• Bulletin of the Korean Chemical Society
• /
• v.24 no.9
• /
• pp.1276-1280
• /
• 2003

Thermal behavior of bromphenols was investigated by direct pyrolysis at high temperature. The thermal degradation products formed by the pyrolysis of mono-bromophenols (o-, m-, and p-) were identified by gas chromatography-mass spectrometry. During the pyrolysis reactions, several kinds of dioxins and furans were produced, and the relative ratio of pyro-products was dependent on the substituted position of bromine in phenolic structure due to the effect of symmetry and steric hindrance. The formation of dioxins can be explained by the phenoxy radical addition and Br atom elimination at an ortho-carbon site on phenolic structure. On the other hand, the formation of furans can be explained by the ortho-ortho carbon coupling of phenoxy radicals at unsubstituted sites to form o, o'-dihydroxydiphenyl intermediate via its keto-tautomer, followed by $H_2O$ elimination. The pyrolysis temperature has also a substantial effect on the dimerized products quantities but little effect on the type of pyro-products. Moreover, the formation mechanism of pyro-products was suggested on the basis of products identified.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2008.05a
• /
• pp.179-182
• /
• 2008

Most of the guided weapons have been kept and transferred at the launching tube and fired in case of necessity in these day. Launching tube is a kind of case to protect the guided weapons from external environments and conducted as a guide when they are fired. When we attached the guided weapons to launching tube we usually has used explosive bolt. Explosive bolts have been used explosives when they had to be separated. But when they are separated there are some bad effects; a flame, fragments and pyro-shock. Because of these bad effects there are many restriction to use bolt as joining devices to precision guided weapons. To solve these problems we invented ball type bolt. Unlike explosive bolt, ball type bolt is separated without a flame, fragments and pyro-shock. And it also has a good mechanical properties as much as those of explosive bolt.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2008.11a
• /
• pp.94-97
• /
• 2008

As the partial admission turbine has a intrinsically unsteady and three dimensional flow region, numerical calculation time of these study has been too long time. The numerical analysis for gas temperature of turbine blade surface has been performed to investigate development of temperature with various pyro start pressure. Computations have been carried out several turbine rotational speeds in the range from 0 to 16000 rpm and inlet conditions with 1423K, 7.2MPa. As a result, the more rotational speed and pyro starter pressure of turbine increased, the more turbine blade's temperature decreased. It is also found that flow field of turbine blade inlet area at pyro starter pressure of 5.75MPa and rotational speed of 12100 rpm formed surface temperature uniformly.

• Journal of Aerospace System Engineering
• /
• v.10 no.2
• /
• pp.34-40
• /
• 2016

A satellite is exposed to various impact environment until orbit entry. It is particularly undergoing the biggest impact by pyro shock, which is generated when the launch vehicle stages are separated or the satellite is separated from the launch vehicle. In this paper, due to the fact that the pyro shock is prerequisite for performing the test and verification on the ground, we developed an air-gun type shock tester for NEXTSat-1 shock test at the KAIST SaTReC along with the development of program introduced by LabVIEW software. The program operated in shock tester is consist of data measurement and analysis with the convenient implementation of user interface and its easy modification of the code.

• Bulletin of the Korean Space Science Society
• /
• 2004.10b
• /
• pp.239-242
• /
• 2004

The fairing of the launch vehicles has a role of protecting the spacecraft from outer thermal, acoustical, and mechanical loads during flight. Among them, the thermal load is analyzed in the present study. The ascent thermal analyses include aerodynamic heating rate on every point of the fairing, heat transfer through the fairing and spacecraft, and the final temperature during ascent flight phase. A design code based on theoretical/experimental database is applied to calculate the aerodynamic heating rate, and a thermal math program, SINDA/Fluint, is considered for conductive heat transfer of the fairing. The results show that the present design satisfies the allowing temperature of the structure. Another important thermal problem, pyro explosive fairing separation device, is calculated because the pyro system is very sensitive to the temperature. The results also satisfies the pyro thermal condition.

• Nuclear Engineering and Technology
• /
• v.54 no.2
• /
• pp.637-643
• /
• 2022

Uranium and plutonium are required to be accounted in spent fuel head-end and major recovery area in pyro-process for safeguards purpose. The possibility of neutron resonance technique, as a nondestructive analysis, was simulated on isotopic fissile analysis for large scale process. Neutron resonance technique has advantage to distinguish uranium from plutonium directly in mixture. Simulation was performed on U235 and Pu239 assay in spent fuel and for scoping examination of assembly type. The resonance energies were determined for U235 and Pu239. The linearity in the neutron transmission was examined for the selected resonance energies. In addition, the limit for detection was examined by changing sample density, thickness and content for actual application. Several factors were proposed for neutron production and the moderated neutron source was simulated for effective and efficient transmission measurement. From the simulation results, neutron resonance technique is promising to analyze U235 and Pu239 for spent fuel assembly. An accurate fissile assay will contribute to an increased safeguards for the pyro-processing system and international credibility on the reuse of fissile materials in the fuel cycle.

• Journal of the Korea Institute of Military Science and Technology
• /
• v.25 no.5
• /
• pp.545-551
• /
• 2022

We proposed a design method for constant current pyro squib circuit. The current method using N MOSFET for the stability problem has a weakness of the current change, requiring a new design. This paper identified the problem with conventional squib circuit where the current is reduced by 25 % when maximum resistance is 3 ohms. Thus, we proposed a stable constant current driving circuit using P MOSFET and PNP BJT. We confirmed stable constant circuit operation through simulations and measurements of the proposed circuit design where the current did not change until the resistance reached 3 ohms.

• Proceedings of the Korean Society of Food and Cookery Science Conference
• /
• 2003.10a
• /
• pp.84-84
• /
• 2003

생면제조시 각종 인산염의 효과를 구명하기 위하여 PG(propylene glycol), 폴리인산나트륨, 메타인산나트륨, 피로인산나트륨 등을 단독 또는 복합으로 첨가하여 제면특성 및 저장 중 생기는 이화학적 특성을 비교, 조사하였다. 인산염의 단독 또는 복합 처리에 의한 amylogram 특성은 최고점도의 경우 대조구, PG, polyphosphate, pyrophosphate, metaphosphate, PG+poly., PG+pyro. 및 PG+meta. 첨가구에서 273, 269, 274, 260, 272, 295, 269 RVU이었고 setback 값은 대조구, PG, polyphosphate, pyrophosphate, metaphosphate, PG+poly., PG+pyro. 및 PG+meta. 첨가구에서 104, 97, 92, 99, 99, 95, 102 RVU이었다. (중략)

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.10 no.3
• /
• pp.171-188
• /
• 2012

A GoldSim template program for a safety assessment of a hybrid-typed repository system, called "A-KRS," in which two kinds of pyro-processed radioactive wastes, low-level metal wastes and ceramic high-level wastes that arise from the pyro-processing of PWR nuclear spent fuels are disposed of, has been developed. This program is ready both for a deterministic and probabilistic total system performance assessment which is able to evaluate nuclide release from the repository and farther transport into the geosphere and biosphere under various normal, disruptive natural and manmade events, and scenarios. The A-KRS has been deterministically assessed with 5 various normal and abnormal scenarios associated with nuclide release and transport in and around the repository. Dose exposure rates to the farming exposure group have been evaluated in accordance with all the scenarios and then compared among other.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.10 no.4
• /
• pp.263-272
• /
• 2012

A GoldSim template program for a safety assessment of a hybrid-typed repository system, called A-KRS, in which two kinds of pyro-processed radioactive wastes, low-level metal wastes and ceramic high-level wastes that arise from the pyro-processing of PWR nuclear spent fuels are disposed of, has been developed. This program is ready both for a deterministic and probabilistic total system performance assessment which is able to evaluate nuclide release from the repository and farther transport into the geosphere and biosphere under various normal, disruptive natural and manmade events, and scenarios. The A-KRS has been probabilistically assessed with 9 selected input parameters, each of which has its own statistical distribution for a normal release and transport scenario associated with nuclide release and transport in and around the repository. Probabilistic dose exposure rates to the farming exposure group have been evaluated. A sensitivity of 9 selected parameters to the result has also been investigated to see which parameter is more sensitive and important to the exposure rates.