• Title/Summary/Keyword: Pure Volume

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A Molecular Dynamics Simulation Study on Hygroelastic behavior of Thermosetting Epoxy (열경화성 에폭시 기지의 흡습탄성 거동에 관한 분자동역학 전산모사)

  • Kwon, Sunyong;Lee, Man Young;Yang, Seunghwa
    • Composites Research
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    • v.30 no.6
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    • pp.371-378
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    • 2017
  • In this study, hygroelastic behavior of thermosetting epoxy is predicted by molecular dynamics simulations. Since consistent exposures to humid environments lead to macroscopic degradation of polymer composite, computational simulation study of the hygroscopically aged epoxy cell is essential for long-time durability. Therefore, we modeled amorphous epoxy molecular unit cell structures at a crosslinking ratio of 30, 90% and with the moisture weight fraction of 0, 4 wt% respectively. Diglycidyl ether of bisphenol F (EPON862) and triethylenetetramine (TETA) are chosen as resin and curing agent respectively. Incorporating equilibrium and non-equilibrium ensemble simulation with a classical interatomic potential, various hygroelastic properties including diffusion coefficient of water, coefficient of moisture expansion (CME), stress-strain curve and elastic modulus are predicted. To establish the structural property relationship of pure epoxy, free volume and internal non-bond potential energy of epoxy are examined.

Study on Background Music of Distributors (유통점의 배경음악에 관한 연구)

  • LEE, Joon-Pyo;HWANG, Hee-Joong
    • Journal of Distribution Science
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    • v.17 no.9
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    • pp.127-131
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    • 2019
  • Purpose - This study focuses on clues that can clearly amplify the effects of background music. Review which store environments have a direct and positive impact on consumer responses, such as purchases. Research design, data, and methodology - This study focuses on clues that can clearly amplify the effects of background music. The purpose of this study is to examine what kind of store environment, combined with background music, has a direct and positive effect on consumer reactions such as purchase, and suggest future research directions. Results - The manager decides to use background music in the store because it is relatively inexpensive and easy to identify the emotional response of the consumer. In addition, appropriate background music lowers the psychological purchasing barriers of consumers. Previous studies have often not conducted a basic review of whether consumers perceive background music when it is used in retail stores. For example, it is necessary to make sure that the volume of the background music is loud enough and that the noise is properly excluded despite the congestion of the store so that the pure influence of the background music on the consumer can be measured. A way for store managers to clarify and differentiate their identity is to create a unique and satisfying store atmosphere for their customers. In order to help customers focus on their purchases, store managers must use marketing elements to integrate the five senses. And they should plan background music aiming at synergy effect of these five senses. In other words, in order to make the store atmosphere positive, it is not enough to have a suitable visual design interior or background music in the store, and consumers should have the opportunity to smell, taste and touch it directly. Conclusions - In conclusion, we hope that the following issues will be studied by several scholars in the future. It should be clarified that the impact of background music on customers varies depending on the customer's movement in the store, the selection of the background music genre order, and the timing (interval) of background music exposure to the customer.

Effect of soil Venting on Dissolution Potential of Gasoline Components in Contaminated Soil: Experimental Observation (Soil Venting이 오염토양중 가솔린 성분의 용출성에 미치는 영향: 1. 실험적 고찰)

  • 염익태;이상현;안규홍
    • Journal of Korea Soil Environment Society
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    • v.3 no.2
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    • pp.53-60
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    • 1998
  • The influence of venting on the leaching characteristics of pure gasoline and gasoline contaminated soil was studied. The change of leaching characteristics by venting of contaminated soil column could be characterized by two distinct trends : 1) the leaching concentration in TPH-GRO rapidly decreased with evaporation until the evaporation loss became 75% of the original volume. Afterwards, it gradually decreased. 2) the leaching concentrations of individual components showed initial increase followed by gradual decrease. In general, the relative increase of leaching concentration and the venting time to reach the maximum increased with the molecular weight of the components. It should be noted that the decrease of gasoline concentration in the vented air occurs faster than that in the leaching solution. This indicates that, after removing most of the gasoline by evaporation, the focus of the risk assessment for the residual contaminants should be on the groundwater contamination rather than air pollution.

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Ultrasonic Nondestructive Evaluation of Creep-Induced Cavities (크리프 기공의 초음파 비파괴평가에 관한 연구)

  • Jang, Young-Su;Jeong, Hyun-Jo
    • Journal of the Korean Society for Nondestructive Testing
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    • v.19 no.2
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    • pp.110-117
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    • 1999
  • In order to ultrasonically evaluate creep cavities pure copper samples were subjected to creep test and their microstructures were examined. Ultrasonic velocities. frequency-dependent magnitude spectra and attenuations were measured on a series of copper samples obtained from the different stages of creep test. Velocities measured in three directions with respect to the loading axis decreased and their anisotropy increased as a function of the creep-induced porosity. The anisotropic behavior could be attributed to the progressive change of pore shape and preferred orientation as the creep advanced. The 2% porosity by volume decreased the longitudinal and shear wave velocities by 11% and 4%, respectively. Furthermore, both velocities decreased nonlinearly with the porosity. As the creep damage developed, the magnitude spectra lost high frequency components and their central frequencies shifted to lower values. The attenuation showed almost linear behavior in the frequency range used. Normalized velocity, central frequency shift and attenuation slope were selected as nondestructive evaluation parameters. These results were presented and showed good relations with the porosity content.

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Removal of Uranium from U-bearing Lime-Precipitate using dissolution and precipitation methods (우라늄 함유 석회침전물의 용해 및 침전에 의한 U 제거)

  • Lee, Eil-Hee;Lee, Keun-Young;Chung, Dong-Yong;Kim, Kwang-Wook;Lee, Kune-Woo;Moon, Jei-Kwon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.2
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    • pp.77-85
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    • 2012
  • This study was carried out to remove (/recover) the uranium from the Uranium-bearing Lime Precipitate (ULP). An oxidative dissolution of ULP with carbonate-acidified precipitation and a dissolution of ULP with nitric acid-hydrogen peroxide precipitation were discussed, respectively. In point of view the dissolution of uranium in ULP, nitric acid dissolution which could dissolved more than 98% of uranium was more effective than carbonate dissolution. However, in this case, uranium was dissolved together with a large amount of impurities such as Al, Ca, Fe, Mg, Si, etc. and some impurities were also co-precipitated with uranium during a hydrogen peroxide precipitation. On the other hand, in the case of carbonate dissolution-acidified precipitation, U was dissolved less than 90%. Therefore, it was less effective than nitric acid dissolution for the volume reduction of radioactive solid waste. However, it was very effective to recover the pure uranium, because impurities were hardly dissolved and hardly co-precipitated with uranium.

Synthesis of Ti-SBA-15 Doped with Lanthanide Ion and Photocatalytic Decomposition of Methylene Blue (La 이온이 도핑된 Ti-SBA-15의 합성 및 메틸렌블루의 광촉매 분해 반응)

  • Jung, Won-Young;Hong, Seong-Soo
    • Applied Chemistry for Engineering
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    • v.21 no.3
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    • pp.323-327
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    • 2010
  • Ti-SBA-15 catalysts doped with lanthanide ion were synthesized using conventional hydrothermal method and they were characterized by XRD, FT-IR, DRS, $NH_3$-TPD and PL. We also examined the activity of these materials on the photocatalytic decomposition of methylene blue. La/Ti-SBA-15 samples with varying lanthanide ions doping maintained the mesoporous structure and the catalysts calcined at $500^{\circ}C$ for 6 h showed the highest crystallinity. With increasing the doping amount of lanthanide ion, the pore size and pore volume of La/Ti-SBA-15 materials decreased but the surface area increased. 1% La/Ti-SBA-15 catalysts showed the highest photocatalytic activity on the decomposition of methylene blue but the catalysts doped with more than 5% lanthanide ions showed lower activity compared to pure Ti-SBA-15 catalyst.

3D Architectures of LaVO4:Eu3+ Microcrystals via an EG-assisted Hydrothermal Method: Phase Selective Synthesis, Growth Mechanism and Luminescent Properties

  • Ding, Yi;Zhang, Bo;Ren, Qifang;Zhang, Qicai;Zha, Weiwei;Li, Xin;Chen, Shaohua;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.54 no.2
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    • pp.96-101
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    • 2017
  • In this article, pure $m-LaVO_4:Eu^{3+}$ and $t-LaVO_4:Eu^{3+}$ nanocrystals were prepared by an EG-assisted hydrothermal method with regular shapes. A series of controlled experiments showed that the pH value of a mixed solution, the volume ratio of $EG/H_2O$ and the dosage of the doped $Eu^{3+}$ all had an important effect on the sizes and shapes of the final products. Furthermore, the constitutional unit of the products changed from 0D to 2D with an increase in the EG dosage. The PL results showed that $t-LaVO_4$ doped with $Eu^{3+}$ ions had better luminescence properties than $m-LaVO_4$ due to its special structure. All of these results not only expand our understanding of the luminescence properties of lanthanide orthovanadates, but they also elucidate the principles of the crystal growth.

Fabrication and Evaluation of 5 vol%CNT/Al Composite Material by a Powder in Sheath Rolling Method (분말시스압연법에 의한 5 vol%CNT/Al 복합재료의 제조 및 평가)

  • Hong, Dongmin;Kim, Woo-Jin;Lee, Seong-Hee
    • Korean Journal of Materials Research
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    • v.23 no.11
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    • pp.607-612
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    • 2013
  • A powder in sheath rolling method was applied to the fabrication of a carbon nano tube (CNT) reinforced aluminum composite. A 6061 aluminum alloy tube with outer diameter of 31 mm and wall thickness of 2 mm was used as a sheath material. A mixture of pure aluminum powder and CNTs with a volume content of 5% was filled in the tube by tap filling and then processed to an 85% reduction using multi-pass rolling after heating for 0.5 h at $400^{\circ}C$. The specimen was then further processed at $400^{\circ}C$ by multi-pass hot rolling. The specimen was then annealed for 1 h at various temperatures that ranged from 100 to $500^{\circ}C$. The relative density of the 5vol%CNT/Al composite fabricated using powder in sheath rolling increased with increasing of the rolling reduction, becoming about 97% after hot rolling under 96 % total reduction. The relative density of the composite hardly changed regardless of the increasing of the annealing temperature. The average hardness also had only slight dependence on the annealing temperature. However, the tensile strength of the composite containing the 6061 aluminum sheath decreased and the fracture elongation increased with increasing of the annealing temperature. It is concluded that the powder in sheath rolling method is an effective process for fabrication of CNT reinforced Al matrix composites.

Effect of Anodizing Current Density on Anti-Corrosion Characteristics for Al2O3 Oxide Film (Al2O3 산화 피막의 내식성에 미치는 양극산화 전류밀도의 영향)

  • Lee, Seung-Jun;Jang, Seok-Gi;Kim, Seong-Jong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.153-153
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    • 2016
  • Aluminum alloys have poor corrosion resistance compared to the pure aluminum due to the additive elements. Thus, anodizing technology artificially generating thick oxide films are widely applied nowadays in order to improve corrosion resistance. Anodizing is one of the surface modification techniques, which is commercially applicable to a large surface at a low price. However, most studies up to now have focused on its commercialization with hardly any research on the assessment and improvement of the physical characteristics of the anodized films. Therefore, this study aims to select the optimum temperature of sulfuric electrolyte to perform excellent corrosion resistance in the harsh marine environment through electrochemical experiment in the sea water upon generating porous films by variating the temperatures of sulfuric electrolyte. To fabricate uniform porous film of 5083 aluminum alloy, we conducted electro-polishing under the 25 V at $5^{\circ}C$ condition for three minutes using mixed solution of ethanol (95 %) and perchloric (70 %) acid with volume ratio of 4:1. Afterward, the first step surface modification was performed using sulfuric acid as an electrolyte where the electrolyte concentration was maintained at 10 vol.% by using a jacketed beaker. For anode, 5083 aluminum alloy with thickness of 5 mm and size of $2cm{\times}2cm$ was used, while platinum electrode was used for cathode. The distance between the two was maintained at 3 cm. Afterward, the irregular oxide film that was created in the first step surface modification was removed. For the second step surface modification process (identical to the step 1), etching was performed using mixture of chromic acid (1.8 wt.%) and phosphoric acid (6 wt.%) at $60^{\circ}C$ temperature for 30 minutes. Anodic polarization test was performed at scan rate of 2 mV/s up to +3.0 V vs open circuit potential in natural seawater. Surface morphology was compared using 3D analysis microscope to observe the damage behavior. As a result, the case of surface modification presented a significantly lower corrosion current density than that without modification, indicating excellent corrosion resistance.

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Bar effects on the central SF and AGN activities in the SDSS galaxy sample

  • Kim, Minbae;Choi, Yun-Yung;Kim, Sungsoo S.
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.35.3-36
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    • 2016
  • We explore the role of bars in AGN-galaxy co-evolution using a volume-limited face-on late-type galaxy sample with $M_r$ < -19.5 and 0.02 < z < 0.055 selected from SDSS DR7. In this study, we investigate how $SFR_{fib}$ as a proxy of gas contents at galactic center (over 1~1.5 kpc bulge scale) and central stellar velocity dispersion, ${\sigma}$, of host galaxies are connected to the bar presence and AGN activity. We find that galaxies are distributed in three distinct regions over the $SFR_{fib}-{\sigma}$ space and the behaviors of their bar fraction ($f_{Bar}$) are clearly different for each region. Galaxies at the AGN dominant region tend to be gas-deficient as $f_{Bar}$ increases and bars are more frequently found in fully-quenched late-type galaxies at the quiescent region, suggesting that bars speed up of the consumption of gas by SF and lead a sudden decline in the central gas. Overall, the bar effects on the AGN activity are positive over the same space except for quiescent galaxies with ${\sigma}$ > $170km\;s^{-1}$. Most significant bar effect on the AGN activity occurs in the less massive galaxies having sufficient gas, whereas the effect on galaxies at the AGN dominant region with higher the AGN fraction is relatively small. We suggest that the bar affect both central SF and AGN activities, but differently for central gas amount and BH (or bulge) mass of galaxies. We also investigate the AGN-bar connection with only pure AGNs and then confirm that they give marginally the same results.

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