• 제목/요약/키워드: Processability

검색결과 169건 처리시간 0.027초

Miscibility of Branched Polycarbonate Blends with Poly(ethylene-co-1,4-dimethyl cyclohexane terephthalate) Copolyesters

  • Song, Jeong-Oh;Jeon, Mi-Young;Kim, Chang-Keun
    • Macromolecular Research
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    • 제15권7호
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    • pp.640-645
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    • 2007
  • The phase behavior of branched polycarbonate (BPC) blends with poly(ethylene terephthalate-co-1,4-dimethyl cyclohexane terephthalate) copolyesters (PECT), as well as their rheological properties, were assessed. Even though BPC blends with PECT prepared by solvent casting proved to be immiscible, BPC and PECT copolyesters containing 1,4-dimethyl cyclohexane (CHDM) from 32 to 80 mole% formed homogeneous mixtures upon heating. The homogenization temperatures of the blends decreased with increasing CHDM content in PECT. The interaction energies of the BPC-PECT pairs calculated from the phase boundary in accordance with the lattice-fluid theory were positive and also decreased with increasing CHDM content in PECT. It was shown that the phase homogenization of these blends occurs upon heating when the combinatorial entropy term, which is favorable for miscibility, overcomes unfavorable energetic terms at elevated temperatures. A novel product, which is not limited by the drawbacks of linear polycarbonate (PC) and evidences processability superior to that of the PC/PECT blends, can be developed via the blending of BPC and PECT.

Improving Gas Barrier Property of Polymer Based Nanocomposites Using Layer by Layer Deposition Method for Hydrogen Tank Liner

  • Lee, Suyeon;Han, Hye Seong;Seong, Dong Gi
    • Composites Research
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    • 제35권3호
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    • pp.121-126
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    • 2022
  • Owing to advantages of polymeric materials for hydrogen tank liner like light-weight property and high specific strength, polymer based composites have gained much attention. Despite of many benefits, polymeric materials for fuel cell tank cause problems which is critical to applications as low gas barrier property, and poor processability when adding fillers. For these reasons, improving gas barrier property of polymer composites is required to study for expanding application fields. This work presents impermeable polymer nanocomposites by introducing thin barrier coating using layer by layer (LBL) deposition method. Also, bi-layered and quad-layered nanocomposites were fabricated and compared for identifying relationship between deposition step and gas barrier property. Reduction in gas permeability was observed without interrupting mechanical property and processability. It is discussed that proper coating conditions were suggested when different coating materials and deposition steps were applied. We investigated morphology, gas barrier property and mechanical properties of fabricated nanocomposites by FE-SEM, Oxygen permeation analyzer, UTM, respectively. In addition, we revealed the mechanism of barrier performance of LBL coating using materials which have high aspect ratio.

토기 복원용 Epoxy Putty 개발 및 물성에 관한 연구 (A study on the development and the physical properties of Epoxy Putty for earthenware restoration)

  • 배진수;정다솜;김우현;강석인;위광철
    • 보존과학회지
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    • 제30권1호
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    • pp.103-109
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    • 2014
  • 본 연구는 토 도기 보존 처리과정에 있어서 결손부위를 복원하는 재료의 문제점과 단점 등을 보완한 재료를 개발하고자 하였다. 우선 기존 재료의 문제점으로는 높은 수축률과 낮은 접착력으로 인한 2 차 파손의 문제, 심한 황변현상으로 인한 이질감의 문제, 재료의 비가역성으로 인한 재용해의 문제 및 높은 강도로 인한 가공성의 문제, 작업 과정 중 긴 경화 시간으로 인한 처짐 현상 및 도구나 장갑에 묻어 유물의 표면을 오염시키는 문제 등이 있다. 이러한 문제점을 해결하기 위해 현재 사용되고 있는 토 도기 복원 재료들 중 Epoxy 수지를 중심으로 종류 및 물성을 파악한 후 개발 목표를 설정하였다. 개발 된 Epoxy는 5 분 내외에 경화가 이루어지는 토기 복원용 Epoxy Putty이다. 토기 복원 방법에 있어서 Epoxy Putty의 경우 페이스트(Paste) 형태로 빠르게 경화되어 작업의 편리성을 높였으며, 표면 오염 등의 단점을 보완하였다. 또한 Epoxy 원액에 백색의 Micro-balloon을 사용함으로 인해 Coloring에 용이하고 경량화하도록 하였으며, 저수축 및 가공성이 우수한 복원 재료를 개발하였다.

Thermotropic Liquid Crystal Polymer and PBT Blend

  • Lim, Sung-Tack;Kim, Seong-Hun
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 1998년도 봄 학술발표회 논문집
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    • pp.14-19
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    • 1998
  • Increasing demand for high modulus high strength polymeric materials have drawn considerable interest in industry. Thermotropic liquid crystal polymers (TLCP), differing from lyotropic liquid crystal polymers, have excellent melt processability and mechanical property resulting from the high degree of molecular orientation under a shear flow field in the molten state with relatively low viscosity$\^$1,2/.(omitted)

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자유곡면 가공을 위한 Machining configuration 결정에 관한 연구 (Determining machining configuration for NC machining of free surfaces)

  • 강재관;서석환
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1992년도 한국자동제어학술회의논문집(국내학술편); KOEX, Seoul; 19-21 Oct. 1992
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    • pp.1084-1089
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    • 1992
  • Process planning is a key feature that an intelligent CAD/CAM system should possess. In this paper, we address the problem of determinig process configuration to manufacture the free surfaces. For analyzing the surface, the method of surface subdivision is used. The developed algorithm evaluates the processability of the given surface by applying the three/four/five-axes procedures sequentially. To illustrate and test the developed algorithm, numerical simulations are presented.

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Electrical Conductivity of Polypyrrole/Copolyester Composite Films. 2. Composite Films Prepared from Copolyester-$FeCl_3$ Surface Absorption

  • Lee, Seong-Mo;Baik, Doo-Hyun
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 1998년도 가을 학술발표회논문집
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    • pp.53-56
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    • 1998
  • Polypyrrole (PPy) is regarded as one of the most Promising intrinsically or naturally conductive polymer for practical applications due to its relatively high electrical conductivity, environmental stability and low toxicity. The typical PPy, which is insoluble and infusible, exhibits poor processability and lacks essential mechanical properties. A number of papers have concerned the efforts to overcome these drawbacks. (omitted)

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리브를 가진 사출제품의 공리 설계 연구 (A Study on Axiomatic Design for Ribbed - Injection-Molded Parts)

  • 허용정
    • 반도체디스플레이기술학회지
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    • 제6권3호
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    • pp.7-11
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    • 2007
  • The design and manufacture of injection-molded parts with desired properties is a costly process dominated by empiricism, Including the repeated modification of actual tooling. The objective of this study is to obtain the good design of injection-molded polymeric parts using axiomatic design approach.

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Concepts for solution-processable OLED materials at Merck

  • Hayer, A.;Anemian, R.;Eberle, T.;Heun, S.;Ludemann, A.;Schulte, N.;Buchholz, H.
    • Journal of Information Display
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    • 제12권1호
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    • pp.57-59
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    • 2011
  • Drastic performance increase and accelerated progress in organic light-emitting diodes from solutions are shown using solution-processable small molecules based on the core structures of vacuum-evaporable materials. Systematic modification of small-molecule materials toward better processability from solutions at identical electro-optical properties is shown. This is demonstrated to lead to a significant improvement in the device performance.

대단면 스킨팀버의 용재 가능성과 이를 활용한 생활용품 디자인 개발 (Manufacturing Life articles and a Possibility of Materials Using the Structural Size Skin-Timber)

  • 임승택
    • 한국가구학회지
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    • 제24권1호
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    • pp.60-69
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    • 2013
  • Timber is an eco-friendly material that is suitable for low carbon and green growth, and recently, studies on utilization and manufacture of timber are increasing. Thus, we need a stable supply of wood working materials for the formative element and widespread function of timber. It is necessary to develop the use of timber because it enhances the added value of this material by making the most of it. In this way, skin-timber is an appropriate material for life articles because skin-timber has a variety of functions including the ability for storage use, the beauty of structure, the ability to maintain heat and insulation, and the capability to control humidity. In this study, I developed household items using skin-timbers that are made up of circular columns and square columns of pine, larch, and yellow popular. The circular and square columns have an inner hole that is approximately 90% of the external structure's width. I intended for the concept of these designs to display creativity considering functionality and productivity. These items are life articles and furniture for modern people. They are eco-friendly products that are varnished with traditional lacquer and natural oil. According to the result of this study, skin-timbers are made of domestic pine, larch, and yellow popular and are resource of furniture, household items, and woodcraft. I believe skin-timber is not only a useful material for processability and design applicability, but it also has the capability to be a multifunctional and high value-added material. Also, if the standards, such as cortex thickness, outside diameter, and length, of skin-timber are producted diversely, I believe skin-timber can be have more the possibility of industrial products' development.

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