• 한국기계가공학회지
• /
• 제16권5호
• /
• pp.141-149
• /
• 2017

Due to the inaccuracy of micro-machining, various special processing methods have been investigated recently. Among them, pulse electrochemical machining is a promising machining method with the advantage of no residual stress and thermal deformation. Because the cross section of the wire electrode used in this study is circular, wire-pulse electrochemical machining is suitable for micro-hole machining. By applying the response surface methodology, the experimental plan was made of three factors and three levels: machining time, duty factor, and voltage. The regression equation was obtained through experiments. Then, by referring to the main effect diagram, we fixed the duty factor and machining time with little relevance, and solved the equation for the target 900 microns to obtain the voltage value. The results obtained from the response surface methodology were approximately those of the target value when the actual experiment was carried out. Therefore, it is concluded that the optimal conditions for hole processing can be obtained by the response surface methodology.

• 공업화학
• /
• 제22권5호
• /
• pp.575-578
• /
• 2011

전기화학적 증착 기법을 이용하여 간단하고 빠르게 3차원적 구조를 가지는 다공성 금 박막(NPGF : nanoporous gold thin film)을 금 기판 위에 제작하였다. 제작된 3차원적 구조의 NPGF는 주사 전자 현미경(SEM)을 이용하여 표면을 분석하였고, 이를 통하여 표면상에 30~50 nm 크기의 균일한 다공성 박막이 생성되었음을 확인하였다. Differential pulse voltammetry(DPV) 기법을 기반으로 3차원적 구조체를 가진 NPGF기판을 전극으로 사용하여 GABA를 농도별($10{\sim}100{\mu}M$)로 측정하였다. 본 연구에서 제안된 방법은 향후, 바이오센서 응용분야에 널리 사용될 수 있을 것으로 기대된다.

• 한국정밀공학회:학술대회논문집
• /
• 한국정밀공학회 2003년도 춘계학술대회 논문집
• /
• pp.1199-1202
• /
• 2003

In this research, microfabrication technique using localized electrochemical deposition is presented. Electric field is localized near the tip end region by applying ultra short pulses. Platinum tip is used as the counter electrode and copper is deposited on the copper substrate in 0.5 M CuSO$_4$ and 0.5 M H$_2$SO$_4$ electrolyte. The deposition characteristics such as size, shape, and structural density according to pulse duration and applied voltage are investigated. Micro-columns less than 10 $\mu\textrm{m}$ in diameter are fabricated using the presented technique. The process can be potentially used for three dimensional metal structure fabrications with micrometer feature size.

• Journal of Electrochemical Science and Technology
• /
• 제5권1호
• /
• pp.23-31
• /
• 2014

The DL-norvaline was electrochemically oxidized and deposited on the glassy carbon electrode surface using cyclic voltammetry (CV). The modified electrode was examined for electrochemical oxidation of hydroquinone (HQ) and catechol (CC). It exhibited good electrocatalytic ability towards their oxidation and simultaneous determination in a binary mixture using differential pulse voltammetry (DPV). The peak currents were linear to the concentration of HQ and CC, in the range from $5{\mu}M$ to $100{\mu}M$, and $4{\mu}M$ to $140{\mu}M$, respectively. The determination limits(S/N = 3) for HQ and CC were $1{\mu}M$ and $0.8{\mu}M$, respectively. The obtained modified electrode was applied to simultaneous detection of HQ and CC in water sample.

• 한국정밀공학회지
• /
• 제28권3호
• /
• pp.308-314
• /
• 2011

In micro electrochemical machining (micro ECM), machining conditions have been determined to maintain a small side gap and to machine a workpiece stably However, machining speed is slow. To improve machining speed while maintaining the form accuracy, the paper investigates machining parameters such as pulse amplitude, duty ratio, pulse on-time, and the electrolyte's temperature and concentration. The experiment in this study shows that the electrolyte's concentration is the key factor that can reduce machining time while maintaining the form accuracy Micro square columns were fabricated to confirm the machining parameters' effects.

• Archives of Pharmacal Research
• /
• 제23권3호
• /
• pp.197-201
• /
• 2000

In an aqueous piperacillin sodium solution, a well-defined single wave or single peak was observed by direct current(DC) polarography or differential pulse polarography(DPP). The peak potential change per pH unit was -54 mV in the phosphate buffer at $18^{\circ}C$, which indicated that protons were involved in the electrochemical reduction of the 2,3-dioxopiperazine moiety of piperacillin sodium with a $H^{+}e^{-}$ ratio of one. Using a phosphate buffer of pH 4.3, the $1.0{times}10^{-7}$ M piperacillin sodium single peak could be determined by DPP with relative standard deviation of 1.6 %(n=3). Piperacillin sodium could be analyzed with-out interference from penicillin G-potassium, which enabled the employment of DPP as a fast and simple technique for monitoring the synthetic process of the antibiotic.

• 한국정밀공학회:학술대회논문집
• /
• 한국정밀공학회 2007년도 추계학술대회 논문집
• /
• pp.151-152
• /
• 2007

• 한국정밀공학회:학술대회논문집
• /
• 한국정밀공학회 2012년도 춘계학술대회 논문집
• /
• pp.491-492
• /
• 2012

• Bulletin of the Korean Chemical Society
• /
• 제33권12호
• /
• pp.4247-4250
• /
• 2012

• 한국정밀공학회:학술대회논문집
• /
• 한국정밀공학회 2010년도 추계학술대회 논문집
• /
• pp.405-406
• /
• 2010