• Title/Summary/Keyword: Pure oxygen

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Effects of $CO_{2}$ Recirculation on Turbulent Jet Diffusion Flames with Pure Oxygen (이산화탄소 재순환이 순산소 난류제트 확산화염에 미치는 영향)

  • Cha, Min-Suk;Kim, Ho-Keun;Kim, Han-Seok;Ahn, Kook-Young
    • 한국연소학회:학술대회논문집
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    • 2003.05a
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    • pp.255-260
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    • 2003
  • Characteristics of methane jet diffusion flames using pure oxygen with recirculating $CO_{2}$ as an oxidizer were investigated experimentally. A coflow burner was considered, and the diameter of confinement was larger than that of the coflow. No stabilized flame could be observed over 75% of $CO_{2}$ volume percent. A comparison between air and $O_{2}/CO_{2}$ mixture was made in terms of liftoff velocity, flame liftoff height, and blowout conditions. As results, more stable flame could be observed with $O_{2}/CO_{2}$ mixture for the case of having similar flame temperature.

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Treatment Characteristics of Paper-mill Wastewater Using Pure Oxygen Activated Sludge Process (순산소 활성오니 공정을 이용한 제지폐수의 처리특성)

  • Kim, Sung Soon;Chung, Tai Hak
    • Journal of Korean Society of Water and Wastewater
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    • v.13 no.4
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    • pp.27-34
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    • 1999
  • An experimental study on improvement of the paper-mill wastewater treatment using the pure oxygen activated sludge process was conducted. The effects of hydraulic retention time(HRT) and BOD loading on organic removal efficiency were investigated. The BOD removal efficiencies were above 90% under all examined HRTs except for HRT of 3 hours. The increase of HRT from 3 hours to 6 hours, and to 12 hours significantly improved BOD and COD removal efficiencies, respectively. However, additional increase of HRT did not affect organic removal efficiency. F/M ratio change at fixed HRT did not affect organic removal efficiency. However, F/M ratio investigated in this study(0.11~1.98kgBOD/kgMLVSS/day) was 5 times greater in maximum than that of conventional activated sludge process, which implies that pure oxygen activated sludge process can treat wastewater with high organic strength. Under the same HRT, the volumetric BOD loading change cause no effect on organic removal efficiency also.

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Chemical activation of precursor and dopant by ozone (오존에 의한 전구체와 혼입제의 화학적 활성화)

  • 이상운;윤천호;박정일;박광자
    • Journal of the Korean Vacuum Society
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    • v.8 no.3A
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    • pp.201-206
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    • 1999
  • Transparent and conduction tin oxide films have been deposited on glass substrates employing the low pressure chemical vapor deposition technique. Tetramethyltin, 1, 1, 1, 2-tetrafluoroethane, and pure oxygen or ozone-containing oxygen were used as the precursor, dopant and oxidant, respectively. In order to examine the role of ozone in the low pressure chemical vapor deposition of tin oxide films, deposition rate, and electrical and optical properties of tin oxide films deposited using ozone-containing oxygen were compared with those using pure oxygen. Tetramethyltin and 1, 1, 1, 2-tetrafluoroethane were chemically activated by thermally initiated decomposition of ozone. Using ozone-containing oxygen under otherwise identical deposition conditions, we succeeded in preparing tin oxide films f better quality at higher deposition rate.

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SIMULATION ON PURE OXYGEN COMBUSTION OF SMV FOR $CO_2$ REDUCTION (이산화탄소 저감을 위한 SMV의 순산소 연소 시뮬레이션)

  • Kim, H.Y.;Sohn, H.S.;Kim, C.M.
    • 한국전산유체공학회:학술대회논문집
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    • 2011.05a
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    • pp.275-277
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    • 2011
  • KOGAS(Korea Gas Corporation) uses two-type vaporizers to send customers natural gas with imported LNG. In winter season, SMVs(SubMerged combustion Vaporizers) are mainly operated due to low seawater temperature. SMVs consume the natural gas of 1,520 $Nm^3/hr$ and emit a lot of $CO_2$ in winter time. If carbon taxes are activated on climate change, the tax burden will be severely heavy. Accordingly this work carried out numerical simulation with a commercail CFX code to investigate its possibility on the practical use of pure oxygen combustion of SMVs to reduce $CO_2$ and to improve its efficiency. First, a nozzle of a SMV's combustor is modelled. The combustion characteristics of Air/Fuel and Oxygen/Fuel are analyzed under folly insulated condition. Although we couldn't find the carbon reduction and the efficient elevation when the pure oxygen/fuel type was compared to the existing air/fuel one, we need a further study to investigate the effect of $CO_2$ recirculation.

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The Study of Biofouling Control and Cause Material in Hybrid Process of Pure Oxygen and Submerged Membrane Bio-reactor (순산소 고율포기시스템 및 침지식 MBR융합공정에서 Biofouling 제어 및 원인물질 규명에 관한 연구)

  • Lee, Sang-Min;Kim, Mi-Hyung
    • Journal of Korean Society on Water Environment
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    • v.27 no.1
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    • pp.44-53
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    • 2011
  • Membrane bio-reactor (MBR) has several advantages over the conventional activated sludge process, including a high biomass, low sludge production, and better permeate quality. Therefore, the MBR have gained popularity for municipal and industrial wastewater treatment. However the MBR usually were used for sewage and low streng th wastewater treatment because of membrane fouling problem and limitation of oxygen transfer into biomass. In this study, the hybrid process combining MBR and pure oxygen was tested for high strength organic wastewater treatment in the COD loading range from 2 to $10kgCOD/m^3{\cdot}day$. The hybrid process, membrane coupled pure oxygen high compact reactor (MPHCR), had been operated for one year and operation parameters, the effect of COD loading, MLSS concentration and the location of membrane module were studied for membrane fouling characteristic. Also membrane resistance test and the component of foulant was analyzed to investigate what is specific foulant in the MBR.

Effect of Dissolved Oxygen on the Stress Cor rosion Cracking Behavior of 3.5NiCrMoV Steels in High Temperature Water

  • Lee, J.H.;Maeng, W.Y.;Kim, U.C.
    • Corrosion Science and Technology
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    • v.2 no.4
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    • pp.178-182
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    • 2003
  • Slow Strain Rate Tests (SSRT) were carried out to investigate the effect of environmental factors on the Stress Corrosion Cracking (SCC) susceptibility of 3.5NiCrMoV steels used in discs for Low-Pressure (LP) steam turbines in electric power generating plants. The influences of dissolved oxygen on the stress corrosion cracking of turbine steel were studied, For this purpose, specimens were strained at variously oxygenated conditions at $150^{\circ}C$ in pure water. When the specimen was strained with $1{\times}10^{-7}s^{-1}$ at $150^{\circ}C$ in pure water, increasing concentration of dissolved oxygen decreased the elongation and the UTS. The corrosion potential and the corrosion rare increased as the amounts of dissolved oxygen increased. The increase of the SCC susceptibility of the turbine steel in a highly dissolved oxygen environment is due to the non protectiveness of the oxide layer on the turbine steel surface and the increase of the corrosion current. These results clearly indicate that oxygen concentration increases Stress Corrosion Cracking susceptibility in turbine steel at $150^{\circ}C$.

Electrical and Optical Properied of Tin Oxide Films Prepared by Ozone Assisted-MOCVD (Ozone Assisted-MOCVD로 제작된 산화주석막의 전기적 광학적 특성)

  • 배정운;이상운;송국현;박정일;박광자;염근영
    • Journal of the Korean institute of surface engineering
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    • v.31 no.2
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    • pp.109-116
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    • 1998
  • Highly transparent conductive pure and fluorine-doped tin oxide(FT0, $SnO_2$ : F) films have been prepared by low pressure metal organic chemical vapor deposition (LP-MOCVD) from various mixtures of tetramethyitin(TMT) with oxygen or oxygen containing ozone. The properties of TO films have been changed with the variation of gases, flow rate, and substrate temperature. The nsing of oxygen containing ozone instead of pure oxygen, reduced substrate temperature by 100-$150^{\circ}C$ while maintaining same thickness. The films prepared by using ozone showed the resistivity in the range from $10^~2$ to $10^{~3}\Omega$cm, and the mobiiity from 10 to $14\textrm{cm}^2$/Vs. Fluorine-doped tin oxide films had properties such as the resistivity about $10^{-4}\Omega$cm, and the mobility from 14 to $19\textrm{cm}^2$/Vs.

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A Study on the Apparatus for Measuring Oxygen-Permeability of Membranes with a Multi-Electrode Oxygen Sensor (다전극 산소 센서를 이용한 고분자 막의 산소 투과도 측정 장치 연구)

  • Jeong, Il-Son;Jung, Jae-Chil;Kim, Tai-Jin
    • Journal of Sensor Science and Technology
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    • v.21 no.3
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    • pp.229-234
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    • 2012
  • The existing permeability measurements based on pressure differential between the polymer membrane that is permeable to measure the amount of oxygen used, but these methods must be kept in a vacuum, and the measurement of the membrane with low permeability in the membrane is too time consuming. In recent years by using electrochemical method polymer membrane currents caused by the amount of oxygen is a measure of how much is used. In this study, apparatus consisting of one anode and six cathodes for multi-oxygen permeability tester used the same number of membranes produced by electrochemical oxygen permeation characteristics. In this study, one silver/silver chloride anode electrochemical method with a hexagonal sensor to put various kinds of polymer membranes with the six oxygen permeability for simultaneous measurement in real-time systems. Six cathodes (Pt), and one of the coil-shaped anode (Ag/AgCl) to form a hexagonal one of the polarographic oxygen sensor in a single measurement system by six sensors. Each sensor for making hexagonal specificity of the sensor to compensate for the conditions obtained in a pure nitrogen gas and pure oxygen gas conditions. With this study, self-developed hexagonal sensor capable of measuring sensors and oxygen permeability tester, for a multi-six different oxygen permeability characteristics of the membrane measured at the same time.

Development of a High Efficiency Polymer Electrolyte Membrane Fuel Cell Stack under Pressurized Operating Conditions (고효율 가압형 고분자전해질 연료전지 셀스택 개발)

  • Han, In-Su;Seo, Hakyu;Jung, Jeehoon;Kim, Minsung;Shin, Hyunkhil;Hur, Taeuk;Cho, Sungbaek
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.125.1-125.1
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    • 2010
  • A high efficiency polymer electrolyte membrane (PEM) fuel cell stack was developed for pressurized pure hydrogen and oxygen supplying conditions. The design objective for the cell stack was to maximize the electric efficiency and to minimize exhaust-gas emissions from it simultaneously. To achieve this objective, the cell stack was designed to use pure hydrogen and oxygen as fuel and oxidant, respectively, and to be operated under high gas inlet pressures and in a stage-wise dead-end operation mode. Major components constituting the cell stack, such as membrane electrode assembly, bipolar-plate, and gasket, have been developed to meet a target durability even in severe operating conditions: high gas inlet pressures and usage of pure oxygen. A high-power fuel cell stack was assembled using these components to verify the performance. The cell stack showed a good performance in terms of the efficiency and maximum power output.

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Kinetic Analysis for Paper-mill Wastewater Treatment Using Pure Oxygen Activated Sludge Process (순산소 활성오니공정을 이용한 제지폐수처리의 동력학적 해석)

  • Kim, Sung Soon;Chung, Tai Hak
    • Journal of Korean Society of Water and Wastewater
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    • v.14 no.2
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    • pp.157-163
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    • 2000
  • An experimental study was conducted to evaluate the treatment efficiency of paper-mill wastewater using pure oxygen activated sludge process. Effects of hydraulic retention time (HRT) and organic loading on process performance and kinetics were investigated. The raw paper-mill wastewater(BOD concentration ${\leq}500mg/L$) and the effluent from dissolved air flotation(DAF) treatment(BOD concentration ${\geq}500mg/L$) were used as influent for pure oxygen activated sludge process. Average BOD removal efficiencies were above 89.3% under 6hours or longer of HRT, while under 3hours of HRT they decreased to about 82%. With the effluent from DAF process, the half saturation constants($K_S$) and the maximum specific substrate removal rate($K_{max}$) were 85 mg/L and 2.25 L/day, respectively. However, with the raw paper-mill wastewater, both $K_S$ and $K_{max}$ increased to 156 mg/L and 3.84 L/day, respectively. The microbial yield coefficient(Y) and the decay coefficient($K_d$) were 0.46 gVSS/gBOD and 0.03 L/day, respectively, with effluent from DAF process. While, Y and $K_d$ were 0.24 gVSS/gBOD and 0.035 L/day, respectively, with the raw paper-mill wastewater.

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