed very similar patterns based on normalization using the behavior, enrichment, compatibility and incompatibility of the elements. Therefore, the source rock of the stone shovel was convey from Mudeung mountain possible interpreted that the domestic-type artifacts are distributed in the vicinity of the Hyocheon site. On the other hand, the stone grinding pestle, the stone sickle, the stone arrowhead and the stone semifinished artifacts were convey from the Hwasun coal mine area possible foreign-type stone artifacts interpreted that the source rocks. Consequently, in the foreign-type stone artifacts are should archaeologic research which it can examine various possibilities clearly that the possibility to coming the introduction with the mankind migration, diffusion to dealings of tribe, the captured enemy equipment through the war and the trade with the behavior of the materials.

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Production and evaluation of raw materials for porcelain using clay mineral (점토 광물을 이용한 도자기용 소지 제조 및 물성 평가)

  • Kim, Jong-Young
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.6
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    • pp.317-328
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    • 2019
  • In this work, we investigated clay and raw materials from China (black clay, red clay, white clay) and Korea (Cheonan clay, Obu clay) used for the manufacture of porcelain products. According to chemical analysis results, feldspar components containing CaO, K2O, Na2O and quartz are found in clay materials besides primary clay such as kaollinte, for the clay materials from Korea, which is found more in clay materials from Korea than from China. For the Fe2O3 content, governing whiteness of porcelain products, more iron oxide (> 5 %) is found in Korean clays (Cheonan clay, obu clay, red clay) compared to those form China (black, white clay). Through X-ray diffraction analysis, kaolinite and Halloysite are found to be main phases for all the raw materials and second phases such as quartz and pyrophyllite are found. Using these clay materials, raw materials for porcelain products were produced, and the physicochemical properties were investigated for sintered samples. Absorption rate is in order of Baekja-A < Baekja-B < Yeonbuncheong < Jinbuncheong < Cheongja, and the sample, sintered at 1250℃ in reductive atmosphere, exhibits the lowest absorption rate. Comparing the color of the sintered samples, the samples sintered in oxidative atmosphere (L* value: 86~95 %) show higher whiteness value than those sintered in reductive atmosphere (L* value: 81~93 %). For the Cheongja and Buncheong, the samples sintered in reductive atmosphre shows higher whiteness, L* values, and low a*/b* value, which is due to reduction of iron oxide (Fe2O3).

Mineral Identification and Field Application by Short Wave Infrared (SWIR) Spectroscopy (단파장적외선 분광분석법을 이용한 광물동정과 현장적용성)

  • Kim, Chang Seong;Kim, Yong-Hwi;Choi, Seon-Gyu;Ko, Kwang-Beom;Han, Kyeong-Soo
    • Economic and Environmental Geology
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    • v.50 no.1
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    • pp.1-14
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    • 2017
  • The analytical conditions including surface state, moisture effect, and device condition were investigated for applying Short Wave Infrared(SWIR) spectroscopy to the field survey. Among the three surface state of samples (exposed surface, cutting face and powder), both spectra from the exposed surface and cutting face are almost identical whereas spectral variation was detected in powder sample. Over 24-hours-dryring of the wet sample at room temperature, the samples show a similar spectrum with that of dry condition. The result suggests that outcrop samples mighty be dried for 24 ~ 48 hours depending on the wetness of outcrop. The bright minerals could produce stable spectra with 10 times measurements as default value of the device under SWIR spectroscopy but the dark minerals would require about 10 seconds, which corresponds to 100 times measurements to get the reliable spectra. The position and shape 2,160 ~ 2,330 nm and/or other spectral features of hydrothermal alteration minerals by SWIR spectroscopy could be used for a classification of hydrothermal alteration zone in the field. Absorption peaks in 2,160 ~ 2180 nm are useful for identifying (advanced) argillic zone by spectral characteristics of kaoline, dickite, pyrophyllite, and alunite. Absorption peaks in 2,180 ~ 2,230 nm are able to define muscovite, sericite, and smectite, which are key alteration minerals in phyllic zone. Absorption peaks in 2,230 ~ 2,270 nm can be used to recognize prophylitic zone where chlorite and epidote occur. Absorption peaks of other principle minerals such as talc, serpentine, amphibole, and carbonate group are mainly detected within the wave length of 2,270 ~ 2,330 nm. This result indicates that the spectra of these minerals need to be carefully interpreted.