• 제목/요약/키워드: Priority pollutants

검색결과 95건 처리시간 0.022초

토지피복분류에 관한 이론적 연구 - 자연환경관리를 중심으로 - (A Theoretical Study on Land Cover Classification - Focused on Natural Environment Management -)

  • 전성우;김귀곤;박종화;이동근
    • 한국환경복원기술학회지
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    • 제2권1호
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    • pp.29-37
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    • 1999
  • Land cover classification is an essential basic information in natural environment management; however, land cover classification studies in Korea have not yet been proceeded to a sufficient level. At the present, only a limited number of the precedent studies that only cover definite city area has been conducted. Furthermore, there is almost no research conducted on the land cover classification schemes that could accurately classify the Korea's land cover conditions. This study primarily focuses on the land cover classification scheme which carries the most urgent priority in order to classify and to map out the Korean land cover conditions. In order to develop the most suitable land cover classification scheme, many foreign land cover classification cases and projects that are being carried out were reviewed in depth. The land cover classification scheme this study proposes comprises 3 levels : The first level consists of 7 different classes; the second level consists of 22 different classes; and the third level is made up of 50 classes. The land cover classification map will serve many important roles in natural environment management, such as the conjecture of natural habitats and estimation of oxygen production or carbon dioxide absorption capability of a forest. In water pollution modelling, the land cover classification data can be used to estimate and locate non-point sources of water pollution. If applied to a watershed, modelling it will allow to estimate the total amount of pollution from non-point sources of pollution in the water shed. The land cover classification data will also be good as a barometer data that determines defusion of air pollutants in air pollution modelling.

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흡착관과 캐니스터를 이용한 대기 중 휘발성유기화합물 측정방법의 비교 평가 (Comparison of Measurement Methods for Volatile Organic Compounds in Ambient Air Using Adsorbent Tubes and Canisters)

  • 백성옥;서영교;허귀석;전찬곤;이민도;한진석
    • 한국대기환경학회지
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    • 제32권3호
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    • pp.305-319
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    • 2016
  • This study was carried out to evaluate the performance of two sampling methods, i.e., adsorbent tubes and canisters, for the measurement of ambient volatile organic compounds (VOCs). A total of 24 target VOCs were selected from a list of 48 priority hazardous air pollutants (HAPs) in Korea. The two sampling methods were investigated with a wide range of performance criteria such as repeatability, linearity, and lower detection limits. In addition, mean relative errors (MRE) and mean duplicate precisions (MDP) were estimated by inter-lab comparison studies for duplicate field samples. Precisions for the two methods appeared to be well comparable with the performance criteria recommended by USEPA TO-15 and TO-17 for canister and adsorbent methods, respectively. Correlations and variations between the VOCs concentrations determined by the two methods were generally good in most cases. However, MREs and MDPs for individual VOCs appeared to be widely ranged, depending on each VOC. This implies that the two methods have its own advantages and disadvantages in determining a variety of VOCs in ambient air, and neither of which has absolute superiority. Finally, 9 of 24 VOCs were found to be difficult to determine by either methods due to their unstability in a canister, and lack of appropriate standard materials. Thus, it is suggested that development of measurement methods for such unstable VOCs is an urgent task from a viewpoint of HAPs management.

남강 중권역의 효율적인 유역관리를 위한 중점관리 대상지류 선정 (Selection of Priority Management Target Tributary for Effective Watershed Management in Nam-River Mid-watershed)

  • 정강영;김경훈;이재운;이인정;윤종수;이경락;임태효
    • 한국물환경학회지
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    • 제29권4호
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    • pp.514-522
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    • 2013
  • The major 24 tributaries in Nam-River mid-watershed were monitored for discharge and water quality in order to understand the characteristics of the watershed and to select the tributary catchment for improving water quality. According to the analytical results of discharge and water quality monitoring data of 24 tributaries, the mean value of discharge below $0.1m^3/s$ was 62.5% among the monitored tributaries and it mostly exceeded the water quality standards of Nam-river mid-watershed ($BOD_5$ = 3 mg/L, T-P = 0.1 mg/L over). According to the stream grouping method and the water quality delivery load density ($kg/day/km^2$) based on the results of tributary discharge and water quality monitoring, the tributary watersheds for improving the water quality were selected. In the Nam-River mid-watershed, tributaries in the GaJwaCheon, HaChonCheon catchment (Group D, $BOD_5$ = 3 mg/L over) and in the UirYeongCheon, SeokGyoCheon catchment (Group A, T-P = 0.1 mg/L over), which have a small flow (and/or large flow) and a high concentrations of water pollutants. The various water quality improving scheme for tributaries, in accordance with the reduction of potential point source pollution by living sewage and livestock wastewater, should be established and implemented.

Biodegradation of Aromatic Compounds by Nocardioform Actinomycetes

  • CHA CHANG-JUN;CERNIGLIA CARL E.
    • 한국미생물학회:학술대회논문집
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    • 한국미생물학회 2001년도 추계학술대회
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    • pp.157-163
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    • 2001
  • Mycolic acid-containing gram-positive bacteria, so called nocardioform actinomycetes, have become a great interest to environmental microbiologists due to their metabolic versatility, multidegradative capacity and potential for bioremediation of priority pollutants. For example, Rhodococcus rhodochrous N75 was able to metabolize 4-methy1catechol via a modified $\beta$-ketoadipate pathway whereby 4-methylmuconolactone methyl isomerase catalyzes the conversion of 4-methylmuconolactone to 3-methylmuconolactone in order to circumvent the accumulation of the 'dead-end' metabolite, 4-methylmuconolactone. R. rhodochrous N75 has also shown the ability to transform a range of alkyl-substituted catechols to the corresponding muconolactones. A novel 3-methylmuconolactone-CoAsynthetase was found to be involved in the degradation of 3-methylmuconolactone, which is not mediated in a manner analogous to the classical $\beta$-ketoadipate pathway but activated by the addition of CoA prior to hydrolysis of lactone ring, suggesting that the degradative pathway for methylaromatic compounds by gram-positive bacteria diverges from that of proteobacteria. Mycobacterium sp. Strain PYR-l isolated from oil-contaminated soil was capable of mineralizing various polyaromatic hydrocarbons (PAHs), such as naphthalene, phenanthrene, pyrene, fluoranthrene, 1-nitropyrene, and 6-nitrochrysene. The pathways for degradation of PAHs by this organism have been elucidated through the isolation and characterization of chemical intermediates. 2-D gel electrophoresis of PAH-induced proteins enabled the cloning of the dioxygenase system containing a dehydrogenase, the dioxygenase small ($\beta$)-subunit, and the dioxygenase large ($\alpha$)-subunit. Phylogenetic analysis showed that the large a subunit did not cluster with most of the known sequences except for three newly described a subunits of dioxygenases from Rhodococcus spp. and Nocardioides spp. 2-D gel analysis also showed that catalase-peroxidase, which was induced with pyrene, plays a role in the PAH metabolism. The survival and performance of these bacteria raised the possibility that they can be excellent candidates for bioremediation purposes.

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활성슬러지 하수처리장에 유입된 Polycyclic Aromatic Hydrocarbons의 농도분포를 예측하기 위한 수학적 모형의 개발 (A Mathematical Model for Prediction of the Fats of Polycyclic Aromatic Hydrocarbons in Activated Sludge Processes : Steady State and Dynamic Simulation)

  • 고광백;벌소폴맥
    • 대한토목학회논문집
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    • 제10권4호
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    • pp.173-184
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    • 1990
  • 본 연구에서는 활성슬러지 하수처리장에 유입된 PAHs의 일종인 anthracene을 대상으로 이의 농도분포, 물리적 혹은 생물학적 변환을 예측하기 위한 수학적 모형을 제안하였다. 이 수학적 모형은 유입 anthracene의 volatilization, biodegradation 및 adsorption/desorption과 같은 반응을 고려한 5개의 연립미분방정식으로 구성되어 있으며, 이들에는 7개의 kinetic rate constants와 18개의 input variables를 포함하고 있다. Steady state simulation의 결과 유입된 anthracene은 1차 침전지에서의 슬러지 배출로 인하여 약 33%가 포기조에서 발생한 volatilization에 의하여 약 61%가 제거되어, 총괄적인 anthracene의 제거율은 약 97%정도이었다. Dynamic simulation의 결과로 본 연구대상 system의 경우에 system이 steady state에 도달하는 시간은 약 160시간 정도로 예측되었다. 이와 아울러 본 연구에서 제안된 수학적 모형의 활용 가능성이 각종 simulation의 결과로 비교적 구체적으로 규명되었다.

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수질유해물질의 지정 및 배출허용기준 설정 시 고려해야 하는 복합적 요인에 대한 고찰: 위해성 저감을 중심으로 (The Various Factors which Should Be Considered in Classifying Toxic Substances in Water and Deriving Their Effluent Limits: Focusing on the Reduction of Risk)

  • 배효관;정윤철;양형재;김재훈;이현동;정진영
    • 한국물환경학회지
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    • 제23권5호
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    • pp.766-775
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    • 2007
  • The use of toxic chemicals was extended as the industry in Korea has grown dramatically during the last three decades. However, list of toxic substances and limit concentrations in the water environment are not consistent within management of ambient water, drinking water and industrial effluent. This article suggests the systematic framework to classify toxic substances in the water environment and deriving their effluent limits. The most important factor for decision-making to classify toxic substances is whether their concentrations in the water environment are higher than the reference concentrations, estimated by considering human health risk and ecological risk. Using a risk-based reference concentration, the ambient water quality criterion, it is possible to derive the regulatory limit concentrations of toxic substances in drinking water and in industrial effluent. The goal concentrations in the effluent, which guarantee the human and ecological safety, should be determined with scientific investigation, balancing environmental benefit and economical effect, considering availability of treatment technology and identifying characteristics of wastewater from different industries.

Distribution of Polycyclic Aromatic Hydrocarbons (PAHs) in Surface Sediments inside Songsanpo and Seogwipo Harbors of Jeju Island, Korea

  • Moon Sang-Hee;Lee Young-Don;Lee Min-Gyu;Kam Sang-Kyu
    • 한국환경과학회지
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    • 제14권2호
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    • pp.105-119
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    • 2005
  • The surface sediments inside Songsanpo and Seogwipo Harbors, major harbors of Jeju Island, were collected three times (June, September and December, 2001) and analyzed for 16 polycyclic aromatic hydrocarbons (PAHs) recommended by US-EPA as priority pollutants to assess their distribution levels and their biological effects on the marine organisms, and to suggest their possible origins. The concentrations of total PAHs inside Songsanpo and Seogwipo Harbors ranged from 41 to 288 ng/g on a dry weight basis with a mean value of 121 ng/g and from 14 to 268 ng/g with a mean value of 119 ng/g, respectively, and the levels were low as compared with those in other areas of the world. The sedimentary PAHs may be correlated with organic carbon and mud content to some extent. Based on comparisons of individual and total concentrations with effects-based sediment quality guidelines, the potential for the biological effects on the marine organisms were expected to be very low. From the examinations of the four PAH origin indices, such as LMW /HMW (low molecular weight 2-3 ring PAHs over high molecular weight 4-6 ring PAHs), phenanthrene/anthracene ratio, fluoranthene/pyrene ratio, chrysene/benzo[a]anthracene ratio, it can be concluded that the sediment PAH contaminations were ascribed to both of pyrolytic and petrogenic origins.

오염물질기준지수(Pollutant Standards Index)를 이용한 대기질의 평가 -서울특별시 대기오염도에 대하여- (An Assessment of Air Pollution using Pollutant Standards Index (PSI) : $1983{\sim}1984$ in Seoul)

  • 정용;장재연;권숙표
    • Journal of Preventive Medicine and Public Health
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    • 제19권1호
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    • pp.65-75
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    • 1986
  • In order to assess the general health effect due to air pollution and to determine the critical pollutant which is meant by the worst effect to health among various pollutants in Seoul, air quality measurements at 10 sites during $1983{\sim}1984$ were analyzed using Pollutant Standards Index(PSI) : This index has been ultimately proposed to describe the comprehensive degree of the air pollution by U.S. Environmental Protection Agency(EPA) since 1976. Total average of PSI in Seoul during the two years was 139 that is described in 'unhealthful' The highest PSI appeared in Winter 183 through the 2 years, the lowest in Summer 99, and Spring 129 and Fall 150 respectively, PSI in Deungchon dong and Seongsu dong which are industrial areas were very high in terms of 'very unhealthful', while shinlim dong was shown in low in terms of 'good'. TSP was a priority pollutant in Seoul as the most frequently occuring critical pollutant. Its frequency was 76.4% in Spring, 86.0% in Summer, 78.0% in Fall and 44.2% in Winter during the 2 years. In Winter, $TSP{\times}SO_2$ was an important term as the critical pollutant in Seoul. Oxidant was the most frequently occuring critical pollutant in Kwangwhamoon through the whole seasons. It was recommended that the PSI could be used to assess the air pollution administratively and legally in context with publich health.

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다환방향족탄화수소에 대한 오존처리의 방법에 관한 연구 (A Study on the Degradation of PAH in Organic and Aqueous Phases by Ozone)

  • 최영익;손희종;정철우
    • 한국물환경학회지
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    • 제22권6호
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    • pp.1123-1129
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    • 2006
  • 대부분의 polycyclic aromatic hydrocarbons (PAHs) 은 최우선 오염물질로 간주되어지고 있는 매우 유독한 물질이다. Pyrene은 PAHs들 중에서도 그 유독성은 가히 심각하다. 그리고 Pyrene과 다른 PAHs화합물들은 물에 잘 용해가 되지 않는 소수성 성질을 가지고 있어 화학적 또는 생물학적 분해가 용이하지 않다. 이러한 성질을 극복하기 위하여 본 연구에서는 Pyrene을 대표 물질로 하여 2 단계 오존처리를 하였다. 첫 단계에서 Pyrene을 무극성인 핵산 용매에 대량 (2000 mg/L) 으로 녹여 오존처리를 하였다. 이때 Pyrene은 극성 분자들, 즉 알콜과 알데하이드 그리고 에시드 기능기를 가지는 물질들로 변화되었으며 이 변화된 물질들을 다시 극성 용매, 물에 녹여 두 번째 오존처리를 하였다. 두 번째 오존 처리된 Pyrene의 부산물들과 중간생성물들은 생물학적 처리로 가능한지 연구되어지기 위해 $BOD_5$와 COD 그리고 E-coli toxicity tests가 이루어졌다. 그 결과 오존 처리된 Pyrene은 유독하지도 않았고 Pyrene의 부산물들과 중간생성물들은 생물학적 처리가 용이하여졌다. Gas chromatograph (GC) 분석을 통해 Pyrene의 부산물들과 중간생성물들을 밝혀내었다. 이 연구를 토대로 소수성 성질을 가지는 많은 방향족 물질들을 처리하기가 매우 용이해졌다.

Remediation of Contaminated Sites in Canada

  • Koo, Jahak
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 1996년도 경북지부 결성 및 추계학술발표회 논문집
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    • pp.39-49
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    • 1996
  • Hundreds of contaminated sites have been generated due to the past mismagement of toxic substances, the lack of adequate environmental controls and ignorance of the potential environmental impacts of general activities in Canada. The general public, industry and governments have been addressing the contaminated sites with a number of cleanup responses. Environmental protection and remediation have become top priorities for the public and private sectors alike in Canada. Between the late 1980s and the early 1990s, the Canadian Environmental Protection Act and Canada's Green Plan were followed by provincial and territorial laws and policies to regulate contaminated sites. The National Contaminated Site Remediation Program(NCSRP) was initiated in 1989. It has been administered through bilateral agreements between the federal and participating provincial/territorial governments. They have committed a total of $250 million toward orphan site cleanup and technology development/demonstration over a five year period. The federal government has committed an additional $25 million to assess contaminated sites on federal crown land. Over 40 orphan high-risk contaminated sites, over 230 federal sites and over 35 technology development/demonstration projects have been addressed. The Canadian Council of Ministers of the Environment has developed a series of guidance documents to ensure a consistent and successful implementation of the Program. The management/regulation scheme of contaminated sites generally consists of: 1) identifying and investigating sites, 2) determining site contamination, 3) recognizing responsibility and liability, 4) assessing priority for remediation, 5) activation, evaluation and implementing remediation options, and 6) documenting remediation completion. The NCSRP supported the successful development/demonstration of a wide range of innovative remedial technologies. They are related to stabilization/solidification, thermal washing/flushing, advanced oxidation, sonics, and groundwater contaminated with hydrocarbons, PAHS, PCBs, heavy metals, and other hazardous pollutants in a variety of site environments.

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