• Title/Summary/Keyword: PtP

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Preparation of Pt-Black Absorber by Electroplating (전기도금법에 의한 백금 흑 수광체 제조)

  • Bae, Seong-Ho;Lee, Sang-Man;Lee, Mun-Ho
    • Korean Journal of Crystallography
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    • v.7 no.2
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    • pp.133-146
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    • 1996
  • Morphology and infrared absorbing characteristics of Pt-black prepared by electroplating have been investigated with XRD, SEM, and IR spectrophotometer. The Pt later was coated on Au-coated alumina/glass substrates for 1-5 min at pH 1.0-1.5, where a solution of platinum chloride and lead acetate was used as the electrolyte. At the electrical current density of 20-50 mA/㎠, the Pt-black showed a dendritic growth which was characterized by a "tree" shape. Absorptivity of above 90% at IR radiation of 10 m was observed for the Pt absorbing layer with an area density of ≥1.3mg/㎠.

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Anti-inflammatory activity of the water extract of Polygala tenuifolia Willd (원지(遠志)의 항염증 작용에 대한 연구)

  • Oh, Hyun-Suk;Kim, Byoung-Woo
    • The Journal of Internal Korean Medicine
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    • v.34 no.2
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    • pp.204-214
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    • 2013
  • Objectives : This study was designed to investigate the cellular and molecular mechanisms of anti-inflammatory activity of the water extract of Polygala tenuifolia Willd. (Pt-WE). Methods : Using lipopolysaccharide (LPS)-stimulated murine RAW264.7 cells, we examined inflammatory mediators such as nitric oxide (NO), inducible NO synthase (iNOS), cyclooxygenase (COX)-2 and prostaglandin $E_2$ ($PGE_2$). Also, the inhibitory effect of Pt-WE on the activity of activator protein 1 (AP-1) and upstream signaling molecules was evaluated. To assess the protective effect of Pt-WE on hydrochloride/ethanol (HCl/EtOH)-induced gastric ulcer in mice, we compared Pt-WE (200 mg/kg) with ranitidine (50 mg/kg) treated mice's gastric mucosa, based on gross observations. Results : Pt-WE inhibited LPS-induced production of NO, $PGE_2$ in a dose-dependent manner, without causing cytotoxicity. Pt-WE suppressed AP-1 activation by reducing generations of both c-Jun and c-Fos. In addition, Pt-WE inhibited the p-MKK 4/7 (mitogen-activated protein kinase kinase 4/7) and p-JNK (c-Jun N-terminal kinase) 1 in LPS-stimulated RAW264.7 cells. HCl/EtOH-induced gastric ulcer lesions were inhibited by pre-treatment of Pt-WE based on gross observations. In addition, Pt-WE decreased the phosphorylation level of JNK. Conclusions : These results demonstrate that Pt-WE has anti-inflammatory and gastroprotective effects. Thus, Pt-WE may be used widely in treatment of not only neurodegenerative diseases but also inflammatory diseases.

Quantitative Comparison of the E-book and Paper-book by using Eye-tracker

  • Kim, Jung-Yong;Lee, Min-Ho;Min, Seung-Nam;Cho, Young-Jin;Choi, Jun-Hyeok
    • Journal of the Ergonomics Society of Korea
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    • v.31 no.5
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    • pp.609-616
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    • 2012
  • Objective: The aim of the study is to evaluate the difference of legibility between e-book and paper-book by using eye-tracker. Background: Despite of many researches on the e-book and paper-book, there are few researches on the difference between e-book and paper-book. In addition, the researches on the e-book were only dependent on the e-book reader. This study focused on the comparison of e-book and paper-book controlled with the same environments. Method: This study was conducted with $2{\times}3$ within-subject design. Independent variables include the types of book (e-book, paper-book) and font sizes (8pt, 10pt, 12pt). Dependent variables are four measures of fixation duration, saccade length, blink rate and subjective discomfort. Analysis of Variance (ANOVA) with repeated measured design was used to investigate the main and interaction effects of independent variables on each of the dependent variables. The multiple comparisons were performed by post hoc analysis and Bonferroni correction was applied. Results: Fixation duration at e-book was longer than paper-book (p<0.01). Saccade length at e-book was shorter than paper-book (p<0.05). Blink rate at e-book was higher than paper-book (p<0.1). Subjective discomfort at e-book was higher than paper-book (p<0.1). Legibility at 8pt was better than 10pt, 12pt (p<0.01) in fixation duration, saccade length and subjective discomfort. Conclusion: It was found that the legibility at e-book are worse than paper-book from this study. These results indicated that the legibility of e-book was needed to be validated and improved to replace the paper-book. Application: This study suggests improving something related to fixation duration, saccade length, blink rate and subjective discomfort for betterment of e-book.

Synthesis of Mesoporous Pt-Au Alloy Electrode by Electrodeposition Method for Direct Methanol Fuel Cell (전기화학적 증착법에 의한 직접 메탄올 연료전지(DMFC)용 메조포러스 백금-금 합금전극제조)

  • Park, Eun-Kyung;Ahn, Jae-Hoon;Kim, Young-Soo;Kim, Kyung-Hwa;Baeck, Sung-Hyeon
    • Korean Chemical Engineering Research
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    • v.46 no.4
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    • pp.727-731
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    • 2008
  • Mesoporous Pt-Au alloy films were successfully fabricated on ITO-coated glass by electrodeposition method using tri-blockcopolymer (P123) as a templating agent. The electrolyte consisted of 10 mM hydrogen hexachloroplatinate ($H_2PtCl_6$), 10 mM hydrogen tetrachloroaurate ($HAuCl_4$), and proper amount of P123. For comparison, control samples were electrodeposited without $HAuCl_4$ and P123. Film composition was determined by EDS(Energy Dispersive X-ray Spectroscopy), and the mesoporous structure was confirmed by TEM(Transmission Electron Microscopy). SEM(Scanning Electron Microscopy) was utilized to examine surface morphology, and it was observed that the addition of P123 affected the particle growth, resulting in the significant change of surface morphology. Methanol oxidation and CO oxidation were carried out to investigate electrocatalytic activities of synthesized samples. It was observed that the catalytic activity was strongly dependent on the film compositions. Compared with nonporous electrode prepared without P123 templating, mesoporous films prepared with P123 templating showed much higher catalytic activities and stability for both methanol oxidation and CO oxidation. These enhanced electrocatalytic activities were due to the high surface area and facilitated charge transfer of mesoporous films.

Development of the pH Inhibition Model Adapting Pseudo Toxic Concentration (CPT) Concept for Activated Sludge Process (의사독성농도 (CPT) 개념을 도입한 활성슬러지 공정 pH 저해 모델 개발)

  • Ko, Joo-Hyung;Jang, Won-Ho;Im, Jeong-Hoon;Woo, Hae-Jin;Kim, Chang-Won
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.11
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    • pp.2037-2046
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    • 2000
  • It has been reported that the inhibition effect of pH on activated sludge follows noncompetitive inhibition kinetics. However. the noncompetitive inhibition kinetic equation can not be directly applied to pH inhibition because of the difficulty in quantification of pH in terms of inhibitor concentration. So, many empirical equations have been developed to describe the pH inhibition effect especially for acidic condition. In this research. the pseudo toxic concentration ($C_{PT}$) concept model to quantify pH inhibition effect on activated sludge was proposed and compared to other existing models. The $C_{PT}$ concept model can explain the reduction of the maximum specific growth rate (${\mu}_{max}$) caused by the pH inhibition more accurately than any other models, at a wide range of pH. The only model parameter. $K_I$ can be easily estimated by Lineweaver-Burk linearization method.

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Effects of Heterostructure Electrodes on the Reliability of Ferroelectric PZT Thin Film (강유전체 PZT박막의 신뢰도에 미치는 헤테로구조 전극의 영향에 대한 연구)

  • Lee, Byoung-Soo;Lee, Bok-Hee;Lee, Duch-Chool
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.52 no.1
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    • pp.14-19
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    • 2003
  • The effect of the Pt electrode and the $Pt-IrO_2$ hybrid electrode on the performance of ferroelectric device was investigated. The modified Pt thin films with non-columnar structure significantly reduced the oxidation of TiN diffusion barrier layer, which rendered it possible to incorporate the simple stacked structure of Pt/TiN/poly-Si plug. When a $Pt-IrO_2$ hybrid electrode is applied, PZT thin film properties are influenced by the thickness and the partial coverage of the electrode layers. The optimized $Pt-IrO_2$ hybrid electrode significantly enhanced the fatigue properties of the PZT thin film with minimal leakage current.

Synthesis and Nephrotoxicity of Pt Complexes as Antitumor Agent (항암활성을 갖는 백금 착체의 합성과 신독성)

  • Lee, Keun-Im;Whang, Kyu-Ja
    • YAKHAK HOEJI
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    • v.38 no.6
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    • pp.627-636
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    • 1994
  • Several Pt(II) and Pt(IV) complexes of N,N'-bis(2-hydroxyethyl)ethylenediamine(2-HEen) and N,N'-bis(2-chloroethyl) ethylenediamine(2-CEen) as carrier ligand were prepared. Water soluble Pt complexes were also synthesized by modification of leaving groups. The cytotoxicity of these compounds against leukemia L1210 and P388 cell in vitro were examined. The Pt complexes containing 2-CEen showed more effective cytotoxicity than those containing 2-HEen. Through the nephrotoxicity tests on the primary cultured proximal tubular cells of rabbit kidney and human kidney cells in vitro, Pt complexes with 2-CEen showed higher than those with 2-HEen which were consistent with cytotoxicity but showed very low nephrotoxicity compared with cisplatin. Also the values of BUN and creatinine in serum of Pt complexes were reduced remarkably compared with cisplatin, therefore it can be concluded that new Pt complexes seems to have much lower nephrotoxicity than cisplatin.

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n-type porous silicon formation using Pt mask & its application (Pt를 mask로 이용한 n-type 다공질 실리콘 형성과 응용)

  • Kang, Chul-Goo;Min, Nam-Ki;Lee, Seung-Jae
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.1760-1762
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    • 2000
  • 본 논문은 기존의 $Si_{3}N_4$, SiN 물질 대신 Pt를 사용해 HF 용액속에서 다공질 실리콘과 전극을 동시에 형성하는 기술을 개발하였다. Pt를 실리콘 웨이퍼 위에 직접 증착한 후 습식 에칭과 Lift-off 공정을 사용하여 Pt를 패터닝하였다. 습식 에칭은 에칭용액의 온도를 일정하게 유지하는 것이 중요하며, 증착한 Pt 박막이 BOE 에칭에 견디고, Lift-off 공정이 가능하기 위해서는 기판온도를 l100$^{\circ}C$ 이하로 해야한다. Pt를 사용하면 기존의 mask에서 발생하는 가장자리 부분에서의 전류 집중이 방지되기 때문에 다공질 실리콘이 일정한 깊이로 형성되고, Al대신 오믹 전극으로 사용할 수 있다. 현재 Pt를 mask와 전극으로 이용한 P-I-N UV detector, 광 바이오센서, 습도센서 제작등에 응용 연구가 진행되고 있다.

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Inhomogeneous Growth of PtSi Studied by Spatially Resolved Photoelectron Spectroscopy

  • Kumar, Yogesh;Lee, Kyoung-Jae;Yang, Mihyun;Ihm, Kyuwook;Hwang, C.C.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.149.1-149.1
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    • 2013
  • Noble metal silicides are widely used in silicon based microelectronic and optoelectronic devices. Among them, as compared to other silicides, structural and electronic properties of platinum silicide (PtSi) are found to be less sensitive to change in its dimensions. PtSi is known to overcome the junction spiking problems of Al-Si contacts. Present study is regarding the spatial evolution of platinum silicide in Pt/SiOx/Si. Scanning photoelectron emission microscopy (SPEM) was used for this purpose. SPEM images were obtained for pristine samples and after an annealing at $500^{\circ}C$ for 1 hr. Core-level spectra were recorded at different points in SPEM images contrasted by the intensity of Pt 4f7/2. Both Pt 4f and Si 2p spectra reveal the formation of PtSi after annealing. However, in contrast to earlier reports, PtSi formation is found to be non-uniform confirmed by the SPEM images and from the core level spectra taken at different intensity points.

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Study on Ginseng Protopanaxadiol and Protopanaxatriol Saponins-Induced Antinociception

  • Shin, Young-Hee;Kim, Seok-Chang;Han, Ji-Won;Kim, Dae-Hoon;Han, Sang-Sub;Shin, Dong-Ho;Nah, Seung-Yeol
    • The Korean Journal of Physiology and Pharmacology
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    • v.1 no.2
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    • pp.143-149
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    • 1997
  • We studied the effects of ginseng protopanaxadiol (PD) and protopanaxatriol (PT) saponins on the analgesia using several pain tests such as writhing, formalin, and tail-flick test. Using mouse, pretreatment of PD or PT saponins (i.p.) induced inhibition of abdominal constrictions caused by 0.9% acetic acid administration(i.p.). The $AD_{50}$ was around 27 (17-43) mg/kg for PD and 13.5 (3-61) mg/kg for PT saponins in writhing test. Both PD and PT saponins also showed the inhibition of bitings and lickings of hindpaw after administration of 1% formalin. In particular, both PD and PT saponins showed analgesic effects on second phase of pain. The $AD_{50}$ was 44.5 (26-76) mg/kg for PD and 105 (55-200) mg/kg for PT saponins in second phase of formalin test. For first phase pain inhibition by PD or PT saponins, they were required higher concentrations. However, PD saponins showed weak analgesic effects in tail-flick test with high concentration. In conclusion, we found that both PD and PT saponins have the analgesic effects in writhing test and second phase of pain in formalin test. These results suggest that both PD and PT saponins inhibit neurogenic or tonic pain rather than acute pain.

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