• Nuclear Engineering and Technology
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• v.55 no.2
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• pp.516-522
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• 2023

The co-precipitation process plays a key role in the decontamination of radionuclides from low and intermediate levels of liquid waste. For that reason, the removal of Cs ions from waste solution by the co-precipitation method was carried out. A simulated liquid waste (¹³³Cs) was prepared from a 0.1 M CsCl solution, while wastewater generated by washing steel ash served as a representative of radioactive cesium solution (¹³⁷Cs). By co-precipitation, potassium ferrocyanide was applied for the adsorption of Cs ions, while nickel nitrate and iron sulfate were selected for supporting the precipitation. The amount of residual Cs ions in the CsCl solution after precipitation and filtration was determined by ICP-OES, while the radioactivity of ¹³⁷Cs was measured using a gamma-ray spectrometer. After cesium removal, the amount of cesium appearing in both XRD and SEM-EDS was analyzed. The removal efficiency of ¹³³Cs was 60.21% and 51.86% for nickel nitrate and iron sulfate, respectively. For the ash-washing solution, the removal efficiency of ¹³⁷Cs was revealed to be more than 99.91% by both chemical agents. This implied that the co-precipitation process is an excellent strategy for the effective removal of radioactive cesium in waste solution treatment.

• Journal of Korea Water Resources Association
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• v.42 no.11
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• pp.1017-1028
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• 2009

NSRPM (Neyman-Scott Rectangular Pulse Model) is one of the common model for generating future precipitation time series in stochastical hydrology. There are 5 parameters to compose the NSRPM model for generating precipitation time series. Generally parameter estimation using moment has some problems related with increased objective functions and shows different results in accordance with random variable generating models. In this study, direct parameter estimation method was proposed to cover with disadvantages of parameter estimation using moment. To apply the direct parameter estimation, generating stochastical data variance in accordance with numbers of precipitation events of NSRPM was done. Both kinds of methods were applied at the Cheongju gauge station data. Precipitation time series were generated using 4 different random variable generator, and compared with observed time series to check the accuracies. As a results, direct method showed more stable and better results.

• Journal of Korea Water Resources Association
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• v.39 no.3 s.164
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• pp.215-226
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• 2006

In this study, we performed verification of VSRF (Very Short Range Forecast of precipitation) model and application of NWSPC (National Weather Service PC) rainfall-runoff model in Kyoungan-chun basin. We used two methods for verification of VSRF model. The first method is a meteorological verification that evaluates the special quality feature for rain amount between AWS and VSRF model over Kyoungan-chun basin, while second method is a hydrological verification that compares the calculated Mean Area Precipitation (MAP) between AWS and VSRF Quantitatively. This study examines the usefulness of VSRF precipitation forecasting model data in NWSPC hydrological model. As a result, correlation coefficient is over 0.6 within 3 hour lead time. It represents that the forecast results from VSRF are useful for water resources application.

• Journal of the Korean Data and Information Science Society
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• v.28 no.4
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• pp.797-810
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• 2017

The Korean peninsula is exposed to typhoons every year. Typhoons cause huge socioeconomic damage because tropical cyclones tend to occur with strong winds and heavy precipitation. In order to understand the complex dependence structure between strong winds and heavy precipitation, the copula links a set of univariate distributions to a multivariate distribution and has been actively studied in the field of hydrology. In this study, we carried out analysis using data of wind speed and precipitation collected from the weather stations in Busan and Jeju. Log-Normal, Gamma, and Weibull distributions were considered to explain marginal distributions of the copula. Kolmogorov-Smirnov, Cramer-von-Mises, and Anderson-Darling test statistics were employed for testing the goodness-of-fit of marginal distribution. Observed pseudo data were calculated through inverse transformation method for establishing the copula. Elliptical, archimedean, and extreme copula were considered to explain the dependence structure between strong winds and heavy precipitation. In selecting the best copula, we employed the Cramer-von-Mises test and cross-validation. In Busan, precipitation according to average wind speed followed t copula and precipitation just as maximum wind speed adopted Clayton copula. In Jeju, precipitation according to maximum wind speed complied Normal copula and average wind speed as stated in precipitation followed Frank copula and maximum wind speed according to precipitation observed Husler-Reiss copula.

• Water for future
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• v.8 no.2
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• pp.81-92
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• 1975

Calculation of the monthly water balance for Nakdong River basin for the period from 1958 to 1968 is made by determining three components independently: precipitation, runoff and evapotranspiration. The areal precipitation is computed by the Thiessen method using the records of nine meteorological stations in the basin, and the runoff is the flow gauged at Jindong which is located on the most downstream. For the computation of evapotranspiration, the Morton method is adopted because this method is relatively fit best in the calculation of water balance among the Morton, Penman and Thornthwaite methods. The values of Morton evapotransp iration are corrected by the factor of 0.82 in the basin in order to bring the error to zero. The areal evapotranspiration is the arithmetic mean of the Morton estimates at the stations. Mean water balance components in the Nakdong river basin are 1117.0mm, 600.6mm and 516.4m for precipitation, runoff and evapotranspiration respectively. Accordingly, the mean runoff ratio comes out to be 0.54. The smallest values of runoff coefficient are due for Daegu area, while the largest ones are for the southwest of the basin with the higher rainfall and high elevations there. The amount of runoff obtained by both Thornthwaite and Budyko methods for water balance computations indicate 59 and 60 per cent of actual values which are lower than the expected. An attempt is made to find the best reliable rainfall-runoff relation among the four methods proposed by Schreiber, 01'dekop, Budyko and Sellers. The modified equation of Schreiber type for annual runoff coefficient could be obtained with the smallest mean error of 11 per cent.

• KSBB Journal
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• v.10 no.3
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• pp.257-263
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• 1995

Fractional precipitation of "native" dextran by the method of nonsolvent addition was studied. Precipitational phenomenon of fractioned dextran was characterized with the quantitative determination of the precipitational capacity of nonsolvents with different dielectric constants. Based upon this characterization, the fractional precipitation process for the dextran production was developed. From the precipitational characteristics, a first-order relationship between the molecular weight of fractioned dextran and the content of nonsolvents was formulated. The slopes of the first-order equation were correlated with the dielectric constants of the nonslovents. A modified fractionation process was constructed on the basis of refractionation method and employed to increase the efficiency of the controlled production of dextran.

• Journal of the Korean Ceramic Society
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• v.33 no.1
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• pp.7-16
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• 1996

${CO_3}^{2-}$ containing whisker-like hydroxyapatite powders were synthesized byhomogeneous precipitation method using urea, Dicalcium phosphate anhdrate[DCPA; $CaHPO_4$] and octacalcium phosphate [OCP; $Ca_8H_2(PO_4_)6\cdot5H_20$]were obtained as precursors and they transformed to high crystalline hydroxyapatites at pH 5.62, and 6.54 respectively. According to the condition of the final pH in the solutions for the solution products and urea contents OCP was remained. When the solution product of $Ca^{2-}$ and ${PO_4}^{3-}$ was $1.5\times 10^4$[$mM^2$] and the content of urea was 0.25 mol.$dm^{-3}$ well crystallized whisker-like hydroxyapatite tens of micrometer in length was obtained. By heat treatment DCPA and OCP were decomposed into $\beta$-tricalcium phosphate [$\beta$-TCP ; $\beta$-$Ca_3{PO_4}_2$] and $\beta$-dicalcium phosphate [$\beta$-DCP ;$\beta$-$Ca_2P_2O_4}_2$]. And well-crystallized hydroxyapatite was partially decomposed into $\beta$-TCP at $800^{\circ}C$.

• Korean Journal of Metals and Materials
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• v.49 no.5
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• pp.367-373
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• 2011

This paper studies the experimental method that uses the homogeneous precipitation method to prepare mica flakes coated with anatase-type titania pearlescent pigment with urea as precipitant. The optimum technology parameters, the chemical composition, the microstructure, and the color property of resulting pigments are discussed. The coating principle of mica coated titania with various coating thickness is analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy(TEM) and tested by spectrophotometer analysis. The colored nanocrystalline pigments with different morphology and coating thickness 45-170 nm were prepared by homogeneous precipitation treatment of $TiOSO_4$(titanum oxysulfate) aqueous solutions. Characterizations on the pigments show that the pearlescent effects of the pigments depend mainly on mica size, thickness of the metal oxide deposit, its chemical composition, and crystal structure.

• Water for future
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• v.14 no.4
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• pp.35-52
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• 1981

This study is to evaluate the areal precipitation from the basic data groups of monthly, seasonal, and annual rainfalls over all ma in stations in Korea. The evaluating pocesses are performed through the point and regional frequency analysis from the basic data. The basic data groups are divided into two periods-the first(1916-1944) and the second (1960-1979)-which are compared with each other. In the point frequecny analysis, the variable transformation method is applied to the best fitting distribution, and the normal fittings are established by using the Chisquare test method. In the regional frequency analysis, the geomorphologic factors and hydrometeorological factors are taken into consideration when dividing into five zones and Thiessen method and the Isohyetal method are applied. The results of this study are as follows: 1)The areal precipitation values of the first period are about 70-80mm less than that of the second period for the whole of Korea. Therefore, a new precipitation value of 1180mm is considered more suitable than the value of 1159mm, which has been up till now. 2)As the annual areal precipitiation values areevaluated over the five divide zones, it tis noticed that the difference between the values of the first period and the second is the largest in spring (to the extent of 5 times that in the other seasonas). Thereform it is considered that this result is necessary for the establishment of a timely insurance plan for the water resources. 3)The application of the Isohyetal method through the division of Korea into five zones is considered to be a reasonable procedure in the analysis of areal precipitation.

• Bulletin of the Korean Chemical Society
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• v.31 no.9
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• pp.2488-2492
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• 2010

A method is described for the determination of the Po nuclides in a water sample. After the Po nuclides were purified from interfering elements in a water sample using a manganese dioxide precipitation followed by a solvent extraction method, the Po nuclides were deposited onto the silver plate. A large volume of the water sample was effectively pretreated with manganese dioxide precipitation method. To determine the optimum conditions for plating Po, the effects of the pH, volume, temperature and time on the Po deposition were investigated in hydrochloric acid solution. The investigated determination method of Po nuclides with solvent extraction was applied to a tap water sample.