• Korean Journal of Food Science and Technology
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• v.50 no.1
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• pp.21-27
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• 2018

Turmeric oleoresin, extracted from the rhizome of Curcuma longa L., is a widely-used natural food colorant. Curcuminoids, the major pigments in turmeric, which include curcumin, demethoxycurcumin (DMC), and bisdemethoxycurcumin (BMC), possess various physiological activities. In the present study, changes in the chemical properties, antioxidant activities, and cytotoxicity of turmeric pigments upon heating were investigated. Color intensity of turmeric was significantly reduced after heating. Residual levels of curcumin, DMC, and BMC after 15 min of heating at $95^{\circ}C$ were 11.9, 37.4, and 77.3% respectively. Scavenging activities of turmeric against 2,2'-azobis-3-ethyl-benz-thiazoline-6-sulfonic acid (ABTS), 2,2-azobis (2-amidinopropane) hydrochloride (AAPH) peroxyl radicals, and nitrite were significantly enhanced after heating, while 2,2-diphenyl-1-picryl-hydrazyl (DPPH) radical scavenging activity remained unaffected. Generation of $H_2O_2$ from turmeric was increased via thermal decomposition. Cytotoxicity of turmeric pigments against colon cancer and normal intestinal cells was reduced significantly after heating. The results indicate that thermal processing affects chemical properties and bioactivities of turmeric pigments. These effects should be considered during the processing of foods containing turmeric pigments.

• Korean Journal of Remote Sensing
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• v.21 no.3
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• pp.189-211
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• 2005

This paper makes an effort to compare the recently evolved soft classification method based on Linear Spectral Mixture Modeling (LSMM) with the traditional hard classification methods based on Iterative Self-Organizing Data Analysis (ISODATA) and Maximum Likelihood Classification (MLC) algorithms in order to achieve appropriate results for mapping, monitoring and preserving valuable coastal wetland ecosystems of southern India using Indian Remote Sensing Satellite (IRS) 1C/1D LISS-III and Landsat-5 Thematic Mapper image data. ISODATA and MLC methods were attempted on these satellite image data to produce maps of 5, 10, 15 and 20 wetland classes for each of three contrast coastal wetland sites, Pitchavaram, Vedaranniyam and Rameswaram. The accuracy of the derived classes was assessed with the simplest descriptive statistic technique called overall accuracy and a discrete multivariate technique called KAPPA accuracy. ISODATA classification resulted in maps with poor accuracy compared to MLC classification that produced maps with improved accuracy. However, there was a systematic decrease in overall accuracy and KAPPA accuracy, when more number of classes was derived from IRS-1C/1D and Landsat-5 TM imagery by ISODATA and MLC. There were two principal factors for the decreased classification accuracy, namely spectral overlapping/confusion and inadequate spatial resolution of the sensors. Compared to the former, the limited instantaneous field of view (IFOV) of these sensors caused occurrence of number of mixture pixels (mixels) in the image and its effect on the classification process was a major problem to deriving accurate wetland cover types, in spite of the increasing spatial resolution of new generation Earth Observation Sensors (EOS). In order to improve the classification accuracy, a soft classification method based on Linear Spectral Mixture Modeling (LSMM) was described to calculate the spectral mixture and classify IRS-1C/1D LISS-III and Landsat-5 TM Imagery. This method considered number of reflectance end-members that form the scene spectra, followed by the determination of their nature and finally the decomposition of the spectra into their endmembers. To evaluate the LSMM areal estimates, resulted fractional end-members were compared with normalized difference vegetation index (NDVI), ground truth data, as well as those estimates derived from the traditional hard classifier (MLC). The findings revealed that NDVI values and vegetation fractions were positively correlated ($r^2$= 0.96, 0.95 and 0.92 for Rameswaram, Vedaranniyam and Pitchavaram respectively) and NDVI and soil fraction values were negatively correlated ($r^2$ =0.53, 0.39 and 0.13), indicating the reliability of the sub-pixel classification. Comparing with ground truth data, the precision of LSMM for deriving moisture fraction was 92% and 96% for soil fraction. The LSMM in general would seem well suited to locating small wetland habitats which occurred as sub-pixel inclusions, and to representing continuous gradations between different habitat types.

• Korean Journal of Heritage: History & Science
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• v.46 no.3
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• pp.150-171
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• 2013

The most important part of conservation treatment of murals is to preserve them against the risk of a damage by injecting fixative into them when the painting loses its cohesion or powderization of pigments occurred due to occurrence of cracks inside the painting layer. However, studies on the stability of fixative used for painting layers of murals are still insufficient. This study manufactured a mural as a specimen and colored it with four kinds of pigments including oyster shell white, cinnabar, malachite and red clay and applied four kinds of fixative, including, Paraloid $B-72^{(R)}$, Caparol-$binder^{(R)}$, glue and Hydoxypropyl $cellulose^{(R)}$. artificially generated environmental changes in temperature, humidity and ultraviolet rays which may occur after the completion of conservation treatment. Then the changes in physical properties were observed in multifaceted ways such as color stability, contact angle, brilliance, adhesive strength and surface. As a result, this study found that ultraviolet rays and hot?humid environment have a large impact on color stability causing changes in brightness and chroma of all painting layers where the fixative were applied, except for oyster shell white and are considered the main factors of decomposition by accelerating the aging process of fixatives applied. In comparison to the synthetic resins that were also tested in this study, the traditional glue showed satisfactory results in terms of color stability and influence preservation and the hydrophile property. As it showed exceptionally outstanding adhesive strength in all painting layers in the aspect of adhesive strength, it is considered to be highly stabile for the fixation treatment of painting layers of mural.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.2
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• pp.789-793
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• 2021

A lithium secondary battery is the most promising candidate for future energy storage devices. On the other hand, the battery capacity decreases gradually due to the small amount of water and decomposition of the salts during the charging and discharging process, which deteriorates at high temperatures. Many researchers focused on increasing the cycling performance, but there have been few studies on the fundamental problem that removes water and HF molecules. In this study, silane molecules that are capable of absorbing water and HF molecules are introduced to the separator. Firstly, silica-coated amino-silane (APTES, 3-aminopropyltriethoxysilane) was synthesized, then the silica reacted with epoxy-silane, GPTMS ((3-glycidyloxypropyl)trimethoxysilane). A ceramic-coated separator was fabricated using the silane-coated silica, which is coated on porous polyethylene substrates. FT-IR spectroscopy and TEM analysis were performed to examine the chemical composition and the shape of the silane-coated silica. SEM was performed to confirm the ceramic layers. LMO half cells were fabricated to evaluate the cycling performance at 60 ℃. The cells equipped with a GPTMS-silica separator showed stable cycling performance, suggesting that it would be a solution for improving the cycling performance of the Li-ion batteries at high temperatures.

• Economic and Environmental Geology
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• v.54 no.1
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• pp.151-160
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• 2021

2:1 clay minerals such as smectite incorporating ammonium were extracted to investigate the ammonium behavior and nitrogen isotope characteristics for two different sediment cores which were collected from shimmering sites on seafloor of the Wakamiko crater, southwestern Japan. Inorganic nitrogen contents in clay fraction were estimated by calibration curve based on consistently decreasing carbon and nitrogen ratio during the treatment to decompose organic materials, after removing inorganic carbon. The results show that the proportions of inorganic nitrogen for total nitrogen in clay fraction of SWS site(Core#1094MR: av. 18.2%) are higher than those in SES site(Core#1093MG: av. 11.5%). Relatively good crystallinity of the former suggests that exchangeable ammonium was transformed to non-exchangeable ammonium during more evolving diagenetic process. Nitrogen isotope variance of clay fraction(SES site: Core#1093MG: -4.4 ~ +0.2 ‰, av. -2.4 ‰; SWS site: Core#1094MR: -0.7 ~ +3.0 ‰, av. +1.5 ‰) during sequential decomposition of exchangeable ammonium suggests that heat flow derived from deep magma led to nitrogen isotope fractionation between dissolved ammonium and ammonia in the fluids involved in the formation of 2:1 clay mineral incorporating ammonium with local temperature variation.

• Journal of Navigation and Port Research
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• v.46 no.3
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• pp.289-296
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• 2022

The purpose of this study was to investigate the inter-correlation between crude oil prices and Dry Bulk Freight rates. Eco-friendly shipping fuels has being actively developed to reduce carbon emission. However, carbon neutrality will take longer than anticipated in terms of the present development process. Because of OVID-19 and the Russian invasion of Ukraine, crude oil price fluctuation has been exacerbated. So we must examine the impact on Dry Bulk Freight rates the oil prices have had, because oil prices play a major role in shipping fuels. By using the VAR (Vector Autoregressive) model with monthly data of crude oil prices (Brent, Dubai and WTI) and Dry Bulk Freight rates (BDI, BCI and (BP I) 2008.10~2022.02, the empirical analysis documents that the oil prices have an impact on Dry bulk Freight rates. From the analysis of the forecast error variance decomposition, WTI has the largest explanatory relationship with the BDI and Dubai ranks seoond, Brent ranks third. In conclusion, WTI and Dubai have the largest impact on the BDI, while there are some differences according to the ship-type.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.48 no.4
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• pp.331-342
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• 2022

Obesity is one of the metabolic diseases caused by excessive differentiation and accumulation of adipose tissue due to an imbalance between energy intake and consumption. In this study, we investigated the anti-obesity effect of SliMax, a natural-derived 6 compounds mixture, by using 3T3-L1 cells. As a result, SliMax showed the inhibitory effect on adipocyte differentiation through down-regulation of the PPARγ and C/EBPα expression, which are known to regulate the late adipogenesis stage. In the process of lipolysis on differentiated 3T3-L1 cells, SliMax accelerated decomposition of large-sized unilocular lipid droplet into numerous small-sized multilocular lipid droplets through up-regulation of the expression of lipolysis-related proteins ATGL and HSL. Finally, in order to confirm the effect of SliMax on induction of brown adipocyte, the expression of UCP-1 and the amount of mitochondria were confirmed by immunofluorescent staining, and as a result, SliMax increased the expression of UCP-1 and the amount of mitochondria in fat cells. Taken together, those results suggest that SliMax, a naturally-derived mixture, have a potential to be anti-obesity agent through exerting inhibitory effect on the formation of lipid droplet by suppression of adipogenesis and stimulation of lipolysis, and browning effect associated with generation of heat energy and energy consumption.

• Applied Chemistry for Engineering
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• v.34 no.1
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• pp.80-85
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• 2023

New yellow quinoline-dione dye derivatives were designed and synthesized for use in image sensor color filters. The synthesized compounds have a basic chemical structure composed of quinoline and dione groups. New materials were evaluated on the basis of their optical and thermal properties under conditions mimicking those of a commercial device fabrication process. A comparison of their related performances revealed that, between the two prepared compounds, 2-(3-hydroxyquinolin-2(1H)-ylidene)-1H-indene-1,3(2H)-dione (HQIDO) exhibited the superior performance as an image sensor color filter material, including a solubility greater than 0.5 wt% in propylene glycol monomethyl ether acetate solvent and a high decomposition temperature of 298 ℃, respectively. The results suggest that HQIDO can be used as a yellow dye additive in an image sensor colorant.

• Journal of Korea Water Resources Association
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• v.55 no.12
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• pp.1065-1076
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• 2022

The purpose of this study was to investigate the effect of the expansion and withering of Salix subfragilis communities on the water quality in Namgang Dam reservoir. The distribution area of the Salix subfragilis communities was 0.12 km² in 2003 for the first time, but it was 3.58 km² in 2019, which has increased rapidly by about 30 times in 16 years. However, in 2013, the distribution area has decreased by 0.17 km² due to long-term immersion in high turbidity, and self-thinning in Salix subfragilis communities. The lake characteristics of reservoir showed a combination of lake type and river type in terms of average water depth, watershed area/lake surface area ratio, water residence time, flushing rate, and stratification. From the result of analyzing long-term changes in lake water quality, COD, TP, and chlorophyll-a in Salix subfragilis communities were significantly larger than those in the three points located in the central part of reservoir. In particular, the fact that the value of chlorophyll-a showed the maximum value in winter rather than summer, unlike the trend of the three points in the Namgang Dam water quality monitoring network, is thought to have occurred internally rather than externally. It can be estimated that one cause of this deterioration of the water quality in Namgang Dam reservoir is the huge amount of nutrients generated in the decomposition process of by-products such as fallen leaves, branches and withered trees in Salix subfragilis communities.

• Korean Chemical Engineering Research
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• v.60 no.3
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• pp.414-422
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• 2022

The objective of this work was to investigate the feasibility of acid-catalyzed hydrothermal fractionation for maximum solubilization of the hemicellulosic portion of two typical agricultural residues. The fractionation conditions converted into combined reaction severity (CS) in the range of 1.2-2.9 was used to establish a simple reaction criteria at glance. The hemicellulosic sugar yield of 56.6% was shown when rice straw was fractionated at the conditions at the conditions; 160 ℃ of temperature 0.75% (w/v) of H₂SO₄, 20 min of reaction time, 1:15 solid/liquid ratio. The hemicellulosic sugar yield of 83.0%, however, was achieved when barley straw was fractionated at the conditions at the conditions; 150 ℃ of temperature 0.75% (w/v) of H₂SO₄, and 15 min of reaction time, 1:10 solid/liquid ratio. For barley straw, acid-catalyzed hydrothermal fractionation could be effectively performed. After the fractionation process, the remaining fractionated solids were 48.5% and 57.5% from raw rice and barley straws, respectively. The XMG contents in the solid residues decreased from 17.3% and 17.6% to 6.0% and 2.6%, which corresponded to 16.7% and 8.5% on the basis of the raw straws, respectively. In another way, only 5.6% of cellulose and 8.5% of XMG were lost due to excessive decomposition during the acid-catalyzed hydrothermal fractionation of barley straw, compared to cellulose and XMG losses of 6.4% and 26.6% in rice straw. Hemicellulosic sugars from the rice straw were considered more over-decomposed due to the somewhat higher reaction severity at the acid-catalyzed hydrothermal fractionation.